Method and device for regeneration of hydrochloric acid
AssigneeAndritz Inc.
InventorFrank Barhold
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Abstract
The subject matter of the present invention is a method to extract or recover hydrochloric acid from hydrochloric acid solutions containing metal by means of pyrohydrolytic treatment, followed by absorption and/or condensation of the gaseous hydrogen chloride thus formed in order to form hydrochloric acid. According to the invention, a first partial flow of the hydrochloric acid solution containing metal undergoes pyrohydrolytic treatment and a second partial flow of the metal-containing solution is fed to the absorption column. A device for implementing the process according to the invention is also the subject of the present invention.
Claims10
Method to extract or recover hydrochloric acid from hydrochloric acid solutions containing metal by means of spray roasting followed by one or both of absorption and condensation of gaseous hydrogen chloride thus formed in order to form hydrochloric acid, comprising
- providing an initial flow of hydrochloric acid solution containing metal;
- splitting the flow of the hydrochloric acid solution containing metal into a first partial flow and a second partial flow of hydrochloric acid solution containing metal;
- feeding the first partial flow of hydrochloric acid solution containing metal to a spray roaster to undergo pyrohydrolytic treatment, which releases gases;
- directly contacting the gases released from the pyrohydrolytic treatment with the hydrochloric acid solution containing metal, thereby cooling the gases released from the pyrohydrolytic treatment and concentrating the hydrochloric acid solution containing metal;
- feeding the second partial flow of hydrochloric acid solution containing metal directly to an absorption column without undergoing pyrohydrolytic treatment, thereby increasing a concentration of metal in the hydrochloric acid solution containing metal, wherein
- at least one of the initial flow or the first partial flow of hydrochloric acid solution containing metal is concentrated by evaporation such that the first partial flow of hydrochloric acid solution containing metal fed to the spray roaster for pyrohydrolytic treatment is a concentrated solution.
Dependencies are inferred from the claim text.