# US 10,483,298 B2 · Multi-sensor optical device for detecting chemical species and manufacturing method thereof

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- Number: US 10,483,298 B2
- Document ID: US10483298B2
- Status: Granted
- Kind: B2
- Application number: 15/583,750
- Filed: 2017-05-01
- Published: 2017-08-17
- Granted: 2019-11-19
- Earliest claimed: 2014-04-24
- Assignees: STMicroelectronics S.r.l.
- Applicants: Stmicroelectronics S.R.L.
- Inventors: Massimo Cataldo Mazzillo; Alfio Russo
- Web page: https://patentgrep.com/patent/US10483298B2

## CPC

- H10F 39/103: {the at least one element covered by H10F30/00 having potential barriers, e.g. integrated devices comprising photodiodes or phototransistors}
- G01N 21/05: Flow-through cuvettes (G01N21/09 takes precedence; handling fluid samples G01N1/10)
- G01N 21/31: Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry {(G01N21/72 takes precedence)}
- G01N 21/314: {with comparison of measurements at specific and non-specific wavelengths (dual wavelength spectrometry G01J3/427)}
- G01N 21/61: Non-dispersive gas analysers {(G01N21/3504 takes precedence)}
- G01N 21/85: Investigating moving fluids or granular solids
- H10F 30/2218: {the devices comprising active layers made of only Group IV-VI materials}
- H10F 30/227: the potential barrier being a Schottky barrier
- H10F 71/1215: {comprising at least two Group IV elements, e.g. SiGe}
- H10F 77/1226: comprising multiple Group IV elements, e.g. SiC
- H10F 77/331: {for filtering or shielding light, e.g. multicolour filters for photodetectors}
- G01M 15/108: {using optical methods}
- G01N 21/33: using ultraviolet light (G01N21/39 takes precedence)
- G01N 2021/3137: {with selection of wavelengths after the sample}
- G01N 2021/8578: {Gaseous flow}
- G01N 2201/0612: Laser diodes
- H10F 30/2215: {the devices comprising active layers made of only Group III-V materials}
- Y02E 10/50: Photovoltaic [PV] energy
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- G01M: TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An optical device for detecting a first chemical species and a second chemical species contained in a specimen, which includes: a first optical sensor, which may be optically coupled to an optical source through the specimen and is sensitive to radiation having a wavelength comprised in a first range of wavelengths; and a second optical sensor, which may be optically coupled to the optical source through the specimen and is sensitive to radiation having a wavelength comprised in a second range of wavelengths, different from the first range of wavelengths.

## Claims

### Claim 1

A device, comprising:
a substrate;
a semiconductor layer on the substrate, the semiconductor layer having a first portion with a first thickness and a second portion with a second thickness, the first portion having a first surface;
a first optical sensor in the first portion, the first optical sensor including:
a first anode recessed in the first portion, the first anode having an exposed surface coplanar with the first surface; and
a second optical sensor in the second portion.

### Claim 2 (depends on 1)

The device of claim 1 wherein the second optical sensor includes a second anode in the semiconductor layer.

### Claim 3 (depends on 2)

The device of claim 2 wherein the semiconductor layer includes the second portion having a second surface, the second anode being coplanar with the second surface.

### Claim 4 (depends on 3)

The device of claim 3 wherein the first anode forms a PN junction with the semiconductor layer and the second anode forms a PN junction with the semiconductor layer.

### Claim 5 (depends on 2)

The device of claim 2 wherein the second optical sensor includes an absorption layer on the second anode.

### Claim 6 (depends on 2)

The device of claim 2 wherein the first optical sensor includes a first contact on the first anode and the second optical sensor includes a second contact on the second anode.

### Claim 7 (depends on 6)

The device of claim 6 wherein the second optical sensor includes an absorption layer on the second anode.

### Claim 8 (depends on 7)

The device of claim 7 wherein the absorption layer abuts the second contact.

### Claim 9

A device, comprising:
a substrate;
a semiconductor layer on the substrate, the semiconductor layer having a first portion with a first thickness and a second portion with a second thickness;
a first optical sensor formed on a first surface of the first portion;
a second optical sensor formed on a second surface of the second portion; and
a contact layer formed on a third surface of the semiconductor layer, the third surface being opposite the first surface and the second surface.

### Claim 10 (depends on 9)

The device of claim 9 wherein the first optical sensor includes a first metal layer formed on the first surface of the semiconductor layer and the second optical sensor includes a second metal layer formed on the second surface of the semiconductor layer.

### Claim 11 (depends on 10)

The device of claim 10 wherein the second optical sensor includes an absorption layer on the second metal layer.

### Claim 12 (depends on 10)

The device of claim 10 wherein the first optical sensor includes a first contact on the first metal layer and the second optical sensor includes a second contact on the second metal layer.

### Claim 13

A device, comprising:
a substrate;
a semiconductor layer on a first surface of the substrate;
a first sensor in the semiconductor layer, the first sensor including:
a first anode; and
a first contact coupled to the first anode;
a second sensor in the semiconductor layer, the second sensor including:
a second anode;
an absorption layer on the second anode; and
a second contact coupled to the second anode;
a cathode on a second surface of the substrate, the second surface being opposite the first surface of the substrate, the cathode extending between the first sensor and the second sensor.

### Claim 14 (depends on 13)

The device of claim 13 wherein the semiconductor layer includes a first portion with a first surface and a second portion with a second surface, the first anode being coplanar with the first surface and the second anode being coplanar with the second surface.

### Claim 15 (depends on 14)

The device of claim 14 wherein the first anode forms a PN junction with the semiconductor layer and the second anode forms a PN junction with the semiconductor layer.

### Claim 16 (depends on 14)

The device of claim 14 wherein the first portion has a first thickness and the second portion has a second thickness, the second thickness being greater than the first thickness.

### Claim 17 (depends on 13)

The device of claim 13 further comprising a contact layer on the cathode.
