# US 10,370,753 B2 · Method for applying a protective coating to a flat steel product and flat steel product having a corresponding protective coating > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,370,753 B2 - Document ID: US10370753B2 - Status: Granted - Kind: B2 - Application number: 14/425,215 - Filed: 2013-08-28 - Published: 2015-08-13 - Granted: 2019-08-06 - Earliest claimed: 2012-09-03 - Assignees: voestalpine Stahl GmbH - Applicants: voestalpine Stahl GmbH - Inventors: Christian K. Riener; Gerhard Angeli; Klaus Hofer; Wilhelm Fischer - Web page: https://patentgrep.com/patent/US10370753B2 ## CPC - C23C 2/06: Zinc or cadmium or alloys based thereon - B32B 15/013: {one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium} - C22C 18/00: Alloys based on zinc - C22C 18/04: with aluminium as the next major constituent - C23C 2/26: After-treatment (C23C2/14 takes precedence) - C23C 2/40: Plates; Strips - Y10T 428/12799: Next to Fe-base component [e.g., galvanized] - C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04) - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - C22C: ALLOYS (treatment of alloys C21D, C22F) - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The invention relates to a method for applying a protective coating (10) to a flat steel product (100), wherein the protective coating (10) is produced by guiding the flat steel product (100) having a strip entry temperature of 400-490 degrees Celsius through a molten zinc alloy bath. The molten zinc alloy bath (11) has a bath temperature of 400-480 degrees Celsius and contains an aluminum fraction and a magnesium fraction. In particular, the molten zinc alloy bath (11) has the following composition: the aluminum fraction is in the range between 1.8 and 3.0 weight percent; the magnesium fraction is in the range between 1.3 and 2.7 weight percent; the aluminum fraction in weight percent is greater than the magnesium fraction in weight percent; the ratio of the magnesium fraction in weight percent to the sum of the aluminum fraction in weight percent and the magnesium fraction in weight percent is in the range between 0.31 and 0.44; and the remainder of the molten zinc alloy bath is zinc and unavoidable impurities. ## Claims ### Claim 1 A method for applying a protective coating (10) on a flat steel product (100), wherein the protective coating (10) is produced by guiding the flat steel product (100) having a strip entry temperature in the range between 400 and 490 degrees Celsius through a molten zinc alloy bath (11), wherein the molten zinc alloy bath (11) has a bath temperature in the range from 400 to 480 degrees Celsius and has an aluminum content and a magnesium content, wherein the molten zinc alloy bath (11) has a composition which is adjusted as follows: the aluminum content lies in the range between 2.0 and 2.9 weight percent; the magnesium content lies in the range between 1.5 and 2.4 weight percent; the aluminum content in weight percent is greater than the magnesium content in weight percent; the ratio of the magnesium content in weight percent to the sum of the aluminum content in weight percent and the magnesium content in weight percent lies in the range between 0.34 and 0.40; and the remainder of the molten zinc alloy bath (11) are zinc and unavoidable impurities, characterized in that a theoretical cooling curve for an alloy composition of the molten zinc alloy bath (11) is calculated such that a Mg2Zn11-phase is excluded and in that in the molten zinc alloy bath (11) before the solidification of the ternary eutectic (TE) a solid content of primary zinc dendrites results, which lies in the range between 0.4 and 0.6 molar fraction of the solid content of the molten zinc alloy bath (11), and in that a cooling rate for solidifying the molten zinc alloy in a solidification process on the flat steel product (100) is adjusted based on the calculated theoretical cooling curve; and is controlled in an apparatus (200) applying control technology using nozzles (14). ### Claim 2 (depends on 1) The method according to claim 1, characterized in that in a process step the composition of the molten zinc alloy bath (11) is controlled by maintaining the composition of the molten zinc alloy bath, such that primary zinc dendrites (Z) and ternary eutectic (TE) are formed on the flat steel product (100) during solidification. ### Claim 3 (depends on 2) The method according to claim 2, characterized in that during solidification on the flat steel product (100) a small residue of aluminum-rich zinc phases (A) and of the binary eutectic (BE) is formed, which in sum comprise less than <10% of the total volume of the coating. ### Claim 4 (depends on 3) The method according to claim 3, characterized in that during solidification on the flat steel product (100) a small residue of aluminum-rich zinc phases (A) and of the binary eutectic (BE) is formed, which in sum comprise less than <5% of the total volume of the coating. ### Claim 5 (depends on 2) The method according to claim 2, characterized in that the solidification process on the flat steel product (100) is controlled in an apparatus (200) applying control technology, wherein in the molten zinc alloy bath (11), before a final eutectic solidification, a solid content results, which lies below 55%. ### Claim 6 (depends on 1) The method according to claim 1, characterized in that the solidification process on the flat steel product (100) is controlled in an apparatus (200) applying control technology, wherein in the molten zinc alloy bath (11), before a final eutectic solidification, a solid content results, which lies below 55%. ### Claim 7 (depends on 1) The method according to claim 1, comprising a process step in which the composition of the molten zinc alloy bath (11) is controlled such that the magnesium content in the molten zinc alloy bath (11) and thus also in the protective coating (10) is always 21% to 45% lower than the aluminum content. ### Claim 8 (depends on 1) The method according to claim 1, characterized in that in a process step, the composition of the molten zinc alloy bath (11) is readjusted by adding blocks of alloy. ### Claim 9 (depends on 1) The method according to claim 1, characterized in that one or more further alloying elements from the group of silicon, lithium, titanium, boron, beryllium, yttrium, zirconium, and phosphorus are added to the molten zinc alloy bath (11), and wherein the content of each element is less than 0.1 percent per weight.