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US 10,442,956 B2Granted
Solvent-free polyurethane liquid membrane
AssigneeSika Technology AG
InventorsHans Häberle, Urs Burckhardt, Ursula Stadelmann
Life of this patent
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Abstract
The present disclosure relates to a two-component composition containing a polymer polyol, a dial chain extender, an aldimine of formula (I), optionally additional polyols and diphenylmethandiisocyanates in the two components. The composition is particularly suitable as a manually applicable solvent-free liquid film for coating and/or sealing floors and roofs. It also has a long open time, cures quickly and without complications in a wide temperature and humidity range, has a high level of strength and is weather resistant.
Claims20
A composition composed of:
- a first component comprising:
- at least one polymer polyol which is a dispersion of a polymer that is solid at room temperature in a polyether polyol that is liquid at room temperature,
- at least one diol chain extender
- and optionally other polyols;
- and
- a second component comprising:
- monomeric diphenylmethane diisocyanate;
- where at least one of the first component and the second component additionally comprises at least one aldimine of the formula (I),
- where
- A is an (m+n)-valent hydrocarbon moiety which optionally comprises ether units and which has from 2 to 20 C atoms,
- X is O or N—R5,
- R1 and R2 are mutually independently respectively a monovalent hydrocarbon moiety having from 1 to 12 C atoms, or together are a divalent hydrocarbon moiety which has from 4 to 12 C atoms and which is part of an optionally substituted carbocyclic ring having from 5 to 8;
- R3 is a hydrogen atom or is an alkyl or arylalkyl or alkoxycarbonyl moiety having from 1 to 12 C atoms;
- R4 is a monovalent hydrocarbon moiety which has from 6 to 20 C atoms and which optionally comprises ether units or aldehyde units;
- R5 is a monovalent hydrocarbon moiety which has from 1 to 30 C atoms and which optionally comprises at least one carboxylic ester group, nitrile group, nitro group, phosphonic ester group, sulfonic group or sulfonic ester group, or a group of the formula
- and
- m is 0 or 1, and n is 1 or 2 or 3, with the proviso that m+n is 2 or 3.
14 more elements
Dependencies are inferred from the claim text.