# US 10,369,560 B2 · Method for limiting the emission of dust from catalyst grains > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,369,560 B2 - Document ID: US10369560B2 - Status: Granted - Kind: B2 - Application number: 15/322,102 - Filed: 2015-06-24 - Published: 2017-06-08 - Granted: 2019-08-06 - Earliest claimed: 2014-06-27 - Assignees: Eurecat S.A. - Applicants: Eurecat S.A. - Inventors: Pauline Galliou; Pierre Dufresne; Mathieu Baffert; Giuseppe Italiano - Web page: https://patentgrep.com/patent/US10369560B2 ## CPC - B01J 37/0217: {Pretreatment of the substrate before coating} - B01J 23/882: and cobalt - B01J 33/00: Protection of catalysts, e.g. by coating - B01J 37/0219: {the coating containing organic compounds} - B01J 37/0225: {of metal substrates} - B01J 37/08: Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS ## Abstract The present invention relates to a method for limiting the emission of dust from catalyst grains. Said method comprises the following two consecutive steps: a first step of performing a heat treatment of the catalyst grains at a temperature no lower than 100° C., followed by a second step of coating the surface of the catalyst grains by placing same in contact with one or more coating materials having a melting point T no lower than 45° C. and which are injected in a solid state, said second step being carried out with no further addition of heat, at a temperature of T−60° C. to T−1° C., while remaining no lower than 40° C. ## Claims ### Claim 1 A process for limiting emission of dust from catalyst grains comprising the following two consecutive steps: a first step consisting of carrying out a heat treatment of the catalyst grains at a temperature greater than or equal to 100° C., followed by a second step that consists of carrying out a coating of the surface of the catalyst grains thereby forming a coated catalyst, by contacting components consisting of catalyst grains and one or more coating materials having a melting point temperature greater than or equal to 45° C., wherein said one or more coating materials are introduced in a form of a solid at a temperature below the melting point temperature, said second step being carried out without any supply of heat other than the heat supplied solely by the catalyst grains from the first step, at a temperature that is 1° C. to 60° C. lower than the melting point temperature of said one or more coating materials, while remaining greater than or equal to 40° C. ### Claim 2 (depends on 1) The process as claimed in claim 1, characterized in that it is carried out continuously. ### Claim 3 (depends on 1) The process of claim 1, characterized in that said second step is carried out on an unheated moving bed, fed continuously by the catalyst grains directly derived from the first step and by the one or more coating materials. ### Claim 4 (depends on 1) The process of claim 1, characterized in that the first step is carried out at a temperature ranging from 120° C. to 650° C. ### Claim 5 (depends on 1) The process of claim 1, characterized in that the first step is selected from a catalyst drying treatment, a catalyst calcination treatment and a catalyst regeneration treatment. ### Claim 6 (depends on 1) The process of claim 1, characterized in that the second step is carried out at a temperature that is 1° C. to 50° C. lower than the melting point temperature of said one or more coating materials. ### Claim 7 (depends on 1) The process of claim 1, characterized in that the melting point temperature of the one or more coating materials used in the second step ranges from 45° C. to 180° C. ### Claim 8 (depends on 1) The process of claim 1, characterized in that the one or more coating materials are selected from mineral waxes, synthetic waxes, natural waxes, fatty acids that are solid at ambient temperature, polymers having a melting point temperature ranging from 45° C. to 180° C., and mixtures thereof. ### Claim 9 (depends on 1) The process of claim 1, characterized in that the one or more coating materials are selected from polymers having a melting point temperature ranging from 50° C. to 130° C. ### Claim 10 (depends on 9) The process of claim 9, characterized in that the coating material is selected from polyethylenes. ### Claim 11 (depends on 9) The process of claim 9, characterized in that the coating material is selected from polyethylene waxes. ### Claim 12 (depends on 1) The process of claim 1, characterized in that the one or more coating materials is in the form of particles, the number-average diameter of which is less than or equal to 3% of the number-average diameter of the catalyst grains. ### Claim 13 (depends on 1) The process of claim 1, characterized in that the total amount of coating material used during the second step ranges from 0.05% to 5% by weight relative to the total weight of the coated catalyst. ### Claim 14 (depends on 1) The process of claim 1, characterized in that the second step consists of covering the catalyst grains at their surface with a layer of the one or more coating materials, a mean thickness of which ranges from 0.01 to 15 μm. ### Claim 15 (depends on 14) The process of claim 14, characterized in that the mean thickness of the layer of the one or more coating materials ranges from 0.01 to 10 μm. ### Claim 16 (depends on 1) The process of claim 1, characterized in that the catalyst grains are a hydrocarbon hydroconversion catalyst, comprising a porous refractory oxide support deposited on which is at least one metal selected from group VIII metals and group VIB metals. ### Claim 17 (depends on 16) The process of claim 16, characterized in that the porous refractory oxide support is selected from amorphous or crystalline aluminas, silicas or silica-aluminas. ### Claim 18 (depends on 17) The process of claim 17, characterized in that the catalyst grains are selected from the catalysts containing the metallic combinations CoMo, NiMo, NiW or NiCoMo, deposited on alumina-based supports. ### Claim 19 (depends on 16) The process of claim 16, characterized in that the catalyst grains are selected from the catalysts containing the metallic combinations CoMo, NiMo, NiW or NiCoMo, deposited on alumina-based supports. ### Claim 20 (depends on 1) The process of claim 1, characterized in that the catalyst grains have a maximum number-average dimension ranging from 1 to 10 mm.