Catalytic gasification to produce methanol

A process for generating a methanol synthesis feed gas from a non-gaseous carbonaceous material and a hydromethanation catalyst, the process comprising the steps of:

• a) preparing a carbonaceous feedstock from the non-gaseous carbonaceous material;
• b) introducing the carbonaceous feedstock, a hydromethanation catalyst, high-pressure, superheated steam, oxygen into a hydromethanation reactor;
• c) reacting the carbonaceous feedstock in the hydromethanation reactor at an operating temperature from about 800° F. (about 427° C.) up to about 1500° F. (about 816° C.), and an operating pressure of at least about 250 psig (about 1825 kPa), to produce a by-product char, and a methane-enriched raw product gas comprising methane, carbon monoxide, hydrogen, carbon dioxide, hydrogen sulfide, steam, ammonia, heat energy and entrained fines;
• d) withdrawing a stream of the by-product char from the hydromethanation reactor as the by-product char stream, wherein the by-product char stream comprises a carbon content and entrained hydromethanation catalyst;
• e) (1) removing a substantial portion of the entrained fines from the methane-enriched raw product gas to form a recovered primary fines stream and a fines-depleted methane-enriched raw product gas stream comprising methane, carbon monoxide, carbon dioxide, hydrogen, hydrogen sulfide, steam, ammonia, heat energy, and residual entrained fines and (2) removing residual entrained fines from the fines-depleted methane-enriched raw product gas stream to form a recovered secondary fines stream and a fines-cleaned methane-enriched raw product gas;
• f) cooling the fines-cleaned methane-enriched raw product gas to generate steam and a cooled stream;
• g) removing additional particulates from the cooled stream to generate a particle-depleted cooled gas;
• h) generating the methanol synthesis feed gas having a module number of 1.75 to 2 by:
• (i) using autothermal reforming by the steps of:
• A) further cooling the particle-depleted cooled gas to generate steam, then recovering the ammonia present in the cooled effluent in an ammonia recovery system to generate an ammonia-depleted effluent;
• B) removing a substantial portion of the carbon dioxide and a substantial portion of the hydrogen sulfide from the ammonia-depleted effluent in an acid gas removal unit to produce a sweetened gas, wherein the sweetened gas comprises hydrogen, carbon monoxide and methane, and has greater than 25% methane on a dry, CO2-free basis;
• C) mixing the sweetened gas with high-pressure, superheated steam and heating the mixture to produce a product stream;
• D) mixing the product stream with oxygen and feeding the mixture into an autothermal reformer unit to form an effluent gas;
• and
• E) cooling the effluent gas to generate steam and a methanol synthesis feed gas, wherein the methanol synthesis feed gas comprises hydrogen, carbon monoxide and carbon dioxide;
• or
• (ii) using cryogenic separation and co-producing substitute natural gas by the steps of:
• A) forming a hydrogen-enriched raw product gas by
• I) introducing a portion of the particle-depleted cooled gas into a water-gas shift reactor and steam shifting at least a portion of the carbon monoxide to generate an effluent gas;
• and
• II) combining the remaining portion of the particle-depleted cooled gas with the effluent gas generated by steam shifting to form hydrogen-enriched raw product gas;
• with the proviso that part A is carried out only when the module number of the methanol synthesis feed gas produced in part E is less than 1.75;
• B) cooling the particle-depleted cooled gas, or the hydrogen-enriched raw product gas, if present, to generate steam and a cooled effluent;
• C) recovering the ammonia present in the cooled effluent in an ammonia recovery system to generate an ammonia-depleted effluent;
• D) removing a substantial portion of the carbon dioxide and a substantial portion of the hydrogen sulfide from the ammonia-depleted effluent in acid gas removal unit to produce a sweetened gas;
• and
• E) feeding the sweetened gas into a cryogenic separator and separating the gas into a substitute natural gas stream and a methanol synthesis feed gas.