# US 10,369,623 B2 · Bio-based binder system

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- Number: US 10,369,623 B2
- Document ID: US10369623B2
- Status: Granted
- Kind: B2
- Application number: 15/199,312
- Filed: 2016-06-30
- Published: 2016-10-27
- Granted: 2019-08-06
- Earliest claimed: 2007-11-14
- Assignees: University of Northern Iowa Research Foundation
- Applicants: University of Northern Iowa Research Foundation
- Inventors: Gerard R. Thiel; Shoshanna R. Coon; Mitchell Patterson; Andrew Simonson; Ian Williams; Ryan Jones
- Web page: https://patentgrep.com/patent/US10369623B2

## CPC

- B22C 1/26: of carbohydrates; of distillation residues therefrom
- B22C 1/2273: {Polyurethanes; Polyisocyanates}
- C08G 18/6484: {Polysaccharides and derivatives thereof}
- C09J 175/04: Polyurethanes
- B22C: FOUNDRY MOULDING (moulding refractory materials in general B28B)
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)

## Abstract

A bio-based binder system for use in preparing foundry molds. In a preferred embodiment, the system includes the use of a) a polyermizable hydroxyl-containing component comprising a saccharide, b) an isocyanate component, and c) a catalyst, and preferably amine catalyst, component adapted to catalyze the polymerization of a) and b), in the presence of a foundry aggregate such as sand. The system can be used in any suitable manner, including in either a cold box process or no bake process as described herein.

## Claims

### Claim 1

A process for making a foundry mold, the process comprising:
forming a mixture comprising:
a foundry aggregate,
a saccharide component which is underivatized,
an isocyanate component, and
a catalyst component capable of catalyzing polymerization of the saccharide component and the isocyanate component to form a polyurethane binder, and
allowing the saccharide component, the isocyanate component and the catalyst component to react to form the polyurethane binder, thereby forming the foundry mold,
wherein the mixture contains sufficient catalyst so that foundry work time of the mixture is between about 1 and about 30 minutes.

### Claim 2 (depends on 1)

The process of claim 1, wherein allowing the saccharide component, the isocyanate component, and the catalyst component to react to form the polyurethane binder comprises allowing the saccharide component, the isocyanate component, and the catalyst component to cure at ambient temperature.

### Claim 3 (depends on 1)

The process of claim 1, wherein the catalyst component comprises a liquid amine, and allowing the saccharide component, the isocyanate component, and the catalyst component to react to form the polyurethane binder comprises allowing the saccharide component, the isocyanate component, and the catalyst component to react to form the polyurethane binder, thereby forming the foundry mold, without baking the foundry mold.

### Claim 4 (depends on 1)

The process of claim 1, wherein:
the catalyst component comprises an amine gas, and
forming the mixture comprises passed the amine gas through a mixture of the foundry aggregate, the saccharide component, and the isocyanate component.

### Claim 5 (depends on 4)

The process of claim 4, wherein allowing the saccharide component, the isocyanate component, and the catalyst component to react to form the polyurethane binder comprises allowing the saccharide component, the isocyanate component, and the catalyst component to react using a cold box process.

### Claim 6 (depends on 1)

The process of claim 1, wherein forming the mixture comprises combining the saccharide component, the isocyanate component, and the catalyst component into the mixture and thereafter forming the mixture into a shape defines an open volume corresponding to an article to be cast.

### Claim 7 (depends on 6)

The process of claim 6, wherein the foundry aggregate, the saccharide component and the isocyanate component are combined, the composition so made is formed into said shape, and thereafter a catalyst component comprising a tertiary amine gas is passed through the shaped composition.

### Claim 8 (depends on 1)

The process of claim 1, wherein the mixture contains water.

### Claim 9 (depends on 1)

The process of claim 1, wherein the saccharide component is substantially free of volatile organic compounds.

### Claim 10 (depends on 1)

The process of claim 1, wherein the saccharide component is substantially free of aromatic solvents.

### Claim 11 (depends on 1)

The process of claim 1, wherein the isocyanate component comprises one or more isocyanates selected from the group consisting of 2,4- and 2,6-diisocyanatotoluene (TDI) and their derivatives, methylenediphenyl 4,4′-, 2,4- and 2,2′-diisocyanates (MDI) and their derivatives, polymeric MDI's (PMDI), 1,5-naphthalene diisocyanate (NDI), 4,4′, 4″-triisocyanatotriphenylmethane and bis(3,5-diisocyanato-2-methylphenyl)methane, 1,6-hexamethylene diisocyanate (HDI), and 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl(isophorone) isocyanate (IPDI).

### Claim 12 (depends on 1)

The process of claim 1, wherein the mixture further comprises a non-saccharide polyol component comprising a polyol selected from the group consisting of ethylene glycol, 1, 2-propylene glycol, 1,3-propylene glycol, hexane 1,6-diol, 2 methyl-1,3 propanediol, glycerol, mannitol, sorbitol, diethylene glycol, triethylene glycol, polyethylene glycols, polypropylene glycols, butylene, dibutylene, and polybutylene glycols, and
allowing the saccharide component, the isocyanate component, and the catalyst component to react to form the polyurethane binder comprises allowing the saccharide component, the non-saccharide polyol, the isocyanate component and the catalyst component to react to form the polyurethane binder.

### Claim 13 (depends on 12)

The process of claim 12, wherein:
the saccharide component is present in an amount ranging from about 5 to about 65 weight percent of the polyurethane binder,
the non-saccharide polyol component is present in an amount ranging from about 1 to about 60 weight percent of the polyurethane binder, and
the isocyanate component is present in an amount ranging from about 10 to about 80 weight percent of the polyurethane binder.

### Claim 14 (depends on 12)

The process of claim 12, wherein:
the saccharide component is present in an amount ranging from about 10 to about 40 weight percent of the polyurethane binder,
the non-saccharide polyol component is present in an amount ranging from about 10 to about 50 weight percent of the polyurethane binder, and
the isocyanate component is present in an amount ranging from about 20 to about 70 weight percent of the polyurethane binder.

### Claim 15 (depends on 1)

The process of claim 1, wherein the saccharide component comprises a polysaccharide selected from the group consisting of cellulose, levan, pullulan, corn syrup, molasses, and combinations thereof.

### Claim 16 (depends on 1)

The process of claim 1, wherein the saccharide component is corn syrup.

### Claim 17 (depends on 1)

The process of claim 1, wherein the foundry aggregate is selected from the group consisting of silica sand, lake sand, zircon, olivine, chromite, mullite, and combinations thereof.

### Claim 18 (depends on 1)

The process of claim 1, wherein:
the saccharide component is present in an amount ranging from about 15 to about 20 weight percent of the polyurethane binder,
the isocyanate component is present in an amount ranging from about 20 to about 70 weight percent of the polyurethane binder, and
the aggregate is present in an amount of at least 70 weight percent of the foundry mold.