# US 10,479,947 B2 · Hydrocracking process integrated with solvent deasphalting to reduce heavy polycyclic aromatic buildup in heavy oil hydrocracker recycle stream

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- Number: US 10,479,947 B2
- Document ID: US10479947B2
- Status: Granted
- Kind: B2
- Application number: 14/874,504
- Filed: 2015-10-05
- Published: 2016-04-07
- Granted: 2019-11-19
- Earliest claimed: 2014-10-07
- Assignees: Shell Oil Company
- Applicants: Shell Oil Company
- Inventors: Aristides Macris
- Web page: https://patentgrep.com/patent/US10479947B2

## CPC

- C10G 67/049: {The hydrotreatment being a hydrocracking}
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

An integrated hydrocracking and solvent deasphalting process that provides for removal from the heavy oil recycle stream heavy polycyclic aromatic compounds formed in the hydrocracking step and recycling the resulting deasphalted paraffinic oil as a feed to the hydrocracker reactor of the process for further conversion.

## Claims

### Claim 1

A hydrocracking process providing for a reduction of the buildup of heavy poly-aromatic hydrocarbons in a heavy oil recycle stream of said hydrocracking process, wherein the process comprises:
(a) hydrocracking in a hydrocracker reactor a heavy feedstock, which at least 90 weight percent boils at a temperature above 380° C., to yield a hydrocracked product;
(b) separating said hydrocracked product into at least two product streams including said heavy oil recycle stream, comprising a concentration of said heavy poly-aromatic hydrocarbons and uncoverted hydrocarbons having a boiling temperature of above 380° C.;
(b) passing a first portion of said heavy oil recycle stream as a recycle feed to said hydrocracker reactor;
(c) passing a second portion of said heavy oil recycle stream to a solvent deasphalting unit for separating said heavy poly-aromatic hydrocarbons from said second portion of said heavy oil recycle stream to yield a deasphalted paraffinic oil and a heavy polycyclic aromatics fraction, comprising said heavy poly-aromatic hydrocarbons;
(d) passing said deasphalted paraffinic oil as a feed to said hydrocracker reactor;
wherein the weight ratio of said second portion of said heavy oil recycle stream to said first potion of said heavy oil recycle stream is less than 0.5; and
wherein the concentration of heavy poly-aromatic hydrocarbons in the heavy oil recycle stream is less than 1,000 ppmw.

### Claim 2 (depends on 1)

A hydrocracking process as recited in claim 1, wherein a weight ratio of said second portion of said heavy oil recycle stream-to-said first portion of said heavy oil recycle stream is less than 0.4 and greater than 0.05.

### Claim 3 (depends on 2)

A hydrocracking process as recited in claim 2, wherein said first portion of said heavy oil recycle stream is at least 50 wt % of said heavy oil recycle stream.

### Claim 4 (depends on 2)

A hydrocracking process as recited in claim 2, wherein said weight ratio of said second portion- of said heavy oil recycle stream to-said first portion of said heavy oil recycle stream is controlled so as to maintain said concentration of said heavy poly-aromatic hydrocarbons to less than 750 ppmw of said heavy oil recycle stream.

### Claim 5 (depends on 2)

A hydrocracking process according to any of claim 2, wherein said first portion of said heavy oil recycle stream exceeds 60 wt. % of said heavy oil recycle stream.

### Claim 6 (depends on 2)

A hydrocracking process according to any of claim 2, wherein said first portion of said heavy oil recycle stream exceeds 75 wt. % of said heavy oil recycle stream.

### Claim 7 (depends on 1)

A hydrocracking process as recited in claim 1, wherein said least two product streams further includes at least one light hydrocracker product, wherein each of said at least one light hydrocracker product has an end point of less than 380° C. (716° F.).

### Claim 8 (depends on 7)

A hydrocracking process as recited in claim 7, wherein said hydrocracking process provides for a conversion of said heavy feedstock of at least 50%, wherein said conversion is defined as the percentage of the hydrocarbons of said heavy feedstock boiling at or above 380° C. (716° F.) that is converted to hydrocarbons boiling below 380° C. (716° F.), based on the weight of said heavy feedstock.

### Claim 9 (depends on 1)

A hydrocracking process as recited in claim 1, wherein the weight ratio of said second portion of said heavy oil recycles stream to said first portion of said heavy oil recycle stream ranges from 0.1 to 0.35.

### Claim 10 (depends on 1)

A hydrocracking process as recited in claim 1, wherein the weight ratio of said second portion of said heavy oil recycles stream to said first portion of said heavy oil recycle stream ranges from 0.15 to 0.3.