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US 10,479,866 B1Granted
Block copolymers including poly(phenylene) and methods thereof
AssigneeNational Technology & Engineering Solutions of Sandia, LLC
InventorCy Fujimoto
Life of this patent
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Abstract
The present invention relates to polymers and copolymer including a poly(phenylene) structure, as well as a long tether. In some embodiments, the long tether facilitates a reaction between the poly(phenylene) structure and another subunit of a second polymer. In some embodiments, the tether is flexible.
Claims10
A composition comprising a structure having the formula (Ia):
- or a salt thereof, wherein:
- each R1 and R3 is, independently, H, halo, optionally substituted C1-12 alkyl, optionally substituted C1-12 haloalkyl, optionally substituted C1-12 perfluoroalkyl, optionally substituted C1-12 heteroalkyl, RS, RP, RC, or RF, wherein RS is an acidic moiety comprising a sulfonyl group, RP is an acidic moiety comprising a phosphoryl group, RC is an acidic moiety comprising a carbonyl group, and RF is an electron-withdrawing moiety;
- each RT is, independently, H, halo, optionally substituted C1-12 alkyl, optionally substituted C1-12 alkoxy, RS, RP, RC, or RF;
- each L1a and L2a is, independently, a covalent bond, carbonyl, oxy, thio, azo, phosphonoyl, phosphoryl, sulfonyl, sulfinyl, sulfonamide, imino, imine, phosphine, nitrilo, optionally substituted C1-12 alkylene, optionally substituted C1-12 alkyleneoxy, optionally substituted C1-12 heteroalkylene, optionally substituted C1-12 heteroalkyleneoxy, optionally substituted C4-18 arylene, or optionally substituted C4-18 aryleneoxy;
- each ArL and ArM is, independently, a bivalent linker comprising optionally substituted arylene;
- each ArP comprises an optionally substituted arylene or is a covalent bond;
- each q is, independently, an integer of from 1 to 5;
- each t is, independently, an integer of from 1 to 4;
- each of m1 and m2 is, independently, an integer of from 3 to 10 from 1 to 10;
- and
- m is an integer of from about 1 to 1000,
- wherein at least one of L1a and/or L2a is not a covalent bond.
9 more elements
Dependencies are inferred from the claim text.