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US 10,463,391 B2Granted
Magnetic ferrocenyl-functionalized nanoparticle
AssigneeKing Fahd University of Petroleum and Minerals
InventorsM. Nasiruzzaman Shaikh, Md. Abdul Aziz, Aasif Helal
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Abstract
A functionalized magnetic nanoparticle including an organometallic sandwich compound and a magnetic metal oxide. The functionalized magnetic nanoparticle may be reacted with a metal precursor to form in a catalyst for various C—C bond forming reactions. The catalyst may be recovered with ease by attracting the catalyst with a magnet.
Claims5
A magnetic nanoparticle functionalized with a ferrocenyl group, comprising:
- a complex represented by Formula (IIIA), Formula (IIIB), Formula (IVA), or Formula (IVB);
- and
- an iron(III) oxide nanoparticle;
- wherein the complex represented by Formula (IIIA) Formula (IIIB), Formula (IVA), or Formula (IVB) is:
- where each of R1, R2, R3, and R4 is independently a hydrogen, an optionally substituted alkyl, or an optionally substituted aryl;
- each of R6 and R7 is independently a hydrogen, an optionally substituted alkyl, an optionally substituted aryl, an optionally substituted arylalkyl, an optionally substituted alkoxy, or an optionally substituted aryloxy;
- each of R8 is an optionally substituted alkyl, an optionally substituted aryl, or an optionally substituted arylalkyl;
- R9 is a single bond, a hydrogen, an optionally substituted alkyl, an optionally substituted aryl, or an optionally substituted arylalkyl;
- R9′ is a —O—, hydrogen, an optionally substituted alkyl, an optionally substituted aryl, an optionally substituted arylalkyl, an optionally substituted alkoxy, an optionally substituted aryloxy, or an optionally substituted arylalkoxy;
- a and b are independently an integer in a range of 1-10;
- X is O or NH;
- M is iron;
- W is an optionally substituted arylene;
- and
- wherein an oxygen atom in —OR9 group in the complex represented by Formula (IIIA), Formula (IIIB), Formula (IVA), or Formula (IVB) is bound to a surface of the nanoparticle.
12 more elements
Dependencies are inferred from the claim text.