# US 10,371,685 B2 · Method, device and apparatus for monitoring halogen levels in a body of water > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,371,685 B2 - Document ID: US10371685B2 - Status: Granted - Kind: B2 - Application number: 16/256,105 - Filed: 2019-01-24 - Published: 2019-05-23 - Granted: 2019-08-06 - Earliest claimed: 2017-03-16 - Assignees: Gecko Alliance Group Inc. - Applicants: Gecko Alliance Group Inc. - Inventors: Benoit Laflamme; André Villemaire; Jean-François Gravel; Serge Caron - Web page: https://patentgrep.com/patent/US10371685B2 ## CPC - G01N 33/182: {Specific anions in water} - E04H 4/00: Swimming or splash baths or pools - E04H 4/1281: {Devices for distributing chemical products in the water of swimming pools} - G01J 3/0205: {Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows} - G01J 3/0291: {Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements} - G01J 3/0297: {Constructional arrangements for removing other types of optical noise or for performing calibration} - G01J 3/42: Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry (beam switching arrangements G01J3/08) - G01N 21/274: {Calibration, base line adjustment, drift correction} - G01N 21/3103: {Atomic absorption analysis} - G01N 21/3151: {using two sources of radiation of different wavelengths (G01N21/33 - G01N21/39 take precedence)} - G01N 21/33: using ultraviolet light (G01N21/39 takes precedence) - C02F 2103/42: from bathing facilities, e.g. swimming pools - C02F 2209/11: Turbidity - C02F 2209/29: Chlorine compounds - G01J 2003/2869: {Background correcting} - G01J 2003/421: {Single beam} - G01N 21/85: Investigating moving fluids or granular solids - G01N 2021/3133: {with selection of wavelengths before the sample} - G01N 2201/0231: Thermostating - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) - E04H: BUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL (foundations E02D) - G01J: MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY (light sources F21, H01J, H01K, H05B; investigating properties of materials by optical means G01N) - C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes) ## Abstract A method and an apparatus are presented for monitoring a concentration of a specific halogen in a body of water such as a spa or bathing unit for example. The apparatus comprises a housing in which is positioned an optical absorption analyzer for making first and second measurement of transmission of ultraviolet light from a light source emitting light at a specific wavelength. The second and first measurements are taken respectively before and after the ultraviolet light has travelled through a sample of water and are used to derive a concentration of the specific halogen. The derived concentration may then be communicated to a user using a display device and/or may be used to control operational components of a bathing unit for adjusting the concentration of halogen in the water. In some practical implementations, the apparatus may be embodied as a standalone device, which may be configured to float on the water of the bathing unit or, alternatively, may be configured for being installed in-line in a water circulation path of the bathing input by connecting the housing to circulation piping. ## Claims ### Claim 1 A device for monitoring a concentration of a specific halogen in a bathing unit, said device comprising: a. a housing configured for floating on top of a body of water held in a receptacle of the bathing unit, said housing having a lower portion configured for being at least partially submerged in water during use and an upper portion configured for extending at least partially above the water, said lower portion including walls extending into the water and defining spaced apart opposing windows made at least in part of a material permeable to ultraviolet light; b. an optical absorption analyzer positioned within said housing, said optical absorption analyzer being configured for making measurements of transmission of ultraviolet light from a light source through a sample of the water held in a receptacle, the sample being between the spaced apart opposing windows, said light source emitting light at a specific wavelength, wherein the specific wavelength of the light source corresponds to the specific halogen whose concentration is being monitored, said optical absorption analyzer comprising a processing unit configured for: i. deriving the concentration of the specific halogen at least in part by processing results of the measurements of transmission of ultraviolet light from a light source through the sample of water; and ii. releasing a signal conveying the derived concentration of the specific halogen. ### Claim 2 (depends on 1) A device as defined in claim 1, wherein the spaced apart opposing windows are made of at least one of quartz, optical glass, cellulose diacetate, polyethylene, acrylic and polyester. ### Claim 3 (depends on 1) A device as defined in claim 1, wherein the measurements of transmission of ultraviolet light include a first measurement of transmission of ultraviolet light and a second measurement of transmission of ultraviolet light, and wherein the optical absorption analyzer further comprises: i. the light source for emitting ultraviolet light at the specific wavelength; ii. a first detector for making the first measurement of transmission of ultraviolet light from said light source through the sample of water; iii. a second detector for making the second measurement of transmission of ultraviolet light, wherein the second measurement is taken prior to the ultraviolet light travelling through the sample of water. ### Claim 4 (depends on 3) A device as defined in claim 3, wherein said light source is a first light source and wherein said specific wavelength is a first specific wavelength, said optical absorption analyzer further comprising a second light source for emitting light at a second specific wavelength different from the first specific wavelength, wherein: a. the first detector is used for making a first measurement of transmission of light from the second light source through the sample of water; b. the second detector is used for making a second measurement of transmission of light from said second light source, wherein the second measurement is taken prior to the light from said second light source travelling through the sample of water; c. the processing unit is configured to derive the concentration of the specific halogen by processing at least: i. results of the first and the second measurements of transmission of light from said second light source; and ii. the results of the first and the second measurements of transmission of light from said first light source. ### Claim 5 (depends on 4) A device as defined in claim 4, wherein said optical absorption analyzer further comprises a beam splitter module for directing: i. a first part of ultraviolet light generated by said first light source toward the first detector through the sample of water; ii. a second part of ultraviolet light generated by said first light source toward the second detector; iii. a first part of light generated by said second light source toward the first detector through the sample of water; and iv. a second part of light generated by said second light source toward the second detector. ### Claim 6 (depends on 4) A device as defined in claim 4, wherein said second specific wavelength at which said second light source emits light is between about 450 nm and 1100 nm. ### Claim 7 (depends on 6) A device as defined in claim 6, wherein said second specific wavelength at which said second light source emits light is between about 475 nm and 550 nm. ### Claim 8 (depends on 4) A device as defined in claim 4, wherein the first light source and the second light source are modulated light sources. ### Claim 9 (depends on 4) A device as defined in claim 4, wherein the first light source and the second light source are configured to emit light according to sinusoidal light patterns. ### Claim 10 (depends on 9) A device as defined in claim 9, wherein the first light source is modulated at a first frequency and the second light source is modulated at a second frequency, wherein the first frequency is different from the second frequency and wherein said processing unit is configured for deriving the concentration of the specific halogen at least in part based on a frequency distribution associated with: a. the results of the first and the second measurements of the transmission of light from said first light source; and b. the results of the first and the second measurements of the transmission of light from said second light source. ### Claim 11 (depends on 10) A device as defined in claim 10, wherein the first frequency of the first light source is between 420 and 580 Hz. ### Claim 12 (depends on 11) A device as defined in claim 11, wherein the second frequency of the second light source is between 540 and 600 Hz. ### Claim 13 (depends on 3) A device as defined in claim 3, wherein said optical absorption analyzer further comprises: i. a beam splitter module for directing: ii. a first part of ultraviolet light generated by said light source toward the first detector through the sample of water; and iii. a second part of ultraviolet light generated by said light source toward the second detector. ### Claim 14 (depends on 1) A device as defined in claim 1, wherein said optical absorption analyzer further comprises a temperature sensor for generating a signal conveying water temperature information for the sample of water, said processing unit being configured for deriving the concentration of the specific halogen at least in part by processing the results of the measurements of transmission of ultraviolet light and of the water temperature information. ### Claim 15 (depends on 1) A device as defined in claim 1, wherein the specific halogen whose concentration is being monitored is selected from the group consisting of chlorine and bromine. ### Claim 16 (depends on 15) A device as defined in claim 15, wherein the specific halogen whose concentration is being monitored is bromine. ### Claim 17 (depends on 16) A device as defined in claim 16, wherein the specific wavelength at which said light source emits light is between about 280 nm and 380 nm. ### Claim 18 (depends on 17) A device as defined in claim 17, wherein the specific wavelength at which said light source emits light is between about 300 nm and 360 nm. ### Claim 19 (depends on 18) A device as defined in claim 18, wherein the specific wavelength at which said light source emits light is about 310 nm. ### Claim 20 (depends on 1) A device as defined in claim 1, wherein said upper portion includes a display screen in electronic communication with the processing unit of said optical absorption analyzer for displaying information derived from the derived concentration of the specific halogen. ### Claim 21 (depends on 1) A device as defined in claim 1, further comprising an antenna for transmitting the signal conveying the derived concentration of the specific halogen to a remote device, said remote device including a display for conveying the derived concentration of the specific halogen. ### Claim 22 (depends on 21) A device as defined in claim 21, wherein said remote device is a smart phone. ### Claim 23 (depends on 1) A device as defined in claim 1, wherein said device is configured to transmit the signal conveying the derived concentration of the specific halogen to a processing module external to the device over a wireless link, said processing module external to the device being configured for using the derived concentration of the specific halogen to control generation of the specific halogen to detect at least one of an excess and an insufficiency of the specific halogen in the water. ### Claim 24 (depends on 23) A device as defined in claim 23, wherein said processing module external to the device being configured for controlling generation of the specific halogen by controlling operation of an electrolytic cell.