A film having a metallic luster, said film comprising a thiophene polymer having a distribution peak of weight-average molecular weight of from 200-30000, is doped with at least one of a perchlorate ion and chloride ion and is polymerized by chemical polymerization from at least one of alkoxy thiophene and alkyl thiophene, whose number of carbon is 1 or 2,
- wherein said thiophene polymer has a layer-like orientation regular structure which is formed by said chemical polymerization and
- three peaks are derived from said layer-like orientational regular structure of said thiophene polymer in the range from 5 to 30 degrees by X-ray diffraction measurement.