# US 10,374,247 B2 · Porous support, preparation method therefor, and reinforced membrane containing same

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- Number: US 10,374,247 B2
- Document ID: US10374247B2
- Status: Granted
- Kind: B2
- Application number: 15/119,040
- Filed: 2015-02-24
- Published: 2016-12-08
- Granted: 2019-08-06
- Earliest claimed: 2014-02-25
- Assignees: Kolon Fashion Material. Inc.
- Applicants: Kolon Fashion Material. Inc.
- Inventors: Heung Ryul Oh; Sung Jin Kim; Yong Hwan Lee; Hwan Kwon Rho; Chul Ki Kim; Jeong Young Choi; Jun Young Park; Ji Suk Baek
- Web page: https://patentgrep.com/patent/US10374247B2

## CPC

- H01M 8/1062: characterised by the physical properties of the porous support, e.g. its porosity or thickness
- D04H 1/4342: Aromatic polyamides
- D04H 1/43838: {Ultrafine fibres, e.g. microfibres}
- D04H 1/54: by welding together the fibres, e.g. by partially melting or dissolving (in combination with needling D04H1/485)
- D04H 1/728: by electro-spinning {(electro-spinning methods and apparatus D01D5/0007)}
- D06C 3/00: Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics (shaping or stretching tubular fabrics upon cores or internal frames D06C5/00)
- D06C 7/00: Heating or cooling textile fabrics
- D06C 15/00: Calendering, pressing, ironing, glossing or glazing textile fabrics (for making patterns or designs D06C23/00)
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- D04H: MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL (weaving D03; knitting D04B; braiding D04C; net-making D04G; sewing D05B; tufting D05C; finishing non-woven fabrics D06); FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING {; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION}(non-woven fabrics having an intermediate or external layer of a different kind, e.g. of woven fabric, B32B)
- D06C: FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

The present invention relates to a porous support, a preparation method therefor, and a reinforced membrane containing the same, wherein the porous support comprises a nanoweb in which nanofibers are integrated in the form of a nonwoven fabric comprising a plurality of pores, and the nanoweb has an elongation at break of 1-10%. The porous support has excellent air permeability and water permeability, remarkable durability, heat resistance and chemical resistance, and excellent mechanical strength and processability.

## Claims

### Claim 1

A porous support comprising a nanoweb in which nanofibers are integrated in the form of a non-woven fabric including a plurality of pores,
wherein the nanoweb has a porosity of 70 to 95% and an elongation at break of 1 to 10%, and
wherein the nanoweb has a strain of 10 length % or less, said strain being determined by standing a sample of the nanoweb with a width 100 mm and a length of 100 mm at 200° C. for 24 hours and calculating an average of width strain and length strain, before and after standing, and
wherein the nanoweb has an intermediate elongation of 0.7 to 5% under a load of 10.204 gf.

### Claim 2 (depends on 1)

The porous support according to claim 1, wherein the nanoweb has a tensile strength of 10 to 50 MPa.

### Claim 3 (depends on 1)

The porous support according to claim 1, wherein the nanoweb has a mean thickness of 5 to 50 μm.

### Claim 4 (depends on 1)

The porous support according to claim 1, wherein the nanoweb has a basis weight of 2 to 10 g/m2.

### Claim 5 (depends on 1)

The porous support according to claim 1, wherein the nanoweb is a polyimide nanoweb.

### Claim 6

A method of manufacturing a porous support comprising:
spinning a spinning solution to form a nanoweb precursor which includes in which nanofibers are integrated in the form of a non-woven fabric including a plurality of pores; and
curing the nanoweb precursor while transferring the nanoweb precursor by a roll-to-roll method under the condition that a MD tension is equal to a TD tension,
wherein the nanoweb has a strain of 10 length % or less, said strain being determined by standing a sample of the nanoweb with a width 100 mm and a length of 100 mm at 200° C. for 24 hours and calculating an average of width strain and length strain, before and after standing, and
wherein the nanoweb has an intermediate elongation of 0.7 to 5% under a load of 10.204 gf.

### Claim 7 (depends on 6)

The method according to claim 6, wherein the spinning solution is a solution comprising polyamic acid having a solid content of 11.5 to 13.5% by weight.

### Claim 8 (depends on 6)

The method according to claim 6, further comprising calendering the nanoweb precursor at a linear pressure of 80 to 200 kgf/cm before curing the nanoweb precursor.

### Claim 9 (depends on 6)

The method according to claim 6, wherein the curing the nanoweb precursor comprises curing the nanoweb precursor to adjust a transverse direction curing shrinkage of the nanoweb precursor to 5 to 15%.

### Claim 10 (depends on 6)

The method according to claim 6, wherein the curing the nanoweb precursor is carried out at a temperature of 80 to 650° C.

### Claim 11 (depends on 6)

The method according to claim 6, wherein the transferring the nanoweb precursor by a roll-to-roll method comprises transferring the nanoweb precursor by a roll-to-roll method without tension.

### Claim 12 (depends on 6)

The method according to claim 6, wherein the transferring the nanoweb precursor by a roll-to-roll method is carried out while applying a tension identical to tension, which is applied to the machine direction of the nanoweb precursor, in the transverse direction of the nanoweb precursor with a roller, after rolling the nanoweb precursor with the roller.

### Claim 13 (depends on 1)

A reinforced membrane comprising:
the porous support according to claim 1; and
an ion exchange polymer filling pores of the porous support.
