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US 10,465,032 B2Granted
Radiation-curable coating compounds consisting of a plurality of components, and the use of same in release-coated substrates
AssigneeEvonik Degussa GmbH
InventorsHardi Doehler, Mike Brand
Life of this patent
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Abstract
A composition contains at least one siloxane having ethylenically unsaturated, radically-polymerizable groups, and at least one hydrocarbon having 2 to 6 ethylenically-unsaturated, radically-polymerizable groups, and can be used as a release coating, said composition allowing a good degree of release behavior from adhesive compounds while at the same time also achieving a high level of adhesion of the coating to the carrier material.
Claims10
A composition, comprising:
- (I) 1 to 90 wt %, based on the sum of all components of the composition, of one or more compounds consisting of the elements carbon, hydrogen and oxygen and having 2 to 6 ethylenically unsaturated, radically polymerizable groups and at least one oxyethylene group,
- (II) 10 to 99 wt %, based on the sum of all components of the composition, of one or more organo-modified silicones of formula (I),
- M1aM2bD1cD2d (I)
- wherein
- M1=[R13SiO1/2],
- M2=[R12R2SiO1/2],
- D1=[R12SiO2/2],
- D2=[R1R2SiO2/2],
- a=0 to 2,
- b=0 to 2, and a+b=2,
- c=50 to 490,
- d=0 to 15,
- the ratio of the sum (b+d) to the sum (c+d+2) is from 0.004 up to 0.1;
- the sum (c+d+2) is from 50 to 500,
- R1 denotes identical or different aliphatic hydrocarbons having 1 to 10 carbon atoms or aromatic hydrocarbons having 6 to 12 carbon atoms, and
- R2 denotes identical or different hydrocarbons which have 1 to 5 identical or different ester functions, the hydrocarbon being linear, cyclic, branched and/or aromatic, and the ester functions being selected from ethylenically unsaturated, radically polymerizable ester functions and from ester groups which are not radically polymerizable;
- (III) 0 to 70 wt %, based on the sum of all components of the composition, of one or more organomodified silicones having 4 to 40 silicon atoms, where 15% to 100% of the silicon atoms have ethylenically unsaturated, radically polymerizable groups.
14 more elements
Dependencies are inferred from the claim text.