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US 10,377,889 B2Granted
Thermoplastic elastomer composition and production process for the same
AssigneeMitsui Chemicals, Inc.
InventorsHayato Kurita, Kazuyoshi Kaneko, Masahiro Enna, Tatsuya Enomoto, Hideki Mochizuki
Life of this patent
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Abstract
A thermoplastic elastomer composition obtained by dynamically crosslinking an ethylene/α-olefin/non-conjugated polymer copolymer (A), a polyolefin resin (B), a softener (C) in an amount of 1 to 200 parts by mass per 100 parts by mass of the total of the copolymer (A) and the resin (B), and a crosslinking agent (D) by the use of a batch mixer under the conditions satisfying the requirements (1) to (4).
Claims4
A production process for a thermoplastic elastomer composition, comprising dynamically crosslinking
- an ethylene/α-olefin/non-conjugated polyene copolymer (A),
- a polyolefin resin (B),
- a softener (C) in an amount of 1 to 200 parts by mass per 100 parts by mass of the total of the copolymer (A) and the resin (B), and
- a crosslinking agent (D),
- by the use of a batch mixer under the conditions satisfying the following requirements (1) to (4):
- 50≤P1≤300 (1)
- wherein P1 is defined by the following formula (i):
- [Math. 1]
- P1=γave.×Log(t1) (i)
- wherein the residence time (sec) after the introduction of the crosslinking agent (D) is denoted as t1 sec, and the average rate (sec−1) of shear rates γ in the t1 is denoted as γave. sec−1,
- 900≤P2≤1450 (2)
- wherein P2 is defined by the following formula (ii):
- [Math. 2]
- P2=(Tave.+273)×Log(t1) (ii)
- wherein the average resin temperature (° C.) after the introduction of the crosslinking agent (D) is denoted as Tave. ° C., and the residence time (sec) after the introduction of the crosslinking agent (D) is denoted as t1 sec,
- −2.5≤P3≤1.5 (3)
- wherein P3 is defined by the following formula (iii):
- [Math. 3]
- P3=Log(t1/t2) (iii)
- wherein the residence time (sec) after the introduction of the crosslinking agent (D) is denoted as t1 sec, and the time (sec) required for the residual amount of the crosslinking agent (D) to become not more than 1 ppm of the introduction amount thereof at the average resin temperature Tave. after the introduction of the crosslinking agent (D) is denoted as t2 sec, and
- (4) the crosslinking agent (D) is introduced into the batch mixer after the ethylene/α-olefin/non-conjugated polyene copolymer (A), the polyolefin resin (B) and the softener (C) have been introduced.
18 more elements
Dependencies are inferred from the claim text.