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US 10,465,019 B2Granted
Catalysts for preparation of ultra high molecular weight polyethylene (UHMWPE) and process for preparation thereof
AssigneeCouncil of Scientific and Industrial Research
InventorsSamir Hujur Chikkali, Ketan Patel
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Abstract
The present invention relates to novel polymerization catalysts. More particularly, the present invention relates to a novel catalysts for the preparation of ultra high molecular weight polyethylene (UHMWPE) and process for preparation thereof. The present invention further relates to a process for the preparation of disentangled ultra high molecular weight polyethylene (dis-UHM-WPE).
Claims37
An olefin polymerization catalyst comprising a metal complex of Formula (I)
- wherein
- M is a transition metal atom of Group 3 to Group 11 of the periodic table;
- A is sulfonate (SO3) or carboxylate (CO2);
- when n=0, D=N═CH—or when n=1, D=N;
- X=Cl, Br, I, BF4, or OAc;
- and
- R, and R1 to R4 are the same or different, and are each a hydrogen atom, a halogen atom, a hydrocarbon group, a heterocyclic group, an oxygen-containing group, a nitrogen-containing group, a boron-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group or a tin-containing group, and two or more of them may be bonded to each other to form a ring.
4 more elements
Dependencies are inferred from the claim text.