# US 10,479,723 B2 · Window with UV-treated low-coating and method of making same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,479,723 B2 - Document ID: US10479723B2 - Status: Granted - Kind: B2 - Application number: 16/272,113 - Filed: 2019-02-11 - Published: 2019-06-06 - Granted: 2019-11-19 - Earliest claimed: 2012-05-31 - Assignees: Guardian Glass, LLC - Applicants: Guardian Glass, LLC - Inventors: Alexey Krasnov; Muhammad Imran; Willem Den Boer; Kevin O'Connor - Web page: https://patentgrep.com/patent/US10479723B2 ## CPC - C03C 17/36: at least one coating being a metal - C03C 17/3644: {the metal being silver} - C03C 17/366: {Low-emissivity or solar control coatings} - C03C 2217/74: UV-absorbing coatings - C03C 2218/32: After-treatment - C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS ## Abstract Certain embodiments of this invention relates to a coated article including a low-emissivity (low-E) coating supported by a substrate (e.g., glass substrate) for use in a window, where the low-E coating is exposed to ultraviolet (UV) radiation in order to improve the coating's and thus the coated article's electrical, optical and/or thermal blocking properties. The low-E coating includes at least one infrared (IR) reflecting layer of or including silver which is located on and directly contacting a contact/seed layer of or including metal oxide such as zinc oxide and/or zinc stannate. Exposing the low-E coating to UV radiation, e.g., emitted from a UV lamp(s) and/or UV laser(s), allows for selective heating of the contact/seed layer which in turn transfers the heat energy to the adjacent IR reflecting layer. This heating of the silver inclusive layer improves the silver layer's electrical, optical and/or thermal blocking properties. The UV treated coated article, with its improved properties, may be used in the context of monolithic or insulating glass (IG) window units. ## Claims ### Claim 1 A method of making a coated article for use in a window, the method comprising: having a coated article including a glass substrate that supports a coating, the coating comprising at least one layer comprising silver located directly on and contacting a layer comprising zinc oxide that can absorb ultraviolet (UV) radiation, the coating further comprising a dielectric layer between at least the layer comprising zinc oxide and the glass substrate, and at least one upper dielectric layer located over at least the layer comprising silver so that the layer comprising silver is located between at least the upper dielectric layer and the glass substrate; directing UV radiation from at least one UV source toward the coating and exposing the coating to UV radiation in order to reduce a sheet resistance of the coating. ### Claim 2 (depends on 1) The method of claim 1, wherein the UV source comprises at least one UV emitting lamp. ### Claim 3 (depends on 1) The method of claim 1, wherein the UV source comprises at least one UV emitting laser. ### Claim 4 (depends on 1) The method of claim 1, wherein said exposing the coating to UV radiation reduces the sheet resistance of the coating by at least 1 ohm/square. ### Claim 5 (depends on 1) The method of claim 1, wherein the layer comprising zinc oxide has a bandgap of from about 3.2 to 3.4 eV. ### Claim 6 (depends on 1) The method of claim 1, wherein the coating has a sheet resistance (Rs) of no greater than 10 ohms/square after said UV exposing. ### Claim 7 (depends on 1) The method of claim 1, wherein said exposing the coating to UV radiation increases the visible transmission of the coated article by at least 1%. ### Claim 8 (depends on 1) The method of claim 1, further comprising, after said exposing, coupling the substrate with the coating thereon to another substrate in making an insulating glass (IG) window unit. ### Claim 9 (depends on 1) The method of claim 1, wherein radiation emitted from the source consists essentially of UV radiation. ### Claim 10 (depends on 1) The method of claim 1, where the coating further comprises a layer comprising an oxide of Ni and/or Cr located over and directly contacting the layer comprising silver. ### Claim 11 (depends on 1) The method of claim 1, wherein the upper dielectric layer comprises silicon nitride. ### Claim 12 (depends on 1) The method of claim 1, wherein the source and the coating are located on the same side of the substrate. ### Claim 13 (depends on 1) The method of claim 1, wherein the layer comprising zinc oxide comprises zinc stannate. ### Claim 14 A method of making a coated article, the method comprising: having a coated article including a glass substrate that supports a low-E coating comprising at least one substantially metallic layer comprising silver located directly on and contacting a contact layer comprising metal oxide that has a bandgap of from 3.2 to 3.4 eV, the low-E coating further comprising a dielectric layer between at least the contact layer and the glass substrate, and an upper dielectric layer located over at least the substantially metallic layer comprising silver so that the substantially metallic layer comprising silver is located between at least the upper dielectric layer and the glass substrate; exposing the coating to UV radiation from at least one UV source in order to reduce a sheet resistance of the coating and increase visible transmission of the coating. ### Claim 15 (depends on 14) The method of claim 14, wherein the layer comprising metal oxide comprises zinc oxide. ### Claim 16 (depends on 14) The method of claim 14, wherein the layer comprising metal oxide comprises zinc stannate. ### Claim 17 (depends on 14) The method of claim 14, wherein the UV source comprises at least one UV emitting lamp and/or laser. ### Claim 18 (depends on 14) The method of claim 14, wherein said exposing the coating to UV radiation reduces the sheet resistance of the coating by at least 1 ohm/square. ### Claim 19 (depends on 18) The method of claim 18, wherein the coating has a sheet resistance (Rs) of no greater than 10 ohms/square after said UV exposing. ### Claim 20 (depends on 14) The method of claim 14, wherein said exposing the coating to UV radiation increases the visible transmission of the coated article by at least 1%. ### Claim 21 A method of making a coated article for use in a window, the method comprising: having a coated article including a glass substrate that supports a coating, the coating comprising at least one layer comprising silver located directly on and contacting a layer comprising zinc oxide, the coating further comprising a dielectric layer between at least the layer comprising zinc oxide and the glass substrate, and at least one upper dielectric layer located over at least the layer comprising silver so that the layer comprising silver is located between at least the upper dielectric layer and the glass substrate; directing UV radiation from at least one UV source toward the coating and exposing the coating to UV radiation in order to reduce a sheet resistance of the coating; wherein the layer comprising zinc oxide has a bandgap of from about 3.2 to 3.4 eV; and wherein the coating has a sheet resistance (Rs) of no greater than 10 ohms/square after said UV exposing.