# US 10,478,794 B1 · Bi-modal radial flow reactor > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,478,794 B1 - Document ID: US10478794B1 - Status: Granted - Kind: B1 - Application number: 16/285,393 - Filed: 2019-02-26 - Granted: 2019-11-19 - Earliest claimed: 2019-02-26 - Assignees: Chevron Phillips Chemical Company LP - Applicants: Chevron Phillips Chemical Company LP - Inventors: Vincent DePaul McGahee; Cameron M. Crager; William Donald Treleaven - Web page: https://patentgrep.com/patent/US10478794B1 ## CPC - B01J 8/0278: {Feeding reactive fluids (for solid material B01J8/0015)} - B01J 35/19: {Catalysts containing parts with different compositions} - B01J 8/0015: {Feeding of the particles in the reactor; Evacuation of the particles out of the reactor} - B01J 8/0214: {in a cylindrical annular shaped bed} - B01J 8/0285: {Heating or cooling the reactor (for tubular reactors in furnaces B01J8/062)} - B01J 8/0411: {the beds being concentric} - B01J 8/0415: {the beds being superimposed one above the other (B01J8/0434 takes precedence)} - B01J 8/0419: {the beds being placed in separate reactors} - B01J 8/0492: {Feeding reactive fluids (for solid material, see B01J8/0015)} - B01J 8/0496: {Heating or cooling the reactor} - B01J 23/42: Platinum - B01J 27/13: Platinum group metals - B01J 29/068: Noble metals - B01J 29/60: of the type L, as exemplified by patent document US3216789 - B01J 29/62: Noble metals - B01J 37/0201: {Impregnation} - B01J 2208/00548: Flow - B01J 2208/00761: Discharging - B01J 2208/00814: the particulate material being provides in prefilled containers - B01J 2208/00884: Means for supporting the bed of particles, e.g. grids, bars, perforated plates - B01J 2208/00893: Feeding means for the reactants - B01J 2208/00938: Flow distribution elements - B01J 2208/025: Two or more types of catalyst - B01J 2229/186: not in framework positions - B01J 2229/42: Addition of matrix or binder particles - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS ## Abstract A bi-modal radial flow reactor comprising: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones including an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and at least two catalyst zones, including an outer catalyst zone and an inner catalyst zone, wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the at least three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the at least three annulus vapor zones. ## Claims ### Claim 1 A bi-modal radial flow reactor comprising: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones and at least two catalyst zones, wherein the at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, and wherein the at least three annulus vapor zones comprise an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the at least three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the at least three annulus vapor zones. ### Claim 2 (depends on 1) The bi-modal radial flow reactor of claim 1, wherein the bi-modal radial flow reactor is a fixed bed bi-modal radial flow reactor, wherein the inner catalyst zone and the outer catalyst zone are configured as fixed beds. ### Claim 3 (depends on 2) The bi-modal radial flow reactor of claim 2, wherein the fixed beds are provided by fixed catalyst baskets. ### Claim 4 (depends on 2) The bi-modal radial flow reactor of claim 2 having a diameter in the range of from about 3 feet 0.91 meters) to about 10 feet (3.05 meters), a height of each of the two catalyst zones in the range of from about 10 feet (3.05 meters) to about 30 feet (9.14 meters), or both. ### Claim 5 (depends on 1) The bi-modal radial flow reactor of claim 1, wherein the bi-modal radial flow reactor is a removable catalyst basket bi-modal radial flow reactor, wherein the inner catalyst zone and the outer catalyst zone are configured as removable catalyst baskets, with the inner catalyst zone provided by an inner removable catalyst basket and the outer catalyst zone provided by an outer removable catalyst basket. ### Claim 6 (depends on 5) The bi-modal radial flow reactor of claim 5, wherein the removable catalyst baskets are extractable via a top end of the cylindrical outer housing. ### Claim 7 (depends on 1) The bi-modal radial flow reactor of claim 1, wherein the manifold is operable to reverse the flow such that the feed can be introduced into the remaining one or two of the at least three annulus vapor zones, and the product can be removed from the one or two of the at least three annulus vapor zones. ### Claim 8 (depends on 7) The bi-modal radial flow reactor of claim 7, wherein the manifold further comprises valves whereby the feed can be introduced into each of at least two inlets of the one or two of the at least three annulus vapor zones at a time. ### Claim 9 (depends on 1) The bi-modal radial flow reactor of claim 1, wherein at least one of the at least two catalyst zones contains a reforming catalyst capable of catalyzing the conversion of at least a portion of convertible hydrocarbons in the feed into aromatic hydrocarbons that are present in the product. ### Claim 10 (depends on 9) The bi-modal radial flow reactor of claim 9, wherein the inner catalyst zone comprises a catalyst that is different from a catalyst in the outer catalyst zone in at least one parameter selected from the group consisting of size, shape, composition, and loading. ### Claim 11 A bi-modal radial flow guard bed reactor comprising: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least two annulus vapor zones, at least two catalyst zones, and a bed separation zone, wherein the at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, wherein the at least two annulus vapor zones comprise an outer annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the bed separation zone, and wherein the inner catalyst zone is intercalated with the bed separation zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of the outer annulus vapor zone, and remove a product from a bottom end of the central annulus vapor zone. ### Claim 12 (depends on 11) The bi-modal radial flow guard bed reactor of claim 11, wherein the inner catalyst zone and the outer catalyst zone are configured as removable catalyst baskets, with the inner catalyst zone provided by an inner removable catalyst basket and the outer catalyst zone provided by an outer removable catalyst basket. ### Claim 13 (depends on 11) The bi-modal radial flow guard bed reactor of claim 11, wherein at least one of the at least two catalyst zones contains a catalyst capable of catalyzing the conversion of at least a portion of convertible hydrocarbons in the feed into aromatic hydrocarbons that are present in the product. ### Claim 14 (depends on 11) The bi-modal radial flow guard bed reactor of claim 11, wherein the inner catalyst zone comprises a different catalyst than the outer catalyst zone. ### Claim 15 A bi-modal radial flow reactor comprising: a cylindrical outer housing surrounding five cylindrical, concentric zones, including three annulus vapor zones and two catalyst zones, wherein the two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, wherein the inner catalyst zone and the outer catalyst zone are configured as removable catalyst baskets, and wherein the three annulus vapor zones comprise an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the three annulus vapor zones. ### Claim 16 (depends on 15) The bi-modal radial flow reactor of claim 15, wherein at least one of the two catalyst zones contains a reforming catalyst capable of catalyzing the conversion of at least a portion of convertible hydrocarbons in the feed into aromatic hydrocarbons that are present in the product. ### Claim 17 A reactor system comprising a bi-modal radial flow guard bed reactor, at least one removable catalyst basket bi-modal radial flow reactor, and at least one fixed bed bi-modal radial flow reactor, wherein the bi-modal radial flow guard bed reactor is upstream of the at least one removable catalyst basket bi-modal radial flow reactor, and wherein the at least one removable catalyst basket bi-modal radial flow reactor is upstream of the at least one fixed bed bi-modal flow radial reactor, wherein the at least one removable catalyst basket bi-modal radial flow reactor and the at least one fixed bed radial flow reactor comprise: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones and at least two catalyst zones, wherein the at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, and wherein the at least three annulus vapor zones comprise an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the at least three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the at least three annulus vapor zones, wherein the inner catalyst zone and the outer catalyst zone of the fixed bed bi-modal radial flow reactor are configured as fixed beds; and wherein the inner catalyst zone and the outer catalyst zone of the at least one removable catalyst basket bi-modal radial flow reactor are configured as removable catalyst baskets, with the inner catalyst zone provided by an inner removable catalyst basket and the outer catalyst zone provided by an outer removable catalyst basket, and wherein the bi-modal radial flow guard bed reactor comprises: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least two annulus vapor zones, at least two catalyst zones, and a bed separation zone, wherein the at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, wherein the at least two annulus vapor zones comprise an outer annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the bed separation zone, and wherein the inner catalyst zone is intercalated with the bed separation zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of the outer annulus vapor zone, and remove a product from a bottom end of the central annulus vapor zone. ### Claim 18 (depends on 17) The reactor system of claim 17, comprising three removable catalyst basket bi-modal radial flow reactors, and three fixed bed bi-modal radial flow reactors, wherein the at least one removable catalyst basket bi-modal radial flow reactor and the at least one fixed bed radial flow reactor comprise: a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones and at least two catalyst zones, wherein the at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone, and wherein the at least three annulus vapor zones comprise an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, and wherein the outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and wherein the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone; and a manifold configured to introduce a feed vertically into a bottom end of each of one or two of the at least three annulus vapor zones, and remove a product from a bottom end of each of the one or two remaining of the at least three annulus vapor zones, wherein the inner catalyst zone and the outer catalyst zone of the fixed bed bi-modal radial flow reactor are configured as fixed beds; and wherein the inner catalyst zone and the outer catalyst zone of the at least one removable catalyst basket bi-modal radial flow reactor are configured as removable catalyst baskets, with the inner catalyst zone provided by an inner removable catalyst basket and the outer catalyst zone provided by an outer removable catalyst basket. ### Claim 19 (depends on 18) The reactor system of claim 18, wherein the volume of each of the three removable catalyst basket bi-modal radial flow reactors is less than the volume of each of the three fixed bed bi-modal flow radial reactors. ### Claim 20 (depends on 17) The reactor system of claim 17, wherein the at least one removable catalyst basket bi-modal flow radial flow reactor of and the at least one fixed bed bi-modal flow radial reactor of contain a reforming catalyst capable of catalyzing the conversion of at least a portion of convertible hydrocarbons in a feed thereto into aromatic hydrocarbons that are present in a product thereof.