# US 10,479,877 B2 · Filler composition and polyolefin resin composition

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- Number: US 10,479,877 B2
- Document ID: US10479877B2
- Status: Granted
- Kind: B2
- Application number: 15/559,754
- Filed: 2016-03-29
- Published: 2018-02-15
- Granted: 2019-11-19
- Earliest claimed: 2015-03-30
- Assignees: Ube Material Industries, Ltd.
- Applicants: Ube Material Industries, Ltd.
- Inventors: Takashi Idemitsu; Shotaro Hida; Tetsuo Takayama; Ryoichi Nomura
- Web page: https://patentgrep.com/patent/US10479877B2

## CPC

- C08K 3/30: Sulfur-, selenium- or tellurium-containing compounds
- C08K 3/36: Silica
- C08K 7/08: Oxygen-containing compounds
- C08K 9/06: with silicon-containing compounds
- C08K 2003/2217: {of magnesium}
- C08K 2003/3063: {Magnesium sulfate}
- C08K 2201/005: Additives being defined by their particle size in general
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

A filler composition comprising fibrous basic magnesium sulfate particles and non-fibrous inorganic micro-particles having an average particle diameter in the range of 0.001 to 0.5 μm in a ratio by weight in the range of 100:0.001 to 100:50, and a polyolefin resin composition comprising a polyolefin resin, fibrous basic magnesium sulfate particles and non-fibrous inorganic micro-particles having an average particle diameter in the range of 0.001 to 0.5 μm, in which the polyolefin resin and fibrous basic magnesium sulfate particles are present in a weight ratio of 99:1 to 50:50, and the non-fibrous inorganic micro-particles are present in an amount of 0.001 to 50 weight parts per 100 weight parts of the basic fibrous magnesium sulfate particles and/or in an amount of 0.0002 to 10 weight parts, per 100 weight parts of the resin.

## Claims

### Claim 1

A polyolefin resin composition comprising a polyolefin resin, fibrous basic magnesium sulfate particles and spherical silicon dioxide particles having an average particle diameter in the range of 0.001 to 0.5 μm in which the polyolefin resin and fibrous basic magnesium sulfate particles are contained in a ratio by weight in the range of 99:1 to 50:50, and the spherical silicon dioxide particles are contained in an amount of 0.001 to 50 weight parts per 100 weight parts of the fibrous basic magnesium sulfate particles and/or in an amount of 0.0002 to 10 weight parts per 100 weight parts of the resin.

### Claim 2 (depends on 1)

The polyolefin resin composition of claim 1, wherein the fibrous basic magnesium sulfate particles have an average longer diameter in the range of 5 to 50 μm and an average shorter diameter in the range of 0.1 to 2.0 μm, and an aspect ratio in terms of the average longer diameter/average shorter diameter is in the range of 5 to 50.

### Claim 3 (depends on 1)

The polyolefin resin composition of claim 1, wherein the average diameter of the spherical silicon dioxide particles is in the range of ⅕ to 1/500 per an average shorter diameter of the fibrous basic magnesium sulfate particles.

### Claim 4 (depends on 1)

The polyolefin resin composition of claim 1, wherein the spherical silicon dioxide particles are contained in an amount of 0.005 to 2 weight parts, per 100 weight parts of the fibrous basic magnesium sulfate particles.

### Claim 5

The polyolefin resin composition comprising a polyolefin resin, fibrous basic magnesium sulfate particles and non-fibrous inorganic micro-particles having an average particle diameter in the range of 0.001 to 0.5 μm in which the polyolefin resin and fibrous basic magnesium sulfate particles are contained in a ratio by weight in the range of 99:1 to 50:50, and the non-fibrous inorganic micro-particles are contained in an amount of 0.001 to 50 weight parts per 100 weight parts of the fibrous basic magnesium sulfate particles and/or in an amount of 0.0002 to 10 weight parts per 100 weight parts of the resin, wherein the non-fibrous inorganic micro-particles have surfaces treated with a coupling agent.

### Claim 6 (depends on 5)

The polyolefin resin composition of claim 5, wherein the polyolefin resin is a polypropylene resin.

### Claim 7 (depends on 1)

The polyolefin resin composition of claim 1, wherein the polyolefin resin is a polypropylene resin.