# US 10,319,911 B2 · Wiring pattern production method and transistor production method

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- Number: US 10,319,911 B2
- Document ID: US10319911B2
- Status: Granted
- Kind: B2
- Application number: 15/243,146
- Filed: 2016-08-22
- Published: 2016-12-08
- Granted: 2019-06-11
- Earliest claimed: 2014-02-28
- Assignees: Nikon Corporation
- Applicants: Nikon Corporation
- Inventors: Shohei Koizumi; Takashi Sugizaki; Yusuke Kawakami
- Web page: https://patentgrep.com/patent/US10319911B2

## CPC

- H10K 71/60: Forming conductive regions or layers, e.g. electrodes
- C23C 18/1605: {by masking}
- C23C 18/204: {Radiation, e.g. UV, laser}
- C23C 18/2086: {with use of organic or inorganic compounds other than metals, first}
- C23C 18/285: {Sensitising or activating with tin based compound or composition}
- C23C 18/32: Coating with nickel, cobalt or mixtures thereof with phosphorus or boron (C23C18/50 takes precedence)
- C23C 18/42: Coating with noble metals
- C23C 18/54: Contact plating, i.e. electroless electrochemical plating
- C23C 18/30: Activating {or accelerating or sensitising with palladium or other noble metal}
- H10K 10/466: {Lateral bottom-gate IGFETs comprising only a single gate}
- H10K 10/481: {characterised by the gate conductors}
- H10K 10/84: Ohmic electrodes, e.g. source or drain electrodes
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

A wiring pattern production method includes forming, on a substrate, a precursor film for a plating base film including a first formation material having an amino group protected by a photoreactive protecting group, forming a photoresist layer including a photoresist material on a surface of the precursor film, exposing the photoresist layer with a desired pattern of light, exposing the precursor film with a desired pattern of light to form the plating base film, developing the exposed photoresist layer, removing a deprotected protecting group, and depositing an electroless plating catalyst on the exposed surface of the plating base film.

## Claims

### Claim 1

A wiring pattern production method comprising:
forming, on a substrate, a precursor film for a plating base film including a first formation material having an amino group protected by a photoreactive protecting group, the first formation material being a silane coupling agent having an amino group protected by the protecting group;
forming a photoresist layer including a photoresist material on a surface of the precursor film;
exposing the photoresist layer with a desired pattern of light;
exposing the precursor film with a desired pattern of light to form the plating base film;
developing the exposed photoresist layer and removing a deprotected protecting group; and
depositing an electroless plating catalyst on the exposed surface of the plating base film.

### Claim 2 (depends on 1)

The wiring pattern production method according to claim 1,
wherein the exposing of the photoresist layer and the exposing of the precursor film are simultaneously performed.

### Claim 3 (depends on 1)

The wiring pattern production method according to claim 1,
wherein, after removing the photoresist layer, a remainder of the precursor film is further exposed to light.

### Claim 4 (depends on 1)

The wiring pattern production method according to claim 1,
wherein the protecting group is an o-nitrobenzyl group or a group having an o-nitrobenzyl skeleton.

### Claim 5 (depends on 1)

The wiring pattern production method according to claim 1,
wherein the amino group is a group represented by —NH2.

### Claim 6 (depends on 1)

The wiring pattern production method according to claim 1,
wherein the precursor film includes a group having at least one of a nitrogen atom and a sulfur atom and the group having the at least one of the nitrogen atom and the sulfur atom further includes a second formation material which is not protected by the protecting group.

### Claim 7 (depends on 6)

The wiring pattern production method according to claim 6,
wherein the second formation material is a silane coupling agent having the group having the at least one of the nitrogen atom and the sulfur atom.

### Claim 8 (depends on 1)

The wiring pattern production method according to claim 1,
wherein the substrate is made of a nonmetallic material.

### Claim 9 (depends on 8)

The wiring pattern production method according to claim 8,
wherein the substrate is made of a resin material.

### Claim 10 (depends on 9)

The wiring pattern production method according to claim 9,
wherein the substrate has flexibility.

### Claim 11 (depends on 1)

A transistor production method comprising:
forming at least one of a gate electrode, a source electrode, and a drain electrode on a substrate using the wiring pattern production method according to claim 1.

### Claim 12 (depends on 11)

The transistor production method according to claim 11, comprising:
forming the gate electrode on the substrate;
covering the gate electrode to form a layer including an insulator layer; and
forming the source electrode and the drain electrode on a surface of the layer including the insulator layer.

### Claim 13 (depends on 11)

The transistor production method according to claim 11, comprising:
forming the source electrode and the drain electrode on the substrate;
covering the source electrode and the drain electrode to form a layer including an insulator layer; and
forming the gate electrode on a surface of the layer including the insulator layer.

### Claim 14

A wiring pattern production method comprising:
forming, on a substrate, a precursor film for a plating base film including a first formation material having an amino group protected by a photoreactive protecting group;
forming a photoresist layer including a photoresist material on a surface of the precursor film;
exposing the photoresist layer with a desired pattern of light;
exposing the precursor film with a desired pattern of light to form the plating base film;
developing the exposed photoresist layer and removing a deprotected protecting group; and
depositing an electroless plating catalyst on the exposed surface of the plating base film,
wherein, after removing the photoresist layer, a remainder of the precursor film is further exposed to light.

### Claim 15

A wiring pattern production method comprising:
forming, on a substrate, a precursor film for a plating base film including a first formation material having an amino group protected by a photoreactive protecting group;
forming a photoresist layer including a photoresist material on a surface of the precursor film;
exposing the photoresist layer with a desired pattern of light;
exposing the precursor film with a desired pattern of light to form the plating base film, developing the exposed photoresist layer and removing a deprotected protecting group; and
depositing an electroless plating catalyst on the exposed surface of the plating base film;
wherein the precursor film includes a group having at least one of a nitrogen atom and a sulfur atom and the group having the at least one of the nitrogen atom and the sulfur atom further includes a second formation material which is not protected by the protecting group.
