Nanoparticle-containing solution and use thereof
AssigneeSekisui Plastics Co., Ltd.
InventorsJunko Kubo, Takashi Motomura, Shuichi Sasahara
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Abstract
A nanoparticle-containing solution comprising nanoparticles of a metal oxide, and a solution obtained by dissolving, in an organic solvent, a phosphoric acid ester and a reactive group-containing carbonyl compound as hydrophobic treatment agents, the phosphoric acid ester having an alkylene oxide chain, and an alkyl group or allyl group at an end, and the reactive group-containing carbonyl compound having at least a vinyl group and a carboxyl group or cyclic ester group, and having a solubility parameter calculated by Fedors' method of 10.0 to 12.5.
Claims8
Nanoparticle-containing resin particles comprising:
- a resin, and
- metal oxide nanoparticles dispersed within the resin,
- the metal oxide nanoparticles being hydrophobized with a phosphoric acid ester and a reactive group-containing carbonyl compound, wherein:
- the phosphoric acid ester is a compound represented by the following general formula (I):
- where:
- R1 is an alkyl group having 8 to 13 carbon atoms or an allyl group,
- R2 is H or CH3,
- n is 1 to 30, and
- the compound is a mixture in which a combination of a and b is a combination of 1 and 2 or 2 and 1;
- and
- the reactive group-containing carbonyl compound is selected from:
- a reactive group-containing carboxylic acid represented by the following general formula (II):
- CH2═CR3—Z—COOH (II)
- where:
- R3 is H or CH3, and
- Z is a divalent hydrocarbon group of 5 or more carbon atoms optionally containing an ester group;
- and
- a reactive group-containing cyclic ester represented by the following general formula (III):
- CH2═CR3—X-M (III)
- where:
- R3 is H or CH3,
- X is a divalent hydrocarbon group of 1 or more carbon atoms optionally containing an ester group, and
- M is a lactone or a lactide.
Dependencies are inferred from the claim text.