# US 10,481,496 B2 · Forming conductive vias using a light guide

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- Number: US 10,481,496 B2
- Document ID: US10481496B2
- Status: Granted
- Kind: B2
- Application number: 15/635,374
- Filed: 2017-06-28
- Published: 2019-01-03
- Granted: 2019-11-19
- Earliest claimed: 2017-06-28
- Assignees: International Business Machines Corporation
- Applicants: International Business Machines Corporation
- Inventors: Gerald Bartley; Matthew Doyle; Darryl Becker; Mark Jeanson
- Web page: https://patentgrep.com/patent/US10481496B2

## CPC

- G03F 7/20: Exposure; Apparatus therefor (photographic printing apparatus for making copies G03B27/00)
- G03F 1/38: Masks having auxiliary features, e.g. special coatings or marks for alignment or testing; Preparation thereof
- G03F 7/038: Macromolecular compounds which are rendered insoluble or differentially wettable (G03F7/075 takes precedence; macromolecular azides G03F7/012; macromolecular diazonium compounds G03F7/021)
- G03F 7/039: Macromolecular compounds which are photodegradable, e.g. positive electron resists (G03F7/075 takes precedence; macromolecular quinonediazides G03F7/023)
- G03F 7/16: Coating processes; Apparatus therefor (applying coatings to base materials in general B05; applying photosensitive compositions to base for photographic purposes G03C1/74)
- G03F 7/26: Processing photosensitive materials; Apparatus therefor (G03F7/12 - G03F7/24 take precedence)
- G03F 7/405: {Treatment with inorganic or organometallic reagents after imagewise removal}
- H05K 3/4038: {Through-connections; Vertical interconnect access [VIA] connections (H05K3/403, H05K3/42 take precedence)}
- H05K 3/428: {initial plating of through-holes in substrates having a metal pattern}
- H05K 3/424: {by direct electroplating}
- H05K 3/429: {Plated through-holes specially for multilayer circuits, e.g. having connections to inner circuit layers}
- H05K 2201/09645: Patterning on via walls; Plural lands around one hole
- H05K 2203/0514: Photodevelopable thick film, e.g. conductive or insulating paste
- H05K 2203/0562: Details of resist
- H05K 2203/1383: Temporary protective insulating layer
- G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G)
- H05K: PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS

## Abstract

The present invention provides a process and a structure of forming conductive vias using a light guide. In an exemplary embodiment, the process includes providing a via in a base material in a direction perpendicular to a plane of the base material, applying a photoresist layer to an interior surface of the via, inserting a light guide into the via, exposing, by the light guide, a portion of the photoresist layer to light, thereby resulting in an exposed portion of the photoresist layer and an unexposed portion of the photoresist layer, removing a portion of the photoresist layer, and plating an area of the via, where the photoresist has been removed, with a metal, thereby resulting in a portion of the via plated with metal and a portion of the via not plated with metal.

## Claims

### Claim 1

A process comprising:
providing a via in a base material in a direction perpendicular to a plane of the base material;
applying a photoresist layer to an interior surface of the via;
inserting a light guide into the via;
exposing, by the light guide, a portion of the photoresist layer to light, thereby resulting in an exposed portion of the photoresist layer and an unexposed portion of the photoresist layer;
removing a portion of the photoresist layer; and
plating an area of the via, where the photoresist has been removed, with a metal, thereby resulting in a portion of the via plated with metal and a portion of the via not plated with metal.

### Claim 2 (depends on 1)

The process of claim 1, wherein a portion of an outer surface of the light guide is masked.

### Claim 3 (depends on 1)

The process of claim 1, wherein the photoresist layer is a positive tone photoresist material.

### Claim 4 (depends on 3)

The process of claim 3, wherein the removing comprises removing the exposed portion of the photoresist layer.

### Claim 5 (depends on 1)

The process of claim 1 wherein the removing comprises washing the via with a photoresist developer.

### Claim 6 (depends on 1)

The process of claim 1, wherein the photoresist layer is a negative tone photoresist material.

### Claim 7 (depends on 6)

The process of claim 6, wherein the removing comprises removing the unexposed portion of the photoresist layer.

### Claim 8

A process comprising:
providing a via in a base material, comprising at least two copper lines and at least one insulator layer separating the at least two copper lines, in a direction perpendicular to a plane of the base material,
wherein the via intersects the at least two copper lines;
applying a photoresist layer to an interior surface of the via;
inserting a light guide into the via,
wherein a portion of an outer surface of the light guide is masked;
exposing, via the light guide, a portion of the photoresist layer to light, thereby resulting in an exposed portion of the photoresist layer and an unexposed portion of the photoresist layer;
removing a portion of the photoresist layer; and
plating an area of the via, where the photoresist has been removed, with a metal, thereby resulting in a portion of the via plated with metal and a portion of the via not plated with metal.

### Claim 9 (depends on 8)

The process of claim 8, wherein the masked portion of the light guide has two or more masked regions separated by one or more unmasked regions.

### Claim 10 (depends on 8)

The process of claim 8, wherein the photoresist layer is a positive tone photoresist material.

### Claim 11 (depends on 10)

The process of claim 10, wherein the removing comprises removing the exposed portion of the photoresist layer.

### Claim 12 (depends on 8)

The process of claim 8 wherein the removing comprises washing the via with a photoresist developer.

### Claim 13 (depends on 8)

The process of claim 8, wherein the photoresist layer is a negative tone photoresist material.

### Claim 14 (depends on 13)

The process of claim 13, wherein the removing comprises removing the unexposed portion of the photoresist layer.

### Claim 15

A process comprising:
providing a via in a base material, comprising at least two copper lines and at least one insulator layer separating the at least two copper lines, in a direction perpendicular to a plane of the base material,
wherein the via intersects the at least two copper lines;
applying a photoresist layer to an interior surface of the via;
inserting a light guide into the via;
exposing, via the light guide, a portion of the photoresist layer to light, thereby resulting in an exposed portion of the photoresist layer and an unexposed portion of the photoresist layer;
removing a portion of the photoresist layer; and
plating an area of the via, where the photoresist has been removed, with a metal, thereby resulting in a portion of the via plated with metal and a portion of the via not plated with metal.

### Claim 16 (depends on 15)

The process of claim 15, wherein a portion of an outer surface of the light guide is masked.

### Claim 17 (depends on 15)

The process of claim 15, wherein the photoresist layer is a positive tone photoresist material.

### Claim 18 (depends on 17)

The process of claim 17, wherein the removing comprises removing the exposed portion of the photoresist layer.

### Claim 19 (depends on 15)

The process of claim 15 wherein the removing comprises washing the via with a photoresist developer.

### Claim 20 (depends on 15)

The process of claim 15, wherein the photoresist layer is a negative tone photoresist material.

### Claim 21 (depends on 20)

The process of claim 20, wherein the removing comprises removing the unexposed portion of the photoresist layer.
