# US 10,501,876 B2 · Highly functional spunbonded fabric made from particle-containing fibres and method for producing same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,501,876 B2 - Document ID: US10501876B2 - Status: Granted - Kind: B2 - Application number: 16/026,273 - Filed: 2018-07-03 - Published: 2018-11-01 - Granted: 2019-12-10 - Earliest claimed: 2010-09-14 - Assignees: Thueringisches Institut Fuer Textil-Und Kunststoff-Forschung E.V. - Applicants: Thüringisches Institut Für Textil- Und Kunststoff-Forschung E.V. - Inventors: Yvonne Ewert; Frank-Günter Niemz; Marcus Krieg; Bernd Riedel - Web page: https://patentgrep.com/patent/US10501876B2 ## CPC - D04H 3/16: with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion - D01D 5/06: Wet spinning methods {(D01D5/0046 takes precedence)} - D01D 5/14: with flowing liquid {or gaseous} stretching media {, e.g. solution-blowing} - D01F 1/10: Other agents for modifying properties - D01F 2/00: Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof - D01F 6/52: of polymers of unsaturated carboxylic acids or unsaturated esters - D04H 3/005: Synthetic yarns or filaments (D04H3/013 takes precedence) - D04H 3/007: Addition polymers - D04H 3/013: Regenerated cellulose series - D04H 3/018: characterised by the shape - D04H 3/02: characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments - D01F 2/02: from solutions of cellulose in acids, bases or salts - D01F 11/02: of cellulose, cellulose derivatives, or proteins - D04H: MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL (weaving D03; knitting D04B; braiding D04C; net-making D04G; sewing D05B; tufting D05C; finishing non-woven fabrics D06); FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING {; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION}(non-woven fabrics having an intermediate or external layer of a different kind, e.g. of woven fabric, B32B) - D01D: MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS - D01F: CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS ## Abstract Functional spunlaid fabrics incorporating fibers made from non-meltable polymers containing permanently one or more functional additives are provided. The fibers are entangled and interlocked to form a firm nonwoven composite, have different lengths, and aspect ratios above 1,000. The fibers have a mean diameter of 0.1 to 500 micrometres and diameter variations within a single fiber and among each other of at least 30%. The fibers contain more than 40 wt % of finely distributed functional additives in solid and/or liquid form. The spunlaid fabric is produced from a spinning solution containing the non-meltable polymer dissolved in a direct solvent and at least one functional additive. The spinning solution is extruded out of a spinneret, and the resulting strands are drawn in the longitudinal direction to form fibers, stabilized and laid down to form a nonwoven fabric with permanent functional properties. Exemplary spunlaid fabrics include clothing, technical textiles and filters. ## Claims ### Claim 1 A spunlaid nonwoven comprising fibers formed from nonmeltable cellulose polymer as fiber-forming material containing one or more functional additives and providing permanent functional properties, wherein the fibers are intertwined and entangled, have differing lengths, have aspect ratios above 1000 and form an interbonded nonwoven, the fibers have an average diameter of 0.1 to 500 micrometers and also random diameter fluctuations of at least 30% within any one fiber as well as between fibers and the fibers in addition to the nonmeltable cellulose polymer contain permanently more than 40 wt %, based on total fiber weight, of functional additives in solid and/or liquid form that are finely distributed within the cross-section of the fibers and which are enclosed by the cellulose polymer matrix material. ### Claim 2 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the nonwoven comprises fibers having different, random lengths in comparison to each other and fibers having broken ends. ### Claim 3 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the functional additives are lipophilic substances, activated carbon, superabsorbent polymers, ion exchange resins, metal oxides, ceramics, abrasives, zeolites, layered silicates, or mixtures thereof. ### Claim 4 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the nonmemeltable cellulose polymer binding the functional additives is a solution-formable polymer and the polymer is insoluble in water. ### Claim 5 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the volume fraction of the additives is ≥50% in the dried fibers. ### Claim 6 (depends on 1) The spunlaid nonwoven as claimed in claim 1, Wherein said nonwoven has a weight per unit area of 2 to 1000 g/m2. ### Claim 7 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein said nonwoven has a thickness of 0.01 to 20 mm. ### Claim 8 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the fraction of functional additives is up to 96 wt %, based on total fiber weight and the additives are incorporated in the fibers permanently. ### Claim 9 (depends on 2) The spunlaid nonwoven as claimed in claim 2, wherein the functional additives are activated carbon, superabsorbents, ion exchange resins, piezoelectric materials, phase change materials, metal oxides, flame retardants, abrasives, zeolites, sheet-silicates, modified sheet-silicates and/or cosmetics. ### Claim 10 (depends on 2) The spunlaid nonwoven as claimed in claim 2, wherein the functional lipophilic additives are paraffins. ### Claim 11 (depends on 1) A process for producing a high-functionality spunlaid nonwoven as claimed in claim 1, comprising extruding a spinning solution comprising more than 40 wt % of one or more functional additives, solvent and dissolved polymer through a spinneret die, the die having holes with a diameter of 0.1 to 1.5 mm, to form polymeric strands; drawing the resulting polymeric strands into fibers, said drawing commencing immediately upon leaving the die, said drawing effected by an obliquely downwardly directed blowing stream the intensity of which is adapted to the reduced thread-drawing capacity of the spun mixture due to the functional additives, in addition to the air stream the strands are blown or sprayed on by a non-solvent starting at a distance between 5 to 20 mm, said drawing performed within a short path, in the longitudinal direction, subsequently stabilizing the drawn fibers upon transitioning into a tensionless space, even before the onset of longitudinal relaxation, said fibers stabilized in their shape via a stream of temperature-controlled air and fine droplets of a non-solvent by consolidation/gelation and partial replacement of the solvent with the non-solvent, wherein in spatial terms the stabilization can take place more or less offset to the die exit and gel-state fibers are obtained, forming a nonwoven by laying down the stabilized fiber on a foraminous belt or drum, rinsing out the remaining solvent by repeated washing and optionally drying the nonwoven wherein the solvent is a direct solvent for the polymer, and the solvent is selected from N-methylmorpholine N-oxide, N-methylmorpholine N-oxide monohydrate, ionic liquids or mixtures thereof. ### Claim 12 (depends on 11) The process as claimed in claim 11, wherein the high-functionality spunlaid nonwoven is further consolidated, refined and formed by textile processes, and the consolidating and refining of the nonwoven is effected before or after drying. ### Claim 13 (depends on 11) The process as claimed in claim 11, wherein the high-functionality spunlaid nonwoven is stabilized by needling or water jet consolidation and/or additionally subjected to chemical crosslinking. ### Claim 14 (depends on 1) Apparel textiles or industrial textiles comprising a spunlaid nonwoven as claimed in claim 1. ### Claim 15 (depends on 14) Apparel textiles or industrial textiles as claimed in claim 14, wherein the apparel textiles are interlinings, and the industrial textiles are hygiene textiles, wound dressings, carrier materials for active ingredients, carrier materials for composites, building material, transportation material, cosmetic material, electrical conductive material, polishing material or filters. ### Claim 16 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the random, non-uniform diameter fluctuations are down the length of the fiber, and the cellulose is formed using a direct solvent selected from N-methylmorpholine N-oxide, N-methyimorpholine N-oxide monohydrate, ionic liquids or mixtures thereof. ### Claim 17 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein said fibers have a roughened surface with crevices. ### Claim 18 (depends on 1) The spunlaid nonwoven as claimed in claim 1, wherein the function is electrical conductivity, absorption, ion exchange, temperature regulation, abrasion and combinations thereof.