# US 10,374,243 B2 · Porous current collector and fuel cell

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- Number: US 10,374,243 B2
- Document ID: US10374243B2
- Status: Granted
- Kind: B2
- Application number: 15/127,797
- Filed: 2015-02-23
- Published: 2017-04-06
- Granted: 2019-08-06
- Earliest claimed: 2014-03-31
- Assignees: Sumitomo Electric Industries, Ltd.
- Applicants: Sumitomo Electric Industries, Ltd.
- Inventors: Takahiro Higashino; Masatoshi Majima; Hiromasa Tawarayama; Naho Mizuhara; Kazuki Okuno; Chihiro Hiraiwa; Yohei Noda; Masahiro Kato
- Web page: https://patentgrep.com/patent/US10374243B2

## CPC

- H01M 8/0637: Direct internal reforming at the anode of the fuel cell
- H01M 4/9058: {of noble metals or noble-metal based alloys}
- H01M 8/0232: Metals or alloys
- H01M 8/0245: in the form of layered or coated products
- H01M 2008/1293: {Fuel cells with solid oxide electrolytes}
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Provided is a porous current collector which is used for a fuel electrode and has a high gas reforming function and high durability. A porous current collector 9 is provided adjacent to a fuel electrode 4 of a fuel cell 101 that includes a solid electrolyte layer 2, the fuel electrode 4 disposed on one side of the solid electrolyte layer, and an air electrode 3 disposed on the other side. The porous current collector includes a porous metal body 1 and a first catalyst 20. The porous metal body has an alloy layer 12a at least on a surface thereof, the alloy layer containing nickel (Ni) and tin (Sn). The first catalyst, which is in the form of particles, is supported on a surface of the alloy layer, the surface facing pores of the porous metal body, and is capable of processing a carbon component contained in a fuel gas that flows inside the pores.

## Claims

### Claim 1

A porous current collector, which is provided adjacent to a fuel electrode of a fuel cell that includes a solid electrolyte layer, the fuel electrode disposed on one side of the solid electrolyte layer, and an air electrode disposed on the other side, comprising a porous metal body and a first catalyst,
wherein the porous metal body has an alloy layer at least on a surface thereof, the alloy layer containing nickel (Ni) and tin (Sn),
the first catalyst is supported on a surface of the alloy layer, the surface facing pores of the porous metal body, and is capable of processing a carbon component contained in a fuel gas that flows inside the pores,
the first catalyst comprises at least one component selected from silver (Ag) or platinum (Pt),
a second catalyst selected from a nickel-tin alloy or a nickel-tin-chromium (Cr) alloy is supported on the surface of the alloy layer facing the pores of the porous metal body, and the first catalyst is partially dissolved in the alloy layer.

### Claim 2 (depends on 1)

The porous current collector according to claim 1, wherein the first catalyst is supported in the amount of 1% to 15% by mass of the total mass of the porous current collector.

### Claim 3 (depends on 1)

The porous current collector according to claim 1, wherein the content of tin (Sn) in the alloy layer is 5% to 30% by mass.

### Claim 4 (depends on 1)

The porous current collector according to claim 1, wherein the porous metal body has a porosity of 50% to 98%.

### Claim 5 (depends on 1)

The porous current collector according to claim 1, wherein the catalyst has an average particle size of 0.05 μm to 5 μm.

### Claim 6 (depends on 1)

The porous current collector according to claim 1, wherein the porous metal body has a three-dimensional network structure.

### Claim 7 (depends on 6)

The porous current collector according to claim 6, wherein the three-dimensional network structure has a skeleton including a shell portion including the alloy layer containing nickel (Ni) and tin (Sn) at least on a surface thereof and a core portion containing one or both of a hollow and an electrically conductive material, and the skeleton is continuous in an integrated manner.

### Claim 8 (depends on 1)

The fuel cell according to claim 1, wherein the fuel cell comprises the porous current collector.