Method for producing polycarbonate-polyorganosiloxane copolymer
AssigneeIdemitsu Kosan Co., Ltd.
InventorsTomoko Abe, Yasuhiro Ishikawa, Yohei Koori, Masaru Nakagawa
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Abstract
Provided is a method of producing a polycarbonate-polyorganosiloxane copolymer, including a step (Q) of causing a polycarbonate oligomer and at least one of polyorganosiloxanes represented by the following general formulae (i) to (iii) to react with each other in an organic solvent, in which in the step, a solid content weight x (g/L) of the polycarbonate oligomer in 1 L of a mixed solution of the organic solvent and the polycarbonate oligomer, a concentration y (mass %) of the polyorganosiloxane in the polycarbonate-polyorganosiloxane copolymer to be obtained, and a chain length n of the polyorganosiloxane satisfy specific conditions.
Claims14
A method of producing a polycarbonate-polyorganosiloxane copolymer, comprising a step (Q) of causing a polycarbonate oligomer and at least one of polyorganosiloxanes represented by the following general formulae (i) to (iii) to react with each other in an organic solvent, wherein in the step, a solid content weight x (g/L) of the polycarbonate oligomer in 1 L of a mixed solution of the organic solvent and the polycarbonate oligomer, a concentration y (mass %) of the polyorganosiloxane in the polycarbonate-polyorganosiloxane copolymer to be obtained, and a chain length n of the polyorganosiloxane satisfy any one of conditions described by following formulae (I-I), (I-II), (I-III), (II-I), (II-II), (II-III), (III-I), and (IV-I):
- 36≤n<75,15≤y<26,80≤x<190, (I-I):
- 36≤n<75,26≤y≤35,80≤x≤170, (I-II):
- 36≤n<75,35<y≤50,80≤x≤130, (I-III):
- 75≤n≤110,10≤y<20,80≤x≤190, (II-I):
- 75≤n≤110,20≤y≤30,80≤x≤145, (II-II):
- 75≤n≤110,30<y≤50,80≤x≤130, (II-III):
- 110<n≤200,5≤y≤15,130≤x≤185, (III-I):
- 200<n≤350,5≤y≤10,130≤x≤185 (IV-I):
- wherein R3 to R6 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and a plurality of R3, R4, R5 or R6 may be identical to or different from each other, Y represents —R7O—, —R7COO—, —R7NH—, —R7NR8—, —COO—, —S—, —R7COO—R9—O—, or —R7O—R10—O—, and a plurality of Y may be identical to or different from each other, the R7 represents a single bond, a linear, branched or cyclic alkylene group, an aryl-substituted alkylene group, a substituted or unsubstituted arylene group, or a diarylene group, R8 represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group, R9 represents a diarylene group, R10 represents a linear, branched, or cyclic alkylene group, or a diarylene group, Z represents a hydrogen atom or a halogen atom, and a plurality of Z may be identical to or different from each other, β represents a divalent group derived from a diisocyanate compound, or a divalent group derived from a dicarboxylic acid or a halide of a dicarboxylic acid, n represents the chain length of the polyorganosiloxane, and n−1, and p and q each represent a number of repetitions of a polyorganosiloxane unit and each represent an integer of 1 or more, and a sum of p and q is n−2.
Dependencies are inferred from the claim text.