Method for production of conjugated diolefin
AssigneeAsahi Kasei Chemicals Corporation
InventorsKazuhiro Takagaki, Hiroyuki Yano
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Abstract
An object of the present invention is to provide a method for production of a high purity conjugated diolefin. The method for production of a conjugated diolefin of the present invention comprises steps of supplying a source gas containing a C4 or higher monoolefin and an oxygen-containing gas into a reactor, bringing a catalyst into contact with the gas mixture, compressing a gas containing a conjugated diolefin produced by an oxidative dehydrogenation reaction to obtain a liquefied gas and rinsing the liquefied gas with water.
Claims20
A method for production of a conjugated diolefin, wherein said method comprises the following steps of (1) to (6) in this order:
- step (1):
- a step of supplying a source gas containing a C4 or higher monoolefin and an oxygen-containing gas into a reactor to form a gas mixture and bringing a catalyst into contact with the gas mixture to obtain a gas containing a conjugated diolefin by an oxidative dehydrogenation reaction,
- step (2):
- a step of cooling the gas containing the conjugated diolefin in a quench column,
- step (3):
- a step of allowing the gas containing the conjugated diolefin to be absorbed in a solvent, subsequently stripping the gas containing the conjugated diolefin from the solvent, followed by compressing the gas to obtain a liquefied gas, wherein the solvent for absorbing the gas containing the conjugated diolefin is toluene, m-xylene, o-xylene, p-xylene, or mixed xylene,
- step (4):
- a step of rinsing the liquefied gas with water,
- step (5):
- a step of removing the water from the liquefied gas by distillation, and
- step (6):
- a step of removing a high boiling component from the liquefied gas, wherein
- in the step (1), an oxygen concentration of the gas containing the conjugated diolefin is in a range of 0.01 to 2.0% by volume.
Dependencies are inferred from the claim text.