# US 10,481,127 B2 · Apparatus for, system for and methods of maintaining sensor accuracy

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- Number: US 10,481,127 B2
- Document ID: US10481127B2
- Status: Granted
- Kind: B2
- Application number: 15/714,592
- Filed: 2017-09-25
- Published: 2018-01-18
- Granted: 2019-11-19
- Earliest claimed: 2015-01-12
- Assignees: Ecolab USA Inc.
- Applicants: Ecolab USA Inc.
- Inventors: Kun Xiong; Brandon M. Davis; William A. Von Drasek
- Web page: https://patentgrep.com/patent/US10481127B2

## CPC

- G01N 27/4168: {Oxidation-reduction potential, e.g. for chlorination of water (water analysis G01N33/18)}
- G01N 27/4167: {pH (electrodes therefor G01N27/302, G01N27/36)}
- G01N 33/18: Water
- G01N 1/34: Purifying; Cleaning {(processes or apparatus for extracting or separating nucleic acids from biological samples C12N15/1003)}
- Y10T 436/12: Condition responsive control
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Methods of maintaining accuracy in the measurement of one or more parameters of industrial water in industrial water systems are provided. The methods include the use of physical and/or chemical procedures to prevent and/or remove deposition from one or more surfaces utilized in measurement of the one or more parameters. The deposition may be caused by, for example, corrosion, fouling, or microbiological growth.

## Claims

### Claim 1

A method comprising:
contacting an industrial water stream at an industrial water stream pressure with a plurality of surfaces utilized for measuring a plurality of parameters of an industrial water in an industrial water system;
isolating a first subset of the surfaces from the industrial water stream while a second subset of the surfaces maintains contact with the industrial water stream;
cleaning at least one surface of the first subset of surfaces while the second subset of surfaces maintains contact with the industrial water stream; and
restoring contact of the industrial water stream with the first subset of surfaces;
wherein the first subset of the surfaces comprises at least one of a wetted surface of a pH sensor, a wetted surface of an oxidation-reduction potential sensor, and a wetted surface of a light transference medium; and
wherein the second subset of the surfaces comprises at least one of a wetted surface of a corrosion detection sensor and a wetted surface of a conductivity sensor.

### Claim 2 (depends on 1)

The method of claim 1, wherein the cleaning comprises contacting a combined gaseous and liquid stream with the at least one surface of the first subset.

### Claim 3 (depends on 2)

The method of claim 2, wherein the combined gaseous and liquid stream comprises a cleaning solution.

### Claim 4 (depends on 3)

The method of claim 3, wherein the cleaning solution comprises aqueous urea hydrogen chloride.

### Claim 5 (depends on 3)

The method of claim 3, wherein the cleaning solution comprises an ingredient selected from urea hydrogen chloride, phosphoric acid, sulfuric acid, nitric acid, a peroxyacid, a detergent, an emulsifier, or a combination thereof.

### Claim 6 (depends on 2)

The method of claim 2, wherein a gaseous stream having a gaseous stream pressure is introduced into a liquid stream at a liquid stream pressure to form the combined gaseous and liquid stream.

### Claim 7 (depends on 6)

The method of claim 6, wherein the gaseous stream pressure is from 10 to 100 psi greater than the liquid stream pressure.

### Claim 8 (depends on 6)

The method of claim 6, wherein the gaseous stream is introduced in a direction perpendicular from the liquid stream.

### Claim 9 (depends on 6)

The method of claim 6, wherein the gaseous stream comprises an acid gas selected from a carbon-containing acid gas, a sulfur-containing acid gas, a nitrogen-containing acid gas, a chlorine-containing acid gas, or a combination thereof.

### Claim 10 (depends on 6)

The method of claim 6, wherein pellets of carbon dioxide are introduced with the gaseous stream into the liquid stream.

### Claim 11 (depends on 6)

The method of claim 6, wherein the gaseous stream is introduced intermittently into the liquid stream.

### Claim 12 (depends on 2)

The method of claim 2, wherein the combined gaseous and liquid stream comprises a gaseous substance selected from air, nitrogen, oxygen, an acid gas, or a combination thereof.

### Claim 13 (depends on 2)

The method of claim 2, wherein the first subset of surfaces comprises a wetted surface of a light transference medium.

### Claim 14 (depends on 13)

The method of claim 13, further comprising fanning the combined gaseous and liquid stream as it flows toward the wetted surface of the light transference medium.

### Claim 15 (depends on 1)

The method of claim 1, wherein the cleaning comprises contacting a cleaning solution with the at least one surface of the first subset.

### Claim 16 (depends on 15)

The method of claim 15, wherein the cleaning solution comprises aqueous urea hydrogen chloride.

### Claim 17 (depends on 15)

The method of claim 15, wherein the cleaning solution comprises an ingredient selected from urea hydrogen chloride, phosphoric acid, sulfuric acid, nitric acid, a peroxyacid, a detergent, an emulsifier, or a combination thereof.

### Claim 18 (depends on 1)

The method of claim 1, wherein the industrial water system is selected from a cooling water system, a heating water system, a papermaking system, a refining system, a chemical processing system, a crude oil extraction system, and a natural gas extraction system.

### Claim 19 (depends on 1)

The method of claim 1, wherein the industrial water system is a cooling water system.

### Claim 20 (depends on 1)

The method of claim 1, wherein at least one of the surfaces is located in a narrowed portion of the industrial water stream.
