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US 10,457,800 B2Granted
Polyethylene composition having high mechanical properties and processability
AssigneeBasell Polyolefine GmbH
InventorsIakovos Vittorias, Bernd Lothar Marczinke, Gerhardus Meier, Ulf Schüller, Andreas Maus, Diana Dötsch, Jens Wiesecke, Harilaos Mavridis
Life of this patent
Estimating the term…
Abstract
A polyethylene composition having the following features: 1) density from about 0.945 to about 0.951 g/cm3, determined according to ISO 1183 at 23° C.; 2) ratio MIF/MIP from about 25 to about 43; 3) MIF from about 3.5 to less than about 8.5 g/10 min.; 4) HMWcopo index from about 1 to about 40; and 5) long-chain branching index, LCBI, equal to or greater than about 0.83. The polyethylene composition can be used to produce pipes.
Claims10
A polyethylene composition comprising:
- A) from about 30 to about 70 wt. %, based on the total weight of the polyethylene composition, of an ethylene polymer, wherein the ethylene polymer is an ethylene homopolymer or copolymer having a density equal to or greater than about 0.960 g/cm3 and melt flow index MIE at 190° C. with a load of 2.16 kg, according to ISO 1133, of about 50 to 100 g/10 min.;
- B) from about 30 to about 70 wt. %, based on the total weight of the polyethylene composition, of a second ethylene polymer, wherein the second ethylene polymer is a copolymer having a MIE value lower than the MIE value of component A),
- wherein the polyethylene composition has:
- 1) a density from about 0.945 to about 0.951 g/cm3, determined according to ISO 1183 at 23° C.;
- 2) a ratio MIF/MIP from about 25 to about 43, where MIF is the melt flow index at 190° C. with a load of 21.60 kg, and MIP is the melt flow index at 190° C. with a load of 5 kg, both determined according to ISO 1133;
- 3) a MIF from about 3.5 to less than 8.5 g/10 min.;
- 4) a HMWcopo index from about 1 to about 40;
- 5) a long-chain branching index, LCBI, equal to or greater than about 0.83;
- wherein the HMWcopo index is determined according to the following formula:
- HMWcopo=(110.02×tmaxDSC)/(10{circumflex over ( )}5)
- where
- (i) η0.02 is the complex viscosity of a melt in Pa·s, measured at a temperature of 190° C., in a parallel-plate rheometer under dynamic oscillatory shear mode with an applied angular frequency of 0.02 rad/s;
- (ii) tmaxDSC is the time in minutes to reach the maximum value of heat flow of crystallization at a temperature of 124° C. under quiescent conditions, measured in isothermal mode in a differential scanning calorimetry apparatus;
- and
- (iii) LCBI is the ratio of the measured mean-square radius of gyration Rg, measured by GPC-MALLS, to the mean-square radius of gyration for a linear PE having the same molecular weight.
12 more elements
Dependencies are inferred from the claim text.