# US 10,373,812 B2 · Enhanced thermonic energy converter and method of use

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- Number: US 10,373,812 B2
- Document ID: US10373812B2
- Status: Granted
- Kind: B2
- Application number: 15/804,118
- Filed: 2017-11-06
- Published: 2018-07-12
- Granted: 2019-08-06
- Earliest claimed: 2013-04-11
- Applicants: William F. Paxton, IV; Jim L. Davidson; Weng P. Kang; Mick E. Howell
- Inventors: William F. Paxton, IV; Jim L. Davidson; Weng P. Kang; Mick E. Howell
- Web page: https://patentgrep.com/patent/US10373812B2

## CPC

- H01J 45/00: Discharge tubes functioning as thermionic generators {(structural combination of fuel element with thermoelectric element G21C3/40; nuclear power plants using thermionic converters G21D7/04; structural combination of a radioactive source with a thermionic converter, e.g. radioisotope batteries G21H1/10; generators in which thermal or kinetic energy is converted into electrical energy by ionisation of a fluid and removal of the charge therefrom H02N3/00)}
- C23C 16/274: {using microwave discharges}
- C23C 16/278: {doping or introduction of a secondary phase in the diamond}
- C23C 16/511: using microwave discharges
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

A thermionic energy converter includes an anode, a cathode spaced from the anode to define a gap therebetween and an operating environment of hydrogen wherein the anode and the cathode are disposed in the hydrogen operating environment so that molecular hydrogen is incorporated into the gap and the anode and the cathode are substantially exposed to the molecular hydrogen. Exposure of diamond samples to a hydrogen plasma reduces the resistance of the bulk diamond film. Hydrogen enhances electron transport through the bulk of the diamond and improves the thermionic emission current. Impregnation of a diamond electrode with hydrogen enhances bulk electron transport of the diamond due to hydrogen lying in the interstitial space between the carbon atoms. Hydrogen increases the bulk conductivity of diamonds films by interact with the diamond surface to form polarized C—H bonds reducing the electron affinity and in turn, reducing the work function. Exposure of diamond cathodes to a low energy hydrogen plasma drastically enhances thermionic emission current relative to as-grown diamond films by up to four orders of magnitude due to surface termination of diamond with hydrogen (i.e. hydrogenation of the diamond surface). Difficulty arises when attempting to utilize hydrogenated diamond electrodes for thermionic generators due to the hydrogen desorbing from the diamond surface following a predictable time-dependent Arrhenius behavior. When hydrogenated diamond cathodes are heated to temperatures above 600° C., the desorption of the performance-enhancing hydrogen begin to decrease with increasing temperature. The present invention provides means for preventing desorption of hydrogen from hydrogenated diamond films at elevated temperatures to overcome the performance-limiting effect of the desorbtion of the hydrogen from the diamond surface by filling the gap between the cathode and anode with molecular hydrogen at a selected specific pressure in equilibrium. The thermionic generator is sealed and pressure remains constant or steady-state so that molecular hydrogen is introduced into the gap at a selected flow rate to replace any molecular hydrogen exiting the gap at the same flow rate whereby a selected pressure and volume of hydrogen is maintained in the gap throughout the process.

## Claims

### Claim 1

A thermal energy conversion device comprising:
a microwave plasma-enhanced chemical vapor deposition reactor;
means for producing a selected kW microwave power;
said reactor including at least one anode selected from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
said reactor including at least one cathode for electron emission spaced apart a selected distance from the anode to define a gap therebetween
said cathode is selected from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
a gaseous species comprising at least molecular hydrogen;
means for heating the cathode in said reactor at a desired temperature;
means for providing a selected pressure within said reactor;
means for monitoring said selected pressure within said reactor;
means for introducing and releasing a selected quantity of the gaseous species to maintain a constant predetermined pressure within said reactor.

### Claim 2

A thermal energy conversion device comprising:
a reactor;
means for producing power;
said reactor including at least one anode selected from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
said reactor including at least one cathode for electron emission spaced apart a selected distance from the anode to define a gap therebetween
said cathode is selected from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
a gaseous species comprising at least molecular hydrogen;
means for heating the cathode in said reactor at a desired temperature;
means for providing a selected pressure within said reactor;
means for monitoring said selected pressure within said reactor;
means for introducing and releasing a selected quantity of the gaseous species to maintain a constant predetermined pressure within said reactor.

### Claim 3

A method of producing energy in a thermal energy conversion device comprising the steps of:
selecting an anode from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
selecting a cathode from the group consisting of a nitrogen-incorporated diamond film, a diamond film, a diamond, a polycrystalline nitrogen-incorporated diamond, and combinations thereof deposited on a selected substrate;
selecting a gaseous species comprising molecular hydrogen;
positioning said anode a selected distance from said cathode forming a gap therebetween;
heating the cathode at a desired temperature;
applying a gaseous species to the cathode and into the gap between the cathode and anode forming H bonds and/or C—H bonds on the surface of the cathode;
pressurizing a selected quantity of the gaseous species to a predetermined pressure;
heating and controlling the temperature of the cathode to emit electrons traversing towards the anode producing an thermionic emisison current;
applying an electric field to an anode to collect an emission of thermionically emitted electrons from said heated cathode; and
replenishing said gaseous species used during the conversion process maintaining said predetermined pressure of said gaseous species at said cathode and said gap.