# US 10,481,420 B2 · Optical detector and filter employing resonant nano-/microparticles > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,481,420 B2 - Document ID: US10481420B2 - Status: Granted - Kind: B2 - Application number: 15/746,350 - Filed: 2016-07-20 - Published: 2018-08-02 - Granted: 2019-11-19 - Earliest claimed: 2015-07-20 - Assignees: Centre National De La Recherche Scientifique; Universite D'Aix-Marseille; Ecole Centrale De Marseille - Applicants: Centre National de la Recherche Scientifique; Université d'Aix-Marseille; Ecole Centrale de Marseille - Inventors: Nicolas Bonod; Marco Abbarchi; Thomas Michael Wood - Web page: https://patentgrep.com/patent/US10481420B2 ## CPC - G02F 1/015: based on semiconductor elements having potential barriers, e.g. having a PN or PIN junction (G02F1/03 takes precedence) - G02B 5/20: Filters (polarising elements G02B5/30) - G02F 1/0126: {Opto-optical modulation, i.e. control of one light beam by another light beam, not otherwise provided for in this subclass} - G02F 2202/36: Micro- or nanomaterials - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract In the field of photonic and opto-electronic components, an optical filter comprises a plurality of semi-conducting nano-/microparticles, exhibiting properties of electromagnetic resonance in the optical and near-infrared domain, arranged on a plane, characterized in that it furthermore comprises a layer with electrically adjustable optical index disposed on the surface formed by said nano-/microparticles and said plane; a first electrically insulating layer disposed on said layer with electrically adjustable optical index and an electrode disposed on said first electrically insulating layer. ## Claims ### Claim 1 An optical filter comprising: a plurality of semi-conducting or dielectric nano-/microparticles, exhibiting properties of electromagnetic resonance in the optical and near-infrared domain, arranged on a plane, further comprising: a layer with electrically adjustable optical index disposed on the surface formed by said nano-/microparticles and said plane; a first electrically insulating layer disposed on said layer with electrically adjustable optical index and an electrode disposed on said first electrically insulating layer. ### Claim 2 (depends on 1) The optical filter as claimed in claim 1, comprising a second electrically insulating layer a face of which coincides with said plane, said second electrically insulating layer being in contact with said nano-/microparticles and the layer with electrically adjustable optical index. ### Claim 3 (depends on 1) The optical filter as claimed in claim 1, in which at least one said nano-/microparticle comprises a semi-conducting core and a semi-conducting shell whose electrical properties are different and suitable for forming at least one junction chosen from among an anisotype homojunction, an isotype heterojunction and an anisotype heterojunction. ### Claim 4 (depends on 1) The optical filter as claimed in claim 1, comprising at least one shell of electrically insulating material in which at least one said nano-/microparticle is surrounded, at least partially, by a said shell of electrically insulating material. ### Claim 5 (depends on 4) The optical filter as claimed claim 4, in which at least one material of said layer with electrically adjustable optical index is an organic material. ### Claim 6 (depends on 1) The optical filter as claimed in claim 1, in which the material of said layer with electrically adjustable optical index is chosen at least from among poly(3,4-ethylenedioxythiophene), sodium polystyrene sulfonate, indium-tin oxide, zinc-aluminum oxide, poly(4,4-dioctylcyclopentadithiophene), poly(methyl methacrylate) and networks of carbon nanotubes. ### Claim 7 (depends on 1) The optical filter as claimed in claim 1, the size and the material of said nano-/microparticles of which are suitable for allowing a resonance of said nano-/microparticles for excitation wavelengths of between 300 nm and 2.5 μm. ### Claim 8 (depends on 1) The optical filter as claimed in claim 1, comprising a first electrical circuit connected on the one hand to a ground and on the other hand to said electrode, suitable for the polarization of said layer with electrically adjustable optical index. ### Claim 9 (depends on 2) The optical filter as claimed in claim 2, in which the optical index of the material of said second electrically insulating layer is strictly less than the optical index of the material of said nano-/microparticles and in which said nano-/microparticles are substantially hemispherical, the plane part of the hemispheres formed by said nano-/microparticles coinciding with said plane. ### Claim 10 (depends on 1) A matrix of optical filters as claimed in claim 1. ### Claim 11 (depends on 8) The matrix of optical filters as claimed in claim 8, in which at least two said first circuits are connected so as to impose the same potential between said ground and each said electrode. ### Claim 12 (depends on 10) The matrix of optical filters as claimed in claim 10, in which at least one said first electrical circuit is suitable for imposing a potential independent of said other first electrical circuits, on at least one said electrode. ### Claim 13 (depends on 1) A photodetector with p-n junction, comprising a filter as claimed in claim 1, whose said filter is disposed on a layer chosen from among an n-doped layer and a p-doped layer of said p-n junction. ### Claim 14 (depends on 1) A photodetector comprising an optical filter as claimed in claim 1, the material of whose said layer with electrically adjustable optical index is conducting. ### Claim 15 (depends on 14) The photodetector as claimed in claim 14, comprising a second electrical circuit, two of whose terminals are connected to said layer with electrically adjustable index, said second electrical circuit being suitable for detecting variations of electric current at said terminals. ### Claim 16 (depends on 13) A matrix of said photodetectors as claimed in claim 13. ### Claim 17 (depends on 16) The matrix of photodetectors as claimed in claim 16, in which at least two said first circuits are connected so as to impose the same potential between said ground and each said electrode. ### Claim 18 (depends on 16) The matrix of photodetectors as claimed in claim 16, in which at least one said first electrical circuit is suitable for imposing a potential independent of said other first electrical circuits, on at least one said electrode. ### Claim 19 (depends on 1) A method for the fabrication of a filter as claimed in claim 1, comprising at least the following steps: a) dewetting of at least one semi-conducting material layer previously deposited on a said second electrically insulating layer; b) deposition of a said layer with electrically adjustable optical index on said semi-conducting and insulating materials. ### Claim 20 (depends on 19) The method as claimed in claim 19, comprising an initial step of etching patterns on said layer of at least one said semi-conducting material, said patterns spatially controlling the formation of said nano-/microparticles during step a). ### Claim 21 (depends on 19) The method as claimed in claim 19, in which at least one said semi-conducting material layer is etched with a focused ion probe. ### Claim 22 (depends on 1) A method for the fabrication of a filter as claimed in claim 1, comprising at least the following steps: a) dewetting of at least one semi-conducting material layer previously deposited on a said second electrically insulating layer; b) deposition of a said layer with electrically adjustable optical index on said semi-conducting and insulating materials, further comprising etching at least said layer with electrically adjustable index so as to spatially define said filter. ### Claim 23 (depends on 1) A method of optical filtering by a filter as claimed in claim 1, said method comprising adjusting the resonance wavelength of said nano-/microparticles by driving the potential on the terminal of said electrode.