# US 10,501,372 B2 · Two-component mortar mass and use thereof

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- Number: US 10,501,372 B2
- Document ID: US10501372B2
- Status: Granted
- Kind: B2
- Application number: 15/323,318
- Filed: 2015-07-30
- Published: 2018-06-21
- Granted: 2019-12-10
- Earliest claimed: 2014-07-31
- Assignees: Hilti Aktiengesellschaft
- Applicants: Hilti Aktiengesellschaft
- Inventors: Anna Sharmak; Armin Pfeil; Beate Gnass; Memet-Emin Kumru; Jens Bunzen
- Web page: https://patentgrep.com/patent/US10501372B2

## CPC

- C04B 28/06: Aluminous cements (monolithic refractories or refractory mortars C04B35/66)
- C04B 24/00: Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B 26/32: containing silicon
- C04B 40/065: {Two or more component mortars}
- C08F 220/20: of polyhydric alcohols or phenols {, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate}
- C08F 220/281: {and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate}
- C08F 2800/20: as weight or mass percentages
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

## Abstract

A two-component mortar mass comprises a resin component (A), which contains at least one radically curable resin as a curable constituent, and a curing component (B), which contains a curing agent for the radically curable resin of the resin component (A). The radically curable resin can be obtained by reaction of an at least difunctional isocyanate with a hydroxy-functional silane and a hydroxy-functional, ethylenically unsaturated compound. The hydroxy-functional silane is the reaction product of a cyclic compound from the group of cyclic carbonates, lactones, and carbamates with a silane compound selected from the group of amino-functional, hydroxy-functional or mercapto-functional silanes.

## Claims

### Claim 1

A two-component mortar mass, comprising:
a resin component (A), which contains at least one radically curable resin as a curable constituent; and
a curing component (B), which contains a curing agent for the radically curable resin of the resin component (A);
wherein the radically curable resin is obtained by reaction of
an at least difunctional component, which has two or more reactive groups (RG-A),
with a silane intermediate compound and
an ethylenically unsaturated compound,
wherein the silane intermediate compound and the ethylenically unsaturated compound each have active functional groups (AG) that react with the reactive groups (RG-A), causing the formation of a covalent bond,
wherein the silane intermediate compound is the reaction product of a cyclic organic compound selected from the group consisting of a cyclic anhydride, a cyclic carbonate, a cyclic thiocarbonate, a cyclic carbamate, a cyclic thiocarbamate, a cyclic urea, a lactone, a lactam and combinations thereof with a functionalized silane compound, which has at least one reactive group (RG-B),
wherein the cyclic organic compound reacts with the reactive group (RG-B) of the functionalized silane compound, causing the formation of the silane intermediate compound having at least one functional active group selected from the group consisting of a carboxyl group, a hydroxy group and an amino group, and
wherein the silane intermediate compound is reacted in a proportion of at least about 2 wt. % of the resin component (A), with reference to organic constituents of the resin component (A).

### Claim 2 (depends on 1)

The two-component mortar mass according to claim 1, wherein the reactive groups (RG-A) are present at most in a stoichiometric ratio relative to the active groups (AG).

### Claim 3 (depends on 1)

The two-component mortar mass according to claim 1, wherein the reactive groups (RG-A) are selected from the group consisting of carboxyl groups, isocyanate groups, oxirane groups, imido groups and combinations thereof.

### Claim 4 (depends on 1)

The two-component mortar mass according to claim 1 wherein the active groups (AG) are selected from the group consisting of carboxyl groups, hydroxy groups, amino groups, thio groups and combinations thereof.

### Claim 5 (depends on 1)

The two-component mortar mass according to claim 1, wherein the functionalized silane compound is a hydroxy silane, mercapto silane, an aminosilane or a mixture thereof.

### Claim 6 (depends on 1)

The two-component mortar mass according to claim 1, wherein the functionalized silane compound carries a Si-bound hydrolyzable group.

### Claim 7 (depends on 1)

The two-component mortar mass according to claim 1, comprising:
the resin component (A), which contains at least one radically curable resin as the curable constituent; and
the curing component (B), which contains a curing agent for the radically curable resin of the resin component (A);
wherein the radically curable resin is obtained by reaction of an at least difunctional isocyanate with a hydroxy-functional silane and a hydroxy-functional, ethylenically unsaturated compound,
wherein the hydroxy-functional silane is the reaction product of at least one cyclic compound selected from the group consisting of cyclic carbonates, lactones, and carbamates, with at least one silane compound selected from the group consisting of amino-functional, hydroxy-functional and mercapto-functional silanes, and
wherein the proportion of the hydroxy-functional silane compound reacted in the resin component (A) amounts to at least 2 wt. %, with reference to the total weight of organic constituents of the resin component (A).

### Claim 8 (depends on 7)

The two-component mortar mass according to claim 7, wherein the at least difunctional isocyanate reacted is selected from the group consisting of aliphatic and aromatic isocyanates, isocyanate prepolymers and mixtures thereof.

### Claim 9 (depends on 7)

The two-component mortar mass according to claim 7, wherein the hydroxy-functional, ethylenically unsaturated compound reacted is a (meth)acrylic acid ester, containing hydroxyl groups, of two or more multivalent alcohols.

### Claim 10 (depends on 7)

The two-component mortar mass according to claim 7, wherein the cyclic compound is reacted with an amino-functional silane compound that contains a primary or secondary amino group.

### Claim 11 (depends on 7)

The two-component mortar mass according to claim 7, wherein the cyclic compound is a cyclic carbonate.

### Claim 12 (depends on 7)

The two-component mortar mass according to claim 7, wherein the hydroxy-functional silane corresponds to the following Formula (I):
in which m is 0, 1 or 2,
R1 is an alkyl radical with 1 to 4 carbon atoms,
R2 is an alkyl radical with 1 to 4 carbon atoms,
R3 is a divalent organic radical with 1 to 10 atoms, selected from C, N, S and/or O in the chain,
X means O, NR4 or S,
wherein R4 is a hydrogen atom or an alkyl radical with 1 to 10 carbon atoms, and
R is a difunctional organic group.

### Claim 13 (depends on 12)

The two-component mortar mass according to claim 12, wherein R3 possesses a meaning indicated in the following Formula (II):
in which n is a whole number between 1 and 6,
Q stands for a covalent bond, 0 or NR4, and
R4 and R5, independently of one another, are a hydrogen atom or an alkyl radical with 1 to 10 carbon atoms.

### Claim 14 (depends on 7)

The two-component mortar mass according to claim 7, wherein the molar ratio of the isocyanate groups to the hydroxy groups of the hydroxy-functional silane is in the range of 23:1 to 3.5:1.

### Claim 15 (depends on 7)

The two-component mortar mass according to claim 7, wherein the proportion of the hydroxy-functional silane compound reacted in the resin component (A) amounts to 2 to 7 wt. %, with reference to a total weight of the organic constituents of the resin component (A).

### Claim 16 (depends on 1)

The two-component mortar mass according to claim 1, wherein the radically curable resin is obtained by reaction of an at least difunctional epoxy with the silane intermediate compound and a carboxy-functional ethylenically unsaturated compound.

### Claim 17 (depends on 1)

The two-component mortar mass according to claim 1, wherein the resin component (A) contains at least one reactive diluent as a further constituent.

### Claim 18 (depends on 1)

The two-component mortar mass according to claim 1, wherein the resin component (A) contains at least one accelerator as a further constituent.

### Claim 19 (depends on 1)

The two-component mortar mass according to claim 1, wherein the resin component (A) and/or the curing component (B) contains at least one inorganic filler as a further constituent.

### Claim 20 (depends on 1)

The two-component mortar mass according to claim 1, wherein the resin component (A) contains a hydraulically binding or polycondensable inorganic compound as a further constituent.

### Claim 21 (depends on 1)

The two-component mortar mass according to claim 1, wherein the curing component (B) contains at least one organic peroxide as a curing agent.

### Claim 22 (depends on 1)

The two-component mortar mass according claim 1 wherein at least one component of said two-component mortar mass is located in at least one of a shell, a cartridge or a film bag, wherein the resin component (A) and the curing component (B) are disposed in chambers separated from one another.

### Claim 23 (depends on 1)

A method for fastening a part, said method comprising:
chemically fastening of said part in a drilled hole which is present in a mineral substrate with the two-component mortar mass according to claim 1,
wherein said part is selected from the group consisting of threaded anchor rods, iron reinforcement bars, threaded sleeves, and screws.