# US 10,370,465 B2 · Propylene homopolymer for stress-resistant molded article, composition containing the polymer, and stress-resistant molded articles obtained therefrom

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- Number: US 10,370,465 B2
- Document ID: US10370465B2
- Status: Granted
- Kind: B2
- Application number: 12/448,983
- Filed: 2008-01-17
- Published: 2010-01-07
- Granted: 2019-08-06
- Earliest claimed: 2007-01-18
- Assignees: Prime Polymer Co., Ltd.; Mitsui Chemicals, Inc.
- Applicants: Keita Itakura; Toshiyuki Ishii; Rikuo Onishi; Satoshi Hashizume
- Inventors: Keita Itakura; Toshiyuki Ishii; Rikuo Onishi; Satoshi Hashizume
- Web page: https://patentgrep.com/patent/US10370465B2

## CPC

- C08F 110/06: Propene
- C08L 23/12: Polypropene
- C08F 4/65912: {in combination with an organoaluminium compound}
- C08F 4/65916: {supported on a carrier, e.g. silica, MgCl2, polymer}
- C08K 7/14: Glass
- C08L 23/16: Ethylene-propylene or ethylene-propylene-diene copolymers
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

Propylene polymers and propylene resin compositions containing the polymers are used as molded articles used under stress for a long period such as automotive parts, housing parts, home appliance parts and electric power tool parts. Stress-resistant molded articles of the invention are obtained from these materials. A propylene homopolymer (A) satisfies the following requirements (1) to (3), and a polypropylene resin composition contains the propylene homopolymer (A). (1) The ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) according to GPC is in the range of 1.2 to 3.5. (2) Mn is in the range of 35,000 to 400,000. (3) The content of components soluble in o-dichlorobenzene at 90° C. is not more than 4 wt %.

## Claims

### Claim 1

A stress-resistant molded article which is obtained from a polypropylene resin composition, wherein the polypropylene resin composition comprises 30 to 95 wt % of a propylene homopolymer (A) and 5 to 70 wt % of a filler (C) (wherein the total of the propylene homopolymer (A) and the filler (C) is 100 wt %),
wherein the filler (C) is glass fibers,
wherein the propylene homopolymer (A) satisfies the following requirements (1) to (5):
(1) the ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) according to GPC is in the range of 2.0 to 2.5;
(2) Mn is in the range of 87,000 to 400,000;
(3) the content of components soluble in o-dichlorobenzene at 90° C. is not more than 2 wt %;
(4) the melting point (Tm) is not less than 157° C.; and
(5) the melt flow rate (accordance with ASTM D 1238, 230° C., 2.16 kg load) is in the range of 0.1 to 15 g/10 min.

### Claim 2

A stress-resistant molded article which is obtained from a polypropylene resin composition, which is formed by injection molding, wherein the injection molding involves a mold that is designed to form a weld, and
wherein the polypropylene resin composition comprises 30 to 95 wt % of a propylene homopolymer (A) and 5 to 70 wt % of a filler (C) (wherein the total of the propylene homopolymer (A) and the filler (C) is 100 wt %),
wherein the filler (C) is glass fibers,
wherein the propylene homopolymer (A) satisfies the following requirements (1) to (5):
(1) the ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) according to GPC is in the range of 2.0 to 2.5;
(2) Mn is in the range of 87,000 to 400,000;
(3) the content of components soluble in o-dichlorobenzene at 90° C. is not more than 4 wt %;
(4) the melting point (Tm) is not less than 157° C.; and
(5) the melt flow rate (accordance with ASTM D 1238, 230° C., 2.16 kg load) is in the range of 0.1 to 15 g/10 min.

### Claim 3 (depends on 2)

The stress-resistant molded article according to claim 2, wherein the molded article has a metal insert.

### Claim 4 (depends on 2)

The stress-resistant molded article according to claim 2, which is an automotive part, a two-wheeled vehicle or bicycle part, a housing part, a home appliance part or an electric power tool part.

### Claim 5 (depends on 2)

The stress-resistant molded article according to claim 2, which is an engine fan, a cooling fan or a fan shroud.

### Claim 6 (depends on 2)

The stress-resistant molded article according to claim 2, wherein the polypropylene resin composition satisfies the following requirement:
the cycle of the vibration fatigue test (weld) is not less than 3.0×104, wherein the vibration fatigue test (weld) employs a welded test piece generally configured in a dumbbell shape having a whole length of 220 mm, a central line portion length of 57 mm, a terminal width of 19 mm, a central line portion width of 13 mm, and a thickness of 3.2 mm, and wherein the notch radius is 76 mm, the welded test piece being produced by injection molding of the polypropylene resin composition at a cylinder temperature of 230° C. and at a mold temperature of 40° C., and wherein the vibration fatigue test (weld) is carried out at a temperature of 85° C., a frequency of 1 Hz, a tensile deformation stress of 5 MPa, and a chuck distance of 115 mm.