Class of organic phosphors based on derivatives of benzimidazoxanthenoisoquinolinone for LED lighting
AssigneeSignify Holding B.V.
InventorsJohan Lub, Paulus Albertus Van Hal, Rifat Ata Mustafa Hikmet, Sylvain Loic Jean-Luc Hamon
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Abstract
The invention provides a lighting device including a light source configured to generate light source light and a light converter configured to convert at least part of the light source light into visible converter light. The light converter includes a matrix containing a luminescent material based on derivatives of benzimidazoxanthenoisoquinolinone. The lighting device may include a further luminescent material.
Claims13
A lighting device comprising (a) a light source configured to generate light source light, and (b) a light converter configured to convert at least part of the light source light into visible converter light, wherein the light converter comprises a matrix containing a luminescent material comprising at least an organic phosphor defined by formula IA, and optionally an organic phosphor defined by formula TB:
- wherein G1-G12 are independently selected from hydrogen, halogen, R1, OR1, NHR1, and NR2R1, wherein R1 and R2 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl, wherein optionally one or more of G1-G12 is covalently linked to the matrix, and wherein when the organic phosphor defined by formula IB is available in the luminescent material, the phosphor defined by formula IB and the phosphor defined by formula IA have a molar ratio of 1B/1A ≤0.1, wherein at least four of G1-G12 for the organic phosphor IA independently are H, and wherein independently one or more of G2 and G7 for the organic phosphor IA comprise R1 or OR1, with R1 being defined by formula II:
- wherein D, E, I, L and M are independently selected from hydrogen, halogen, R3, OR3, NHR3, and NR4R3, and wherein R3 and R4 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl.
A lighting device comprising (a) a light source configured to generate light source light, and (b) a light converter configured to convert at least part of the light source light into visible converter light, wherein the light converter comprises a matrix containing a luminescent material comprising at least an organic phosphor defined by formula IA, and optionally an organic phosphor defined by formula IB:
- wherein G1-G12 are independently selected from hydrogen, halogen, R1, OR1, NHR1, and NR2R1, wherein R1 and R2 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl, wherein optionally one or more of G1-G12 is covalently linked to the matrix, and wherein when the organic phosphor defined by formula IB is available in the luminescent material, the phosphor defined by formula IB and the phosphor defined by formula IA have a molar ratio of 1B/1A ≤0.1, wherein one or more of G1-G12 of the organic phosphor IA are independently selected from R1, OR1, NHR1, and NR2R1, wherein one or more of R1 and R2 independently comprise a group defined by formula II:
- wherein D, E, I, L and M are independently selected from hydrogen, halogen, R3, OR3, NHR3, and NR4R3, and wherein R3 and R4 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl.
A luminescent material comprising at least an organic phosphor defined by formula IA and optionally also an organic phosphor defined by formula IB:
- wherein G1-G12 are independently selected from hydrogen, halogen, R1, OR1, NHR1, and NR2R1, wherein R1 and R2 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl, and wherein when the organic phosphor defined by formula IB is available in the luminescent material, the phosphor defined by formula IB and the phosphor defined by formula IA have a molar ratio of 1B/1A ≤0.1, and wherein one or more of G2 and G7 comprises independently a group selected from the group consisting of R1, OR1, NHR1, and NR2R1, and wherein at least four of G1-G12 for the organic phosphor IA independently are H, and wherein independently one or more of G2 and G7 for the organic phosphor IA comprise R1 or OR1, with R1 being defined by formula II;
- wherein D, E, I, L and M are independently selected from hydrogen, halogen, R3, OR3, NHR3, and NR4R3, and wherein R3 and R4 are independently selected from C1-C18alkyl, C6-C24aryl, and C6-C24heteroaryl,
- the luminescent material, comprising an organic phosphor selected from the group consisting of
- 6,16-diphenyl-8H-benzo[3,4]isochromeno[7,8,1-def]benzo[4,5]imidazo[1,2-b]isoquinolin-8-one;
- 6,16-diphenoxy-8H-benzo[3,4]isochromeno[7,8,1-def]benzo[4,5]imidazo[1,2-b]isoquinolin-8-one;
- 16-phenoxy-8H-benzo[3,4]isochromeno[7,8,1-def]benzo[4,5]imidazo[1,2-b]isoquinolin-8-one;
- 6,16-bis(4-(2,4,4-trimethylpentan-2-yl)phenoxy)-8H-benzo[3,4]isochromeno[7,8,1-def]benzo[4,5]imidazo[1,2-b]isoquinolin-8-one;
- and
- 16-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)-8H-benzo[3,4]isochromeno[7,8,1-def]benzo[4,5]imidazo[1,2-b]isoquinolin-8-one.
Dependencies are inferred from the claim text.