# US 10,441,853 B2 · Multi-piece solid golf ball

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- Number: US 10,441,853 B2
- Document ID: US10441853B2
- Status: Granted
- Kind: B2
- Application number: 15/880,649
- Filed: 2018-01-26
- Published: 2018-09-13
- Granted: 2019-10-15
- Earliest claimed: 2017-03-10
- Assignees: Bridgestone Sports Co., Ltd.
- Applicants: Bridgestone Sports Co., Ltd.
- Inventors: Hideo Watanabe
- Web page: https://patentgrep.com/patent/US10441853B2

## CPC

- A63B 37/0092: {Hardness distribution amongst different ball layers}
- A63B 37/0024: {Materials other than ionomers or polyurethane}
- A63B 37/0031: {Hardness}
- A63B 37/0043: {Hardness}
- A63B 37/00621: {Centre hardness}
- A63B 37/00622: {Surface hardness}
- A63B 37/0063: {Hardness gradient}
- A63B 37/0065: {Deflection or compression}
- A63B 37/0076: {Multi-piece balls, i.e. having two or more intermediate layers}
- A63B 37/0083: {Weight; Mass}
- A63B 37/0087: {Deflection or compression}
- A63B: APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT (apparatus for passive exercising, massage A61H)

## Abstract

In a multi-piece solid golf ball having a core and four successive layers encasing the core—an inner envelope layer, an outer envelope layer, an intermediate layer and a cover, the inner envelope, outer envelope and intermediate layer are each formed of different highly neutralized resin materials, and the cover thickness is larger than the respective thicknesses of the inner envelope layer, outer envelope layer and intermediate layer. Also, the value (A)−(B) obtained by subtracting the material hardness (B) of the softest layer among the inner envelope layer, outer envelope layer and intermediate layer from the material hardness (A) of the cover is a Shore D hardness of 13 or more. This golf ball holds down the spin rate on full shots with a driver by amateur golfers having modest head speeds, and also has a soft and good feel at impact.

## Claims

### Claim 1

A multi-piece solid golf ball comprising a core and four successive layers encasing the core—an inner envelope layer, an outer envelope layer, an intermediate layer and a cover, wherein the inner envelope layer, the outer envelope layer and the intermediate layer are each formed of different highly neutralized resin materials; the cover has a larger thickness than the respective thicknesses of the inner envelope layer, the outer envelope layer and the intermediate layer; and the value (A)−(B) obtained by subtracting the material hardness (B) of the softest layer among the inner envelope layer, the outer envelope layer and the intermediate layer from the material hardness (A) of the cover is a Shore D hardness of 13 or more, wherein the value obtained by subtracting the core surface hardness from the surface hardness of the inner envelope layer-encased sphere, expressed in terms of the Shore D hardness, is from 0 to 10, and the material hardness of the cover on the Shore D hardness scale is at least 58, and the material hardnesses of the respective layers and the center hardness of the core satisfy the following condition:
cover material hardness>intermediate layer material hardness>outer envelope layer material hardness>inner envelope layer material hardness>core center hardness, and
wherein the golf ball has a five-piece construction consisting of the single core, the single inner envelope layer, the single outer envelope layer, the single intermediate layer and the single cover.

### Claim 2 (depends on 1)

The golf ball of claim 1, wherein the material hardness of the intermediate layer on the Shore D hardness scale is from 50 to 60.

### Claim 3 (depends on 1)

The golf ball of claim 1, wherein the material hardness of the outer envelope layer on the Shore D hardness scale is from 45 to 57.

### Claim 4 (depends on 1)

The golf ball of claim 1, wherein the material hardness of the inner envelope layer on the Shore D hardness scale is from 40 to 52.

### Claim 5 (depends on 1)

The golf ball of claim 1 wherein, letting the JIS-C hardness at the core center be Cc, the JIS-C hardness at a position 5 mm from the core center be C5, the JIS-C hardness at a position 10 mm from the core center be C10, the JIS-C hardness at a position 15 mm from the core center be C15 and the JIS-C hardness at the core surface be Cs, the core has a hardness profile which satisfies the following relationships (i) to (vi):
18≤Cs−Cc (i)
0≤C10−Cc≤10 (ii)
C10−Cc<Cs−C10 (iii)
10<Cs−C10 (iv)
Cs≥68 (v)
Cc≥48 (vi).

### Claim 6 (depends on 5)

The golf ball of claim 5, wherein Cs is from 68 to 80, C15 is from 64 to 78, C10 is from 56 to 67, C5 is from 52 to 63, Cc is from 48 to 62, Cs−C15 is from 1 to 9, C15−C10 is from 4 to 15, C10−C5 is from 1 to 7, C5−Cc is from 0 to 7, (Cs−C10)/(C10−Cc) is from 1.0 to 5.0, and Cs−Cc is from 14 to 30.

### Claim 7 (depends on 1)

The golf ball of claim 1, wherein the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) that is at least 4.0 mm.

### Claim 8 (depends on 1)

The golf ball of claim 1, wherein the core diameter, intermediate layer thickness and cover thickness satisfy the following relationship:
cover thickness>intermediate layer thickness<core diameter.

### Claim 9 (depends on 1)

The golf ball of claim 1, wherein the initial velocities of the sphere (I) consisting of the core encased by the inner envelope layer, the sphere (II) consisting of sphere (I) encased by the outer envelope layer, the sphere (III) consisting of sphere (II) encased by the intermediate layer, and the ball satisfy the following relationships:
ball initial velocity Sphere (III) initial velocity>Sphere (II) initial velocity Sphere (I) initial velocity; and
ball initial velocity>core initial velocity.

### Claim 10 (depends on 1)

The golf ball of claim 1, wherein at least 50 wt % of the total amount of cover material is a high-acid ionomer resin having an acid content of at least 16 wt %.

### Claim 11 (depends on 1)

The golf ball of claim 1, wherein the core is formed from a rubber composition containing compounding ingredients (A) to (C) shown below:
(A) a base rubber
(B) an organic peroxide
(C) water and/or a metal monocarboxylate.

### Claim 12 (depends on 11)

The golf ball of claim 11, wherein the component (C) is water and the amount of water included per 100 parts by weight of the base rubber is from 0.1 to 5 parts by weight.

### Claim 13 (depends on 6)

The golf ball of claim 6, wherein (Cs−C10)/(C10−Cc) is from 1.0 to 2.8.

### Claim 14 (depends on 1)

The golf ball of claim 1, wherein the intermediate layer has a thickness of from 0.4 to 1.0 mm.

### Claim 15 (depends on 1)

The golf ball of claim 1, wherein the thicknesses of the respective layers and the core diameter satisfy the following condition:
the cover thickness>the intermediate layer thickness<the envelope layer outside thickness<the envelope layer inside thickness<the core diameter.

### Claim 16 (depends on 1)

The golf ball of claim 1, wherein the (cover thickness)/(inner envelope layer thickness) value is from 1.1 to 1.8 and the (cover thickness)/(outer envelope layer thickness) value is from 1.1 to 1.8.

### Claim 17 (depends on 1)

The golf ball of claim 1, wherein the total thickness of the layers encasing the core (the cover thickness+the intermediate layer thickness+the outer envelope layer thickness+the inner envelope layer thickness) value is from 3.5 to 5.0 mm.

### Claim 18 (depends on 1)

The golf ball of claim 1, wherein the value obtained by subtracting the surface hardness of the intermediate layer-encased sphere from the surface hardness of the ball, expressed in terms of the Shore D hardness, is from 3 to 15.