# US 10,501,402 B2 · Multifunctional acrylic ether-ester products modified with carboxylic anhydride or its polyacid form, process for preparing same and associated crosslinkable compositions > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,501,402 B2 - Document ID: US10501402B2 - Status: Granted - Kind: B2 - Application number: 15/523,129 - Filed: 2015-10-13 - Published: 2017-12-14 - Granted: 2019-12-10 - Earliest claimed: 2014-10-29 - Assignees: Arkema France - Applicants: Arkema France - Inventors: Guillaume P. Monnier; Philippe Ciceron; Catherine M. Leroy; Charles Bourrousse - Web page: https://patentgrep.com/patent/US10501402B2 ## CPC - C07C 69/80: Phthalic acid esters - C07C 67/29: by introduction of oxygen-containing functional groups - C08F 122/1006: {of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate} - C08G 63/676: in which at least one of the two components contains aliphatic unsaturation - C09D 4/06: {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00 - C08F 222/1061: {of alcohol terminated polyesters or polycarbonates, e.g. polyester (meth)acrylates} - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS - C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS - C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) ## Abstract The invention relates to a multifunctional acrylic product having a number-average functionality f of acrylate groups greater than 2.1, which is the product of reaction by esterification and by etherification, via Michael addition reaction, between a) a polyol or a mixture of polyols R(OH)m having a functionality m of at least 3 for a polyol alone or having an average functionality greater than 2.1 for a mixture of polyols, and b) the acrylic acid (R1OH) in the presence of c) at least one cyclic polycarboxylic anhydride or of its polyacid form having a carboxy functionality z of at least 2 and up to 4, the ratio r1 of number of carboxy groups of said anhydride or polyacid c) with respect to those of the acrylic acid b) r1=CO2Hc/CO2Hb being from 0.01 to 0.4 with overall r=CO2H/OH<1, said acrylic product comprising in its composition both: units A) of oligoether-ester acrylate that are derived from a) and b) and units B) of oligoester acrylate that are derived from c), said acrylic product being a mixture of acrylic products comprising at least one acrylic product p1 chemically linking, in its molecular structure, the two types of units A) and B) as defined above. The invention also relates to a process for preparing said product, to crosslinkable compositions comprising same and to the use thereof in coatings, sealing, moulding or composite compositions, chemical sealing compositions, 3D printing compositions or compositions for 3D objects produced layer-by-layer. One particular advantage of these compositions is their low shrinkage despite their high functionality. ## Claims ### Claim 1 Multifunctional acrylated product having a number-average functionality f greater than 2.1 acrylic groups per mole of said product and with a density of said acrylic groups DA ranging from 2 to 12 mmol per g of said product, said product being the product of reaction by esterification and by etherification, by Michael addition reaction, between: a) a polyol R(OH)m or a mixture of polyols R(OH)m, of functionality m of at least 3 for a single polyol present and a number-average OH functionality greater than 2.1 for a mixture of said polyols, and b) the acrylic acid represented by R1OH, said reaction between a) and b) taking place in the presence of c) at least one cyclic carboxylic anhydride or of its polycarboxylic acid form R2(CO2H)z, of carboxy group (—CO2H) functionality z of at least 2 and ranging up to 4: the ratio r1 of number of carboxy groups of said anhydride c) relative to those of b) acrylic acid, r1=(CO2H)c/(CO2H)b ranging from 0.01 to 0.4, the carboxy groups being overall in stoichiometric deficit relative to the hydroxyl groups of said polyol a), with r=CO2H/OH<1, wherein: R is the residual radical of a polyol of valency m or a mixture of polyols of valency m; R1 is an acryloyl radical; and R2 is the residue of valency z of said at least one cyclic carboxylic anhydride or of its polycarboxylic acid form; said acrylic product comprising in its composition both: units A) of oligoether-ester acrylate that are derived from the reaction of a) and of b), formed by a Michael addition reaction: of the OH groups of said polyol a) or of OH groups of hydroxylated partial acrylates formed on the unsaturation of the acrylic acid b) or on the unsaturation of one of the acrylates formed by esterification with b) and simultaneous esterification with b) of said polyol a) and of said b hydroxylated partial acrylates or simultaneous esterification with the carboxy groups of the carboxylated Michael adduct formed between a) and b), and units B) of oligoester acrylates derived from c) by a reaction of esterification with said anhydride or with its polyacid form c) of said polyol a) or of said hydroxylated partial acrylates or of the hydroxylated ether-ester acrylates formed, said acrylic product being a mixture of acrylic products comprising at least one acrylic product (p1) chemically linking, in its molecular structure, the units A) and B) as defined above, wherein the product has an overall composition represented by the following average general formula (I): R1O-[[A]a-[B]b]n—R(OR1)m-1 (I) with a and b representing the average mole fraction of each unit A) and B) per overall average unit of said product and with a+b=1 and a/b ranging from 0.15 to 22, n being the number of repeat overall units, with average n per mole of product nave ranging from 0.2 to 10. ### Claim 2 (depends on 1) The product of claim 1, wherein the product comprises said product p1 and that said product p1 has a molecular structure defined according to general formula (II) below: (R1O)m-1—R—[—[O—CH2CH2—CO2—R(OR1)m-2]a[O2C—R2(CO2X)z-2—CO2—R(OR1)m-2]b]n—OR1 (II) and with the presence of at least four products having a different n, corresponding to n=0 and n=1, n=2 and n=3 with: R1 being the acryloyl radical, R being the residual radical of said polyol R(OH)m or representing an average radical of a mixture of polyols, R2 being the residue of valency z of said anhydride or its polycarboxylic acid form and X being —R(OR1)m-1 with X possibly being more than 95%, —R(OR1)m-1 and the rest less than 5% of X being H, with an acid number not exceeding 15 mg KOH/g, n being the number of repeat units and a and b being the respective mole fractions of the particular units in the overall repeat unit with the ratio a/b ranging from 0.15 to 22. ### Claim 3 (depends on 1) The product of claim 1 wherein it comprises, in addition to said product p1, the oligoether-ester acrylate product p2 based on units A) of general formula (III) below: (R1O)—[—R[OR1]m-2—O—(C═O)—CH2—CH2—O—]n—R—(OR1)m-1 (III) with the presence of at least four products having a different n and corresponding to n=0 and n=1, n=2 and n=3 and n being the number of repeat units. ### Claim 4 (depends on 1) The product of claim 1 wherein it comprises, in addition to said product p1, the oligoester acrylate product p3 of general formula (IV) below: (R1O)—[—R[OR1]m-2—O—(C═O)—R2(C═O)O—]n—R—(OR1)m-1 (IV) with the presence of at least four products having a different n and corresponding to n=0 and n=1, n=2 and n=3 and n being the number of repeat units. ### Claim 5 (depends on 2, 3, 4) The product of claim 4, wherein it comprises a product p2 as defined according to formula (III) of claim 3, said product p1 is as defined according to formula (II) of claim 2 and the three products p1, p2 and p3 thus defined each comprise at least a fifth product corresponding to n=4 and, optionally, an additional product corresponding to n=5. ### Claim 6 (depends on 1, 2, 3, 4, 5) The product of claim 1 to 5, wherein said product p1 has the following general formula (V): (R1O)—[—R[OR1]m-2—O2C—CH2—CH2—O—]n—R—(OR1)m-2—O2C—R2(CO2—X1)z-2—CO2—X2 (V) with R2 being the radical having valency z corresponding to said carboxylic anhydride or to said polycarboxylic acid and X1 and X2 possibly being identical or different and chosen from: —R(OR1)m-1 or —R(OR1)m-2—[O—CH2—CH2—CO2—R(OR1)m-2]n—(OR1) or in part H or in part the residue of a reactive blocking agent chosen from a monofunctional reactive blocking agent, reactive with the carboxy group. ### Claim 7 (depends on 1) The product of claim 1 wherein the overall molecular distribution in terms of n of said product is such that it represents at least 80% by weight for n ranging from 0 to 4 and no more than 20% by weight of said distribution for n being greater than 4, with a number-average weight Mn of said product, measured by GPC in THF and expressed in polystyrene equivalents, ranging from 500 to 10000. ### Claim 8 (depends on 1) The product of claim 1 wherein said polyol a) has a functionality m for polyol a) alone of at least 3 and that said product comprises linear oligoether-ester acrylate products p2 according to general formula (III) and also at least one oligoether-ester acrylate product of branched structure. ### Claim 9 Acrylated product, wherein it can be obtained by simultaneous or successive and alternating reactions between a) a polyol R(OH)m or a mixture of polyols R(OH)m, having a functionality m of at least 3 for a polyol a) alone, or having a number-average functionality with respect to m greater than 2.1 for a mixture of polyols R(OH)m and b) the acrylic acid (R1OH) in stoichiometric deficit relative to a), and in the presence of c) at least one cyclic carboxylic anhydride or of its polyacid form having a carboxy group functionality z ranging from 2 to 4, with an overall ratio r=CO2H/OH of less than 1 with r1 being the ratio of the carboxy groups of c) to the carboxy groups of b) acrylic acid, r1=(carboxy)c/(carboxy)b, wherein R is the residual radical of a polyol of valency m or a mixture of polyols of valency m and R1 is an acryloyl radical. ### Claim 10 (depends on 1) The product of claim 1 wherein said polyol a) is selected from polyol monomers and/or polyol oligomers with Mn for polyol oligomers not exceeding 700. ### Claim 11 (depends on 10) The product of claim 10, wherein said polyol is a polyol monomer and selected from: diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, butanediol, neopentyl glycol, hexanediol, isosorbide, glycerol, trimethylolpropane, pentaerythritol, ditrimethylolpropane, erythritol, xylitol, dipentaerythritol and sorbitol, including the alkoxylated derivatives of the polyols mentioned. ### Claim 12 (depends on 10) The product of claim 10, wherein said polyol is a polyol oligomer chosen from polyether polyols, polyester polyols, and hydroxylated acrylic oligomers which are optionally alkoxylated. ### Claim 13 (depends on 1) The product of claim 1 wherein, in addition to said polyol a) having a functionality of at least 3, a second polyol different from the first and having a functionality of at least 2 is present, this second polyol being an oligoester diol, optionally comprising, as component in its repeat unit, said anhydride c) or its polyacid form. ### Claim 14 (depends on 1) The product of claim 1 wherein said polycarboxylic anhydride c) or its polyacid form or isomer of the latter is chosen from aromatic or cycloaliphatic or aliphatic polycarboxylic anhydrides or polycarboxylic acids, with the cycloaliphatic or aliphatic structures possibly being unsaturated. ### Claim 15 (depends on 14) The product of claim 14, wherein said polycarboxylic anhydride or polyacid or said isomer of the latter is aromatic and in particular selected from: (o-) phthalic anhydride, iso- or terephthalic acid, naphthenic anhydride or acid, trimellitic anhydride or acid, pyromellitic anhydride or pyromellitic acid. ### Claim 16 (depends on 14) The product of claim 14, wherein said anhydride or its polyacid form is cycloaliphatic and selected from tetrahydrophthalic anhydride and acid, dihydrophthalic anhydride and acid, nadic (bicyclo (2,2,1) hept-5-ene-2,3-dicarboxylic) anhydride and acid or cyclohexanedicarboxylic anhydride and acid. ### Claim 17 (depends on 14) The product of claim 14, wherein said anhydride or acid is aliphatic and chosen from: maleic anhydride and acid, fumaric acid, itaconic anhydride and acid, and succinic anhydride and acid. ### Claim 18 (depends on 14) The product of claim 14, wherein said anhydride or acid is chosen from: (o-) phthalic anhydride, iso- or terephthalic acid, tetrahydrophthalic anhydride and acid, dihydrophthalic anhydride and acid, nadic anhydride and acid, maleic anhydride and acid, fumaric acid, itaconic anhydride and acid, and succinic anhydride and acid. ### Claim 19 (depends on 1) The product of claim 1 wherein said anhydride or polyacid is a mixture of at least two anhydrides or polyacids c). ### Claim 20 (depends on 1) Process for preparing the product of claim 1, comprising: i) mixing in a reactor of said polyol a), of the acrylic acid b) and of said anhydride or of said polyacid c) in proportions such that the overall mole ratio r=CO2H/OH is less than 1, with r1=(CO2H)c/(CO2H)b being in the range of from 0.01 to 0.4 and in the presence of an acidic esterification catalyst and of a solvent forming an azeotrope with water, to form the reaction mixture, followed by ii) refluxing said reaction mixture, with simultaneous or successive and alternating reactions of esterification, by reaction of the acrylic acid b) and/or of said anhydride or polyacid c) with a hydroxyl of said polyol a) with formation of hydroxylated acrylate esters, and of etherification, via Michael addition reaction of a hydroxyl of said polyol or of formed hydroxylated acrylate, to an acrylate group and/or the acrylic acid b), and of esterification of the hydroxyl groups of said polyol and of said hydroxylated acrylates by said anhydride or diacid and gradual removal of the esterification water, with iii) continuation of the reaction until complete consumption of the OH functions meaning IOH<20 mg KOH/g by Michael addition reactions and esterification reactions with said acrylic acid b) and said anhydride or diacid c), iv) neutralization of said acidic catalyst before recovery of the final product, by removal of said solvent, without any other purification step required. ### Claim 21 (depends on 20) A composition obtained by means of a process as defined according to claim 20. ### Claim 22 (depends on 21) The composition of claim 21, wherein, in the case where the calculated Mn of said product is greater than 1000, in addition to said product, the composition comprises at least one reactive diluent, selected from acrylic monomers. ### Claim 23 (depends on 21) The composition of claim 21 wherein the composition is capable to be crosslinked via radiation, by UV radiation in the presence of a photoinitiating system or by an electron beam (EB) in the absence of a photoinitiating system and/or by a thermal radical initiating system, and/or by Michael addition (M-cure) or by a mixed system. ### Claim 24 (depends on 21) The composition of claim 21 wherein the composition is a pigmented or non-pigmented coating composition or is a moulding composition or a sealing composition or a composite composition or a chemical sealing composition or a 3D printing composition or a composition for 3D objects produced layer-by-layer. ### Claim 25 (depends on 20) Crosslinked final product chosen from crosslinked pigmented or non-pigmented coatings, or chosen from moulded parts, seals, composites, chemical seals, 3D printing or 3D objects produced layer-by-layer, obtained by the process of claim 20.