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US 10,472,458 B2Granted
Stabilizer for polymer polyol production processes
AssigneeBASF SE
InventorsChristian Koenig, Dejan Petrovic
Life of this patent
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Abstract
This invention relates to a stabilizer for polymer polyol production processes, its production and use.
Claims13
A process for producing a polymer polyol dispersion by melt emulsification, the process comprising:
- physically mixing a polymer melt and a polyol in the presence of a stabilizer (S),
- wherein the stabilizer (S) comprises, based on the total weight of the stabilizer (S):
- from 10 to 59 wt % of a polyether polyol P2 having a number average molecular weight, Mn, of 1,000-6,000 g/mol;
- and
- a polyol CSP consisting of, in reacted form, a macromere M, styrene, acrylonitrile, optionally an initiator, and optionally a chain transfer agent, wherein the macromere M, styrene, acrylonitrile, optional initiator, and optional chain transfer agent are reacted in the presence of the polyol P2, to obtain the polyol CSP,
- wherein the content of macromere M in the stabilizer (S) is between 35 to 54 wt %, based on the total weight of the stabilizer (S),
- wherein the content of styrene in the stabilizer (S) is between 4 to 15 wt %, based on the total weight of the stabilizer (S),
- wherein the content of acrylonitrile in the stabilizer (S) is between 2 to 7 wt %, based on the total weight of the stabilizer (S),
- wherein the macromere M is obtained by reacting 1,1-dimethyl meta isopropenyl benzyl isocyanate (TMI) with a polyether polyol PM, optionally in the presence of a Lewis acid catalyst, and
- wherein the stabilizer (S) comprises no additional solvent.
7 more elements
Dependencies are inferred from the claim text.