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US 10,407,625 B2Granted
Device, process, and catalyst intended for desulfurization/demercaptanization/dehydration of gaseous hydrocarbons
AssigneeStart-Catalyst LLC
InventorsLiudmila Aleksandrovna Tyurina, Alexander Ivanovich Tyurin, Irina Gennadievna Tarkhanova, Alexey Aleksandrovich Tyurin
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Abstract
This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc, including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.
Claims11
A process of desulfurization and/or demercaptanization and/or dehydration of gaseous hydrocarbons, comprising:
- mixing one or more gaseous hydrocarbons comprising an initial amount of hydrogen sulfide, mercaptans, and water, to be purified with an oxygen-containing gas,
- pressurizing and passing through a reactor loaded with a solution of a catalyst for oxidating the hydrogen sulfide and mercaptans in an absorbent that also provides for dehydration of said gaseous hydrocarbons,
- maintaining a gas pressure, as determined by a desired content of water in purified gas thereby simultaneously dehydrating the gaseous hydrocarbons,
- wherein the catalyst comprises mixed-ligand complexes of transition metals,
- wherein the catalyst comprises an amine, dimethylformamide (DMF), and CuCl2*2H2O, and
- producing an end product having a residual mercaptan concentration of 10 ppm or less and a residual hydrogen sulfide concentration of 10 ppm or less.
3 more elements
Dependencies are inferred from the claim text.