# US 10,374,158 B2 · Method for making organic light emitting diode > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,374,158 B2 - Document ID: US10374158B2 - Status: Granted - Kind: B2 - Application number: 15/851,924 - Filed: 2017-12-22 - Published: 2019-02-28 - Granted: 2019-08-06 - Earliest claimed: 2017-08-30 - Assignees: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Applicants: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Inventors: Wen Ning; Peng Liu; Kai-Li Jiang; Shou-Shan Fan - Web page: https://patentgrep.com/patent/US10374158B2 ## CPC - H10K 71/50: Forming devices by joining two substrates together, e.g. lamination techniques - H10K 50/16: Electron transporting layers - H10K 50/82: Cathodes - H10K 71/191: {characterised by provisions for the orientation or alignment of the layer to be deposited} - H10K 50/11: characterised by the electroluminescent [EL] layers - H10K 50/15: Hole transporting layers - H10K 50/828: Transparent cathodes, e.g. comprising thin metal layers - H10K 85/221: {Carbon nanotubes} - H10K 2102/331: {Nanoparticles used in non-emissive layers, e.g. in packaging layer} - H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES ## Abstract A method for making an organic light emitting diode includes providing a first carbon nanotube composite structure having a first surface and a second surface opposite to the first surface. The first carbon nanotube composite structure includes a polymer and a plurality of first carbon nanotubes dispersed in the polymer. A preform structure includes a support body, an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order. The preform structure is located on the first surface, wherein the first surface is in direct contact with the organic light emitting layer. A cathode electrode is formed on the second surface. ## Claims ### Claim 1 A method for making an organic light emitting diode, the method comprising: providing a first carbon nanotube composite structure having a first surface and a second surface opposite to the first surface, wherein the first carbon nanotube composite structure comprises a polymer and a plurality of first carbon nanotubes dispersed in the polymer, and a length direction of the plurality of first carbon nanotubes is from the first surface to the second surface; providing a preform structure comprising a support body, an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order; locating the preform structure on the first surface, wherein the first surface is in direct contact with the organic light emitting layer; and forming a cathode electrode on the second surface. ### Claim 2 (depends on 1) The method of claim 1, wherein a method for making the first carbon nanotube composite structure comprising: providing a second carbon nanotube composite structure having a third surface and a fourth surface opposite to the third surface, wherein a vertical distance between the third surface and the fourth surface is defined as a thickness of the second carbon nanotube composite structure, the second carbon nanotube composite structure comprises the polymer and a plurality of second carbon nanotubes dispersed in the polymer, and a length direction of the plurality of second carbon nanotubes is substantially perpendicular to a thickness direction of the second carbon nanotube composite structure; and cutting off the second carbon nanotube composite structure along a direction from the third surface to the fourth surface. ### Claim 3 (depends on 2) The method of claim 2, wherein the cutting off the second carbon nanotube composite structure is performed along the thickness direction. ### Claim 4 (depends on 2) The method of claim 2, wherein a method for making the second carbon nanotube composite structure comprising: providing a substrate having a substrate surface; placing a carbon nanotube structure comprising the plurality of second carbon nanotubes on the substrate surface to form a composite structure, wherein the plurality of second carbon nanotubes is in direct contact with the substrate surface; disposing a monomer solution on the carbon nanotube structure, wherein the monomer solution is formed by dispersing monomers into an organic solvent; polymerizing the monomer; and removing the substrate. ### Claim 5 (depends on 4) The method of claim 4, wherein the plurality of second carbon nanotubes is joined end-to-end by van der Waals attractive force and substantially extends along the same direction. ### Claim 6 (depends on 5) The method of claim 5, wherein the carbon nanotube structure comprises two carbon nanotube films, and an angle between the plurality of second carbon nanotubes in the two carbon nanotube films ranges from about 0 degree to about 90 degrees. ### Claim 7 (depends on 4) The method of claim 4, wherein the plurality of second carbon nanotubes is substantially parallel to the substrate surface. ### Claim 8 (depends on 4) The method of claim 4, wherein a plurality of gaps is defined by the plurality of second carbon nanotubes, and the monomer solution passes through the plurality of gaps and arrive at the substrate surface during disposing the monomer solution. ### Claim 9 (depends on 4) The method of claim 4, wherein the disposing the monomer solution comprises placing the carbon nanotube structure and the substrate in a container having an opening and injecting the monomer solution into the container from the opening. ### Claim 10 (depends on 4) The method of claim 4, wherein disposing the monomer solution to the carbon nanotube structure comprises: locating two composite structures on a base and spacing the two composite structures apart from each other; forming a mold having an opening, by using the substrates of the two composite structures and the base, wherein the carbon nanotube structures of the two composite structures are opposite to each other and inside of the mold. ### Claim 11 (depends on 10) The method of claim 10, wherein the disposing the monomer solution to the carbon nanotube structure comprises injecting the monomer solution into the mold from the opening. ### Claim 12 (depends on 1) The method of claim 1, wherein a length direction of the plurality of first carbon nanotubes is substantially perpendicular to the first surface. ### Claim 13 (depends on 1) The method of claim 1, wherein each of the plurality of first carbon nanotubes comprises a first end and a second end opposite to the first end, the first end is in direct contact with the organic light emitting layer, and the second end is in direct contact with the cathode electrode.