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US 10,377,884 B2Granted
Rubber composition for tyres, and pneumatic tyre
AssigneeSumitomo Rubber Industries, Ltd.
InventorYuka Yokoyama
Life of this patent
Estimating the term…
Abstract
Provided are a rubber composition for tires that shows a balanced improvement in fuel economy, abrasion resistance, wet performance, and handling stability, and a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition for tires containing a modified diene rubber containing a functional group reactive with silica, a fine particle silica having a nitrogen adsorption specific surface area of 180 m2/g or more, and a silane coupling agent represented by a specific formula.
Claims9
A rubber composition for tires, comprising:
- a modified diene rubber containing a functional group reactive with silica;
- a fine particle silica having a nitrogen adsorption specific surface area of 180 m2/g or more and a cetyltrimethylammonium bromide specific surface area of 180 m2/g or more;
- and
- a silane coupling agent represented by the following formula (1):
- [Y1R1Sx—]m[G1(R2SiX1X2X3)a]n[G2]o[R3Y2]p (1)
- wherein each G1 independently represents a C1-C30 polyvalent hydrocarbon group containing a polysulfide group, represented by [(CH2)b—]cR4[—(CH2)dSx—]e;
- each G2 independently represents a C1-C30 polyvalent hydrocarbon group containing a polysulfide group, represented by [(CH2)b—]cR5[—(CH2)dSx—]e;
- each of Y1 and Y2 independently represents a silyl group represented by —SiX1X2X3, a hydrogen atom, a carboxyl group, or an ester group represented by —C(═O)OR6;
- each X1 independently represents —Cl, —Br, —OH, —OR6, or R6C(═O)O—;
- each of X2 and X3 independently represents a hydrogen atom, R6, X1, or a —OSi— containing group formed by silanol condensation;
- each of R1 and R3 independently represents a C1-C20 divalent hydrocarbon group;
- each R2 independently represents a linear hydrocarbon group represented by —(CH2)f—;
- each R4 independently represents a C1-C28 polyvalent hydrocarbon group or a heteroatom-containing C1-C27 polyvalent hydrocarbon group;
- each R5 independently represents a C1-C28 polyvalent hydrocarbon group;
- R6 represents a C1-C20 monovalent hydrocarbon group;
- and
- a, b, c, d, e, f, m, n, o, p, and x are independent from one another, each of a, c, and e represents a number of 1 to 3, each of b and d represents a number of 1 to 5, f represents a number of 0 to 5, each of m and p represents a number of 1 to 100, n represents a number of 1 to 15, o represents a number of 0 to 10, and x represents a number of 1 to 10,
- wherein the modified diene rubber containing a functional group reactive with silica contains at least two selected from the group consisting of a silyl group, an amino group, an amide group, a hydroxy group, and an epoxy group.
15 more elements
Dependencies are inferred from the claim text.