Method for preparing zeolite catalyst
AssigneesHyundai Motor Company, Kia Motors Corporation, Postech Academy-Industry Foundation
InventorsSuk Bong Hong, Donghui Jo, Taekyung Ryu, Gi Tae Park, In-Sik Nam, Pyung Soon Kim, Chang Hwan Kim
Life of this patent
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Abstract
A method for manufacturing a zeolite catalyst includes: manufacturing a first Linde Type A (LTA) zeolite using an LTA seed; manufacturing a second LTA zeolite including ions by substituting ions to the first LTA zeolite; and manufacturing a copper LTA zeolite by performing copper ion exchange on the second LTA zeolite.
Claims12
A method for manufacturing a zeolite catalyst, the method comprising steps of:
- manufacturing a first Linde Type A (LTA) zeolite, which includes first ions, using an LTA seed;
- manufacturing a second LTA zeolite including second ions by substituting the second ions in place of the first ions in the first LTA zeolite;
- and
- manufacturing a copper LTA zeolite by substituting copper ions in place of the second ions in the second LTA zeolite;
- wherein an Si/Al molar ratio of the zeolite catalyst is 5 to 30.
A method for manufacturing a zeolite catalyst, the method comprising steps of:
- manufacturing a first LTA zeolite, which includes first ions, using an LTA seed;
- manufacturing a second LTA zeolite including ions by substituting second ions in place of ions in the first LTA zeolite;
- and
- manufacturing an iron LTA zeolite by substituting iron ions in place of the second species ions in the second LTA zeolite.
A method for manufacturing a zeolite catalyst, the method comprising:
- preparing a first mixture by mixing a 1,2-dimethyl-3-(4-methylbenzyl)imidazolium hydroxide aqueous solution, aluminum hydroxide (Al(OH)3), and tetramethylammonium hydroxide pentahydrate;
- preparing a second mixture by mixing tetraethyl orthosilicate (TEOS) (Si(OC2H5)4) into the first mixture and then mixing an LTA seed thereto;
- preparing a third mixture by evaporating ethanol and water contained in the second mixture;
- preparing a first LTA zeolite by mixing a hydrofluoric aqueous solution into the third mixture, heating, and then performing drying;
- preparing a second LTA zeolite including NH4+ ions by mixing the first LTA zeolite with an ammonium nitrate (NH4NO3) solution to react them and then drying;
- and
- preparing a third LTA zeolite by mixing the second LTA zeolite with copper acetate monohydrate solution to react them and then performing drying.
Dependencies are inferred from the claim text.