Back to results
US 10,487,065 B2Granted
Polymerizable compound, polymerizable composition, polymer, optically anisotropic body, and method for producing polymerizable compound
AssigneeZeon Corporation
InventorsKei Sakamoto, Satoshi Kiriki, Kumi Okuyama, Kanako Taira
Life of this patent
Estimating the term…
Abstract
A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article.
Claims1
A method for producing a polymerizable compound represented by a formula (I), the method comprising reacting a carbonyl compound represented by a formula (4),
- wherein Y1 to Y8 are independently a chemical single bond, —O—, —S—, —O—C(═O)—, —C(═O)—O—, —O—C(═O)—O—, —NR1—C(═O)—, —C(═O)—NR1—, —O—C(═O)—NR1—, —NR1—C(═O)—O—, —NR1—C(═O)—NR1—, —O—NR1—, or —NR1—O—, R1 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- G1 and G2 are independently a substituted or unsubstituted divalent linear aliphatic group having 1 to 20 carbon atoms that optionally includes —O—, —S—, —O—C(═O)—, —C(═O)—O—, —O—C(═O)—O—, —NR2—C(═O)—, —C(═O)—NR2—, —NR2—, or —C(═O)—, provided that a case where the aliphatic group includes two or more contiguous —O— or —S— is excluded, R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- Z1 and Z2 are independently an alkenyl group having 2 to 10 carbon atoms that is unsubstituted, or substituted with a halogen atom,
- A1 is a substituted or unsubstituted trivalent aromatic group,
- A2 and A3 are independently a substituted or unsubstituted divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms,
- A4 and A5 are independently a substituted or unsubstituted divalent aromatic group having 6 to 30 carbon atoms, and
- Q1 is a hydrogen atom, or a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms,
- with a hydrazine compound represented by the following formula,
- wherein Ax is an organic group having 3 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and a heteroaromatic ring,
- Ay is a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 12 carbon atoms, —C(═O)—R3, —SO2—R4, —C(═S)NH—R9, or an organic group having 3 to 30 carbon atoms that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and a heteroaromatic ring, R3 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 12 carbon atoms, or an aromatic hydrocarbon group having 5 to 12 carbon atoms, R4 is an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, a phenyl group, or a 4-methylphenyl group, R9 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 12 carbon atoms, or a substituted or unsubstituted aromatic group having 5 to 20 carbon atoms, provided that the aromatic ring included in Ax and Ay is substituted or unsubstituted, and
- Ax and Ay are optionally bonded to each other to form a ring,
- wherein Ax and Ay are the same as defined above,
- Y1 to Y8 are independently a chemical single bond, —O—, —S—, —O—C(═O)—, —C(═O)—O—, —O—C(═O)—O—, —NR1—C(═O)—, —C(═O)—NR1—, —O—C(═O)—NR1—, —NR1—C(═O)—O—, —NR1—C(═O)—NR1—, —O—NR1—, or NR1—O—, R1 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- G1 and G2 are independently a substituted or unsubstituted divalent linear aliphatic group having 1 to 20 carbon atoms that optionally includes —O—, —S—, —O—C(═O)—, —C(═O)—O—, —O—C(═O)—O—, —NR2—C(═O)—, —C(═O)—NR2—, —NR2—, or —C(═O)—, provided that a case where the aliphatic group includes two or more contiguous —O— or —S— is excluded, R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- Z1 and Z2 are independently an alkenyl group having 2 to 10 carbon atoms that is unsubstituted, or substituted with a halogen atom,
- A1 is a substituted or unsubstituted trivalent aromatic group,
- A2 and A3 are independently a substituted or unsubstituted divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms,
- A4 and A5 are independently a substituted or unsubstituted divalent aromatic group having 6 to 30 carbon atoms, and
- Q1 is a hydrogen atom, or a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms.
16 more elements
Dependencies are inferred from the claim text.