Mold flux for continuous-casting Ti-containing hypo-peritectic steel and method therefor
AssigneeNippon Steel & Sumitomo Metal Corporation
InventorsMasahito Hanao, Masaki Nagashima, Masatsugu Ishibashi
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Abstract
A mold flux is used in continuous casting of Ti-containing hypo-peritectic steel so as to prevent longitudinal cracks from forming on a surface of a slab. The mold flux contains CaO, SiO2, an alkali metal oxide and a fluorine compound as major components. f(1), f(2) and f(3), which are calculated from the initial chemical composition, are (1.1−0.5×T) to (1.9−0.5×T), 0.05 to 0.40 and 0 to 0.40, respectively, if the Ti content of the molten steel (mass %) is T. The TiO2 content in the melting state during the casting is no more than 20 mass % and the ratio of the first peak height of perovskite to the first peak height of cuspidine in the mold flux film is no more than 1.0.
Claims1
A method for continuous-casting Ti-containing hypo-peritectic steel, the method comprising:
- continuous-casting hypo-peritectic steel containing 0.1 to 1 mass % of Ti, using a mold flux,
- wherein
- the mold flux contains CaO, SiO2, an alkali metal oxide and a fluorine compound as major components,
- a chemical composition of the mold flux before the mold flux is put into a mold satisfies the formulas (1), (2) and (3),
- a TiO2 content of the mold flux in a melting state during the casting is no more than 20 mass %, and
- a strength ratio of a film of the mold flux in a solidifying state after the casting is no more than 1.0:
- 1.1−0.5×T≤f(1)≤1.9−0.5×T (1)
- 0.05≤f(2)≤0.40 (2)
- 0≤f(3)≤0.40 (3),
- wherein in the formulas (1) to (3),
- f(1)=(CaO)h/(SiO2)h (A)
- f(2)=(CaF2)h/{(CaO)h+(SiO2)h+(CaF2)h} (B)
- f(3)={(alkali metal fluoride)h}/{(CaO)h+(SiO2)h+(alkali metal fluoride)h)} (C),
- wherein in the formulas (A) to (C),
- (CaO)h=WCaO−(CaF2)h×0.718 (D)
- (SiO2)h=WSiO2 (E)
- (CaF2)h=(WF−WLi2O×1.27−WNa2O×0.613−WK2O×0.403)×2.05 (F)
- (alkali metal fluoride)h=WLi2O×1.74+WNa2O×1.35+WK2O×1.23 (G)
- wherein T is a Ti content of molten steel (mass %), WCaO is a CaO content of the mold flux (mass %), WSiO2 is a SiO2 content of the mold flux (mass %), WF is a F content of the mold flux (mass %), and WLi2O, WNa2O and WK2O are contents of Li2O, Na2O and K2O respectively, which are alkali metal oxides, of the mold flux (mass %), and
- wherein the strength ratio of the film means a ratio of a first peak height of perovskite to a first peak height of cuspidine, the ratio being obtained from X-ray diffraction analysis of powder obtained by pulverizing the film of the mold flux.
Dependencies are inferred from the claim text.