# US 10,501,675 B2 · Fluid loss additive for water based drilling fluids with improved thermal stability

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- Number: US 10,501,675 B2
- Document ID: US10501675B2
- Status: Granted
- Kind: B2
- Application number: 16/222,575
- Filed: 2018-12-17
- Published: 2019-04-25
- Granted: 2019-12-10
- Earliest claimed: 2018-12-17
- Assignees: Halliburton Energy Services, Inc.
- Applicants: Halliburton Energy Services, Inc.
- Inventors: Weibin Zha; Hui Zhou
- Web page: https://patentgrep.com/patent/US10501675B2

## CPC

- C09K 8/035: Organic additives
- C08F 291/00: Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C09K 8/508: macromolecular compounds {(C09K8/512 takes precedence)}
- C09K 8/516: characterised by their form or by the form of their components, e.g. encapsulated material
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

## Abstract

A polymer microsphere for use as a fluid loss additive in drilling muds including a hydrophobic core of hydrophobic monomers and a hydrophilic shell of hydrophilic monomers wherein the hydrophilic shell surrounds the hydrophobic core. The polymer microsphere is capable of forming micelles or microgels in water without using surfactants and can be block, graft, and random copolymers. The hydrophilic shell is physically or chemically linked to the hydrophobic core. The polymer microsphere further includes crosslinkers, preferably where the crosslinkers are monomers containing at least two ethylenically unsaturated groups.

## Claims

### Claim 1

A method of using a plurality of self-dispersible polymer microspheres as fluid loss additives, which comprises the step of introducing the self-dispersible polymer microspheres into a drilling mud; where each self-dispersible polymer microsphere comprises:
a hydrophobic core of hydrophobic monomers; and
a hydrophilic shell of hydrophilic monomers;
wherein the hydrophilic shell surrounds the hydrophobic core; and
wherein the polymer microsphere is formed in water without addition of an emulsifier and disperses in water without the need for an emulsifier.

### Claim 2 (depends on 1)

The method of claim 1 wherein the self-dispersible polymer microspheres are free of surfactants.

### Claim 3 (depends on 1)

The method of claim 1 wherein the hydrophilic shell has a weight of between about 10% to about 90% by weight of the self-dispersible polymer microspheres.

### Claim 4 (depends on 1)

The method of claim 1 wherein each self-dispersible polymer microsphere has a particle size of between about 0.01 to about 1000 microns.

### Claim 5 (depends on 1)

The method of claim 1 wherein each self-dispersible polymer microsphere is selected from the group consisting of block, graft, and random copolymers.

### Claim 6 (depends on 1)

The method of claim 1 wherein the hydrophilic shell is physically or chemically linked to the hydrophobic core of each self-dispersible polymer microsphere.

### Claim 7 (depends on 1)

The method of claim 1 wherein the hydrophobic monomers comprises one of styrene, substituted styrene, alkyl acrylate, alkyl methacrylate, acrylonitrile, methacrylonitrile, N-alkyl acrylamide, N-alkyl methacrylamide, vinyl acetate, vinyl esters, N-vinylamides, isoprene, butadiene, diesters of maleic, fumaric, or itaconic acid.