Method and device for treating nitroso compound
AssigneeMitsubishi Hitachi Power Systems, Ltd.
InventorsKoichi Yokoyama, Eiji Miyamoto, Jun Shimamura
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Abstract
A method for decomposing a nitroso compound, comprising: adding an aqueous solution containing hydrogen halide to a liquid to be treated that contains the nitroso compound in such a manner that the hydrogen halide is present in an amount of 2 mol or more and 20 mol or less per mol of a nitroso group in the nitroso compound; and subsequently heating the resulting liquid to be treated at a temperature of not lower that 75° C. and not higher than a boiling point of water under ordinary pressure, thereby an amines are recovered.
Claims6
A method for decomposing a nitroso compound, the method comprising:
- adding an aqueous solution containing hydrogen halide to a liquid to be treated that contains the nitroso compound so as to obtain a mixture, wherein an amount of the hydrogen halide in the mixture is 2 mol or more and 20 mol or less per mol of a nitroso group in the nitroso compound;
- and
- subsequently heating the mixture at a temperature of not lower than 75° C. and not higher than 100° C. and under ordinary pressure to decompose the nitroso compound.
A method for decomposing a nitroso compound in a method for recovering carbon dioxide in a gas to be treated, the method comprising:
- a step (I) of bringing a gas to be treated that contains carbon dioxide into contact with a CO2 lean absorption liquid containing amines for absorbing the carbon dioxide into the CO2 lean absorption liquid to obtain a CO2 rich absorption liquid;
- a step (II) of heating the CO2 rich absorption liquid for releasing the carbon dioxide to regenerate the CO2 lean absorption liquid;
- a step (IIIa) of adding an aqueous solution containing hydrogen halide to part of the CO2 lean absorption liquid regenerated in the step (II) that contains the nitroso compound so as to obtain a mixture, wherein an amount of the hydrogen halide in the mixture is 2 mol or more and 20 mol or less per mol of a nitroso group in the nitroso compound contained in the part of the CO2 lean absorption liquid regenerated in the step (II), and subsequently heating the mixture at a temperature of not lower than 75° C. and not higher than 100° C. and under ordinary pressure to decompose the nitroso compound;
- and
- a step (IV) of providing the step (I) with the rest of the CO2 lean absorption liquid regenerated in the step (II) and/or the mixture heated in the step (Ma) to be mixed with the CO2 lean absorption liquid for bringing into contact with the gas to be treated that contains carbon dioxide in the step (I).
A method for decomposing a nitroso compound in a method for recovering carbon dioxide in a gas to be treated, the method comprising:
- a step (I) of bringing a gas to be treated that contains carbon dioxide into contact with a CO2 lean absorption liquid containing amines for absorbing the carbon dioxide into the CO2 lean absorption liquid to obtain a CO2 rich absorption liquid;
- a step (II) of heating the CO2 rich absorption liquid for releasing the carbon dioxide to regenerate the CO2 lean absorption liquid;
- a step (V) of reclaiming a part of the CO2 lean absorption liquid regenerated in the step (II) to remove a heat stable salt;
- a step (IIIb) of adding an aqueous solution containing hydrogen halide to a remaining liquid obtained in the step (V) that contains the nitroso compound so as to obtain a mixture, wherein an amount of the hydrogen halide in the mixture is 2 mol or more and 20 mol or less per mol of a nitroso group in the nitroso compound contained in the remaining liquid, and subsequently heating the mixture at a temperature of not lower than 75° C. and not higher than 100° C. and under ordinary pressure to decompose the nitroso compound and recover amines;
- and
- a step (IV) of providing the step (I) with the rest of the CO2 lean absorption liquid regenerated in the step (II) and/or the amines recovered in the step (IIIb) to be mixed with the CO2 lean absorption liquid for bringing into contact with the gas to be treated that contains carbon dioxide in the step (I).
Dependencies are inferred from the claim text.