# US 10,370,748 B2 · Lean austenitic stainless steel

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- Number: US 10,370,748 B2
- Document ID: US10370748B2
- Status: Granted
- Kind: B2
- Application number: 15/427,667
- Filed: 2017-02-08
- Published: 2017-05-25
- Granted: 2019-08-06
- Earliest claimed: 2007-11-29
- Assignees: ATI Properties, Inc.
- Applicants: ATI Properties LLC
- Inventors: David S. Bergstrom; James M. Rakowski; Charles P. Stinner; John J. Dunn; John F. Grubb
- Web page: https://patentgrep.com/patent/US10370748B2

## CPC

- C22C 38/58: with more than 1.5% by weight of manganese
- C22C 38/001: {containing N}
- C22C 38/002: {containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60}
- C22C 38/02: containing silicon
- C22C 38/22: with molybdenum or tungsten
- C22C 38/30: with cobalt
- C22C 38/32: with boron
- C22C 38/34: with more than 1.5% by weight of silicon
- C22C 38/38: with more than 1.5% by weight of manganese
- C22C 38/42: with copper
- C22C 38/44: with molybdenum or tungsten
- C22C 38/52: with cobalt
- C22C 38/54: with boron
- C22C: ALLOYS (treatment of alloys C21D, C22F)

## Abstract

An austenitic stainless steel having low nickel and molybdenum and exhibiting comparable corrosion resistance and formability properties to higher nickel and molybdenum alloys comprises, in weight %, up to 0.20 C, 2.0-9.0 Mn, up to 2.0 Si, 16.0-23.0 Cr, 1.0-5.0 Ni, up to 3.0 Mo, up to 3.0 Cu, 0.1-0.35 N, up to 4.0 W, up to 0.01 B, up to 1.0 Co, iron and impurities, the steel having a ferrite number of less than 10 and a MD30 value of less than 20° C.

## Claims

### Claim 1

An austenitic stainless steel comprising, in weight percentages:
up to 0.20 C;
greater than 2.0 to 9.0 Mn;
up to 1.0 Si;
16.0 to 23.0 Cr;
1.0 to 3.0 Ni;
up to 2.0 Mo;
0.1 to 0.35 N;
0.05 to 4.0 W;
up to 0.01 B;
up to 1.0 Co;
iron; and
impurities;
the austenitic stainless steel having a ferrite number of at least 3 up to less than 10, and a MD30 value less than 20° C.

### Claim 2 (depends on 1)

The austenitic stainless steel according to claim 1, wherein 0.5≤(Mo+W/2)≤5.0.

### Claim 3 (depends on 1)

The austenitic stainless steel of claim 1, having a PREW value greater than 22.

### Claim 4 (depends on 1)

The austenitic stainless steel of claim 1, having a PREW value greater than 22 and up to 30.

### Claim 5 (depends on 1)

The austenitic stainless steel of claim 1, having a ferrite number of 3 up to 5.

### Claim 6 (depends on 1)

The austenitic stainless steel of claim 1, having a MD30 value less than −10° C.

### Claim 7 (depends on 1)

The austenitic stainless steel of claim 1, wherein C is limited to up to 0.08.

### Claim 8 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mn is limited to greater than 2.0 to 8.0.

### Claim 9 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mn is limited to 3.0 to 6.0.

### Claim 10 (depends on 1)

The austenitic stainless steel of claim 1, wherein Cr is limited to 16.0 to 22.0.

### Claim 11 (depends on 1)

The austenitic stainless steel of claim 1, wherein Cr is limited to 17.0 to 21.0.

### Claim 12 (depends on 1)

The austenitic stainless steel of claim 1, wherein Cr is limited to 17.0 to 20.0.

### Claim 13 (depends on 1)

The austenitic stainless steel of claim 1, wherein Cr is limited to 16.0 to 18.0.

### Claim 14 (depends on 1)

The austenitic stainless steel of claim 1, wherein N is limited to 0.1 to 0.30.

### Claim 15 (depends on 1)

The austenitic stainless steel of claim 1, wherein N is limited to 0.14 to 0.30.

### Claim 16 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mo is limited to 0.40 to 2.0.

### Claim 17 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mo is limited to 0.5 to 2.0.

### Claim 18 (depends on 1)

The austenitic stainless steel of claim 1, wherein B is limited to up to 0.008.

### Claim 19 (depends on 1)

The austenitic stainless steel of claim 1, wherein W is limited to 0.05 to 0.60.

### Claim 20 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mo is limited to 0.40 to 2.0 and having a MD30 value less than −10° C.

### Claim 21 (depends on 1)

The austenitic stainless steel of claim 1, wherein Mo is limited to 0.40 to 2.0 and wherein 0.5≤(Mo+W/2)≤4.0.

### Claim 22 (depends on 21)

The austenitic stainless steel of claim 21, having a MD30 value less than −10° C.

### Claim 23

An austenitic stainless steel comprising, in weight percentages:
up to 0.20 C;
6.0 to 9.0 Mn;
up to 1.0 Si;
16.0 to 23.0 Cr;
1.0 to 3.0 Ni;
0.40 to 2.0 Mo;
0.1 to 0.30 N;
0.05 to 4.0 W;
up to 0.01 B;
up to 1.0 Co;
iron; and
impurities;
the austenitic stainless steel having a ferrite number at least 3 up to less than 10, a PREW value greater than 22 up to 30, and a MD30 value of less than 20° C.

### Claim 24 (depends on 23)

The austenitic stainless steel of claim 23, wherein 0.5≤(Mo+W/2)≤4.0.

### Claim 25

An article of manufacture including an austenitic stainless steel comprising, in weight percentages:
up to 0.20 C;
greater than 2.0 to 9.0 Mn;
up to 1.0 Si;
16.0-23.0 Cr;
1.0-3.0 Ni;
up to 2.0 Mo;
0.1-0.35 N;
0.05 to 4.0 W;
up to 0.01 B;
up to 1.0 Co;
iron; and
impurities;
the austenitic stainless steel having a ferrite number of at least 3 up to less than 10, and a MD30 value less than 20° C.

### Claim 26 (depends on 25)

The article of manufacture of claim 25, wherein the austenitic stainless steel has a MD30 value less than −10° C.

### Claim 27 (depends on 25)

The article of manufacture of claim 25, wherein in the austenitic stainless steel Mo is limited to 0.40-2.0 Mo.

### Claim 28 (depends on 25)

The article of manufacture of claim 25, wherein the article is adapted for use in at least one of a low temperature environment and a cryogenic environment.

### Claim 29 (depends on 25)

The article of manufacture of claim 25, wherein the article is selected from the group consisting of a corrosion resistant article, a corrosion resistant architectural panel, a flexible connector, a bellows, a tube, a pipe, a chimney liner, a flue liner, a plate frame heat exchanger part, a condenser part, a part for pharmaceutical processing equipment, a sanitary part, and a part for ethanol production or processing equipment.

### Claim 30 (depends on 1)

The austenitic stainless steel of claim 1, wherein the ferrite number is calculated according to the following equation, in which elemental contents are weight percentages:
Ferrite Number=[3.34×(Cr+1.5Si+Mo+2Ti+0.5Cb)]−[2.46×(Ni+30N+30C+0.5Mn+0.5Cu)]−28.6.

### Claim 31 (depends on 23)

The austenitic stainless steel of claim 23, wherein the ferrite number is calculated according to the following equation, in which elemental contents are weight percentages:
Ferrite Number=[3.34×(Cr+1.5Si+Mo+2Ti+0.5Cb)]−[2.46×(Ni+30N+30C+0.5Mn+0.5Cu)]−28.6.

### Claim 32 (depends on 25)

The article of manufacture of claim 25, wherein the ferrite number is calculated according to the following equation, in which elemental contents are weight percentages:
Ferrite Number=[3.34×(Cr+1.5Si+Mo+2Ti+0.5Cb)]−[2.46×(Ni+30N+30C+0.5Mn+0.5Cu)]−28.6.
