# US 10,319,779 B2 · Method for manufacturing image capturing device and image capturing device > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,319,779 B2 - Document ID: US10319779B2 - Status: Granted - Kind: B2 - Application number: 16/014,774 - Filed: 2018-06-21 - Published: 2018-10-18 - Granted: 2019-06-11 - Earliest claimed: 2017-01-12 - Assignees: Renesas Electronics Corporation - Applicants: Renesas Electronics Corporation - Inventors: Takeshi Kamino; Takahiro Tomimatsu - Web page: https://patentgrep.com/patent/US10319779B2 ## CPC - H10F 39/014: {of CMOS image sensors} - H04N 25/76: Addressed sensors, e.g. MOS or CMOS sensors - H10D 30/0212: {using self-aligned silicidation} - H10D 64/0112: {using conductive layers comprising silicides} - H10D 64/01326: {Aspects related to lithography, isolation or planarisation of the conductor} - H10F 39/024: {of coatings or optical elements} - H10F 39/8033: {Photosensitive area} - H10F 39/8037: {the integrated elements comprising a transistor} - H10F 39/805: {Coatings} - H10P 30/22: using masks - H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION - H04N: PICTORIAL COMMUNICATION, e.g. TELEVISION - H10D: INORGANIC ELECTRIC SEMICONDUCTOR DEVICES - H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10 ## Abstract An offset spacer film (OSS) is formed on a side wall surface of a gate electrode (NLGE, PLGE) to cover a region in which a photo diode (PD) is disposed. Next, an extension region (LNLD, LPLD) is formed using the offset spacer film and the like as an implantation mask. Next, process is provided to remove the offset spacer film covering the region in which the photo diode is disposed. Next, a sidewall insulating film (SWI) is formed on the side wall surface of the gate electrode. Next, a source-drain region (HPDF, LPDF, HNDF, LNDF) is formed using the sidewall insulating film and the like as an implantation mask. ## Claims ### Claim 1 A method for manufacturing an image capturing device having a photoelectric conversion region, a transfer transistor and a first peripheral transistor, comprising the steps of: (a) defining a pixel region and a peripheral region by forming an element isolation insulating film in a semiconductor substrate; (b) forming a transfer gate electrode of the transfer transistor in the pixel region and forming a first peripheral gate electrode of the first peripheral transistor in the peripheral region, (c) forming the photoelectric conversion region in a portion of the pixel region on one side of the transfer gate electrode; (d) forming a first insulating film so as to cover the pixel region and the peripheral region; (e) forming a first resist pattern over the first insulating film so as to cover the pixel region; (f) performing anisotropic etching of the first insulating film to form respective offset spacers on opposite side surfaces of the first peripheral gate electrode; (g) removing the first resist pattern; (h) forming respective first extension diffusion regions in the peripheral region on the opposite side surface sides of the first peripheral gate electrode by implanting an impurity of a predetermined conductivity type using the first peripheral gate electrode and the offset spacers as an implantation mask; and (i) removing at least a portion of the first insulating film on the photoelectric conversion region by performing a wet etching process. ### Claim 2 (depends on 1) The method for manufacturing the image capturing device according to claim 1, wherein in the step (i), the offset spacers are removed by performing the wet etching process; and the method further comprises, after the step (i), the steps of: (j) forming a second insulating film so as to cover the pixel region and the peripheral region; (k) forming a second resist pattern over the second insulating film so as to cover the photoelectric conversion region; (l) performing anisotropic etching of the second insulating film to form respective sidewall spacers on the opposite side surfaces of the first peripheral gate electrode; (m) removing the second resist pattern; (n) after the step (m), forming source-drain regions in the peripheral region on the opposite side surface sides of the first peripheral gate electrode by implanting an impurity of a predetermined conductivity type using the first peripheral gate electrode and the sidewall spacers as an implantation mask. ### Claim 3 (depends on 2) The method for manufacturing the image capturing device according to claim 2, including in the step (n), forming a floating diffusion region in the pixel region on one side of the transfer gate electrode, such that the transfer gate electrode is disposed between the floating diffusion region and the photoelectric conversion region, by implanting an impurity of a predetermined conductivity type. ### Claim 4 (depends on 2) The method for manufacturing the image capturing device according to claim 2, wherein in the step (1), each sidewall spacer is constituted of at least two layers. ### Claim 5 (depends on 2) The method for manufacturing the image capturing device according to claim 2, wherein in the step (a), the pixel region is one of a first pixel region, a second pixel region, and a third pixel region respectively corresponding to red, green and blue; in the step (c), the photoelectric conversion region, is one of a first photoelectric conversion region in the first pixel region, a second photoelectric conversion region in the second pixel region, and a third photoelectric conversion region in the third pixel region; and the method further comprises, after the step (n), the steps of: (o) forming a silicidation blocking film to cover the pixel region including the first photoelectric conversion region, the second photoelectric conversion region, and the third photoelectric conversion region; (p) removing a portion of the silicidation blocking film; and (q) forming a metal silicide film, wherein in the step (p), the silicidation blocking film is processed such that a portion of the silicidation blocking film covers at least one of the first to third photoelectric conversion regions. ### Claim 6 (depends on 5) The method for manufacturing the image capturing device according to claim 5, wherein in the step (p), the silicidation blocking film is processed such that portions of the silicidation blocking film cover two of said first to third photoelectric conversion regions, and the silicidation blocking film remaining on one of said two photoelectric conversion regions has a film thickness different from a film thickness of the silicidation blocking film remaining on the other of the two photoelectric conversion regions. ### Claim 7 (depends on 1) The method for manufacturing the image capturing device according to claim 1, wherein the first insulating film consists of a silicon oxide film. ### Claim 8 (depends on 2) The method for manufacturing the image capturing device according to claim 2, wherein the first insulating film consists of a silicon oxide film, and the second insulating film consists of a silicon oxide film and a silicon nitride film. ### Claim 9 (depends on 1) The method for manufacturing the image capturing device according to claim 1, wherein the first peripheral transistor is a resetting transistor, an amplification transistor, or a selection transistor. ### Claim 10 (depends on 1) The method for manufacturing the image capturing device according to claim 1, wherein in the step (b), a second peripheral gate electrode of a second peripheral transistor is further formed adjacent to the first peripheral transistor in the peripheral region; and the method further comprises, after the step (c) and before the step (d), the step of: (r) forming second extension diffusion regions in the peripheral region on opposite side surface sides of the second peripheral gate electrode by implanting an impurity of a predetermined conductivity type using the second peripheral gate electrode as an implantation mask. ### Claim 11 A method for manufacturing an image capturing device having a photoelectric conversion region, a transfer transistor and a first peripheral transistor, comprising the steps of: (a) defining a pixel region and a peripheral region by forming an element isolation insulating film in a semiconductor substrate; (b) forming a transfer gate electrode of the transfer transistor in the pixel region and forming a first peripheral gate electrode of the first peripheral transistor in the peripheral region; (c) forming the photoelectric conversion region in a portion of the pixel region on one side of the transfer gate electrode; (d) forming a first insulating film so as to cover the pixel region and the peripheral region; (e) forming a first resist pattern over the first insulating film so as to cover the pixel region; (f) performing anisotropic etching of the first insulating film to form respective offset spacers on opposite side surfaces of the first peripheral gate electrode; (g) removing the first resist pattern; (h) forming respective first extension diffusion regions in the peripheral region on the opposite side surface sides of the first peripheral gate electrode by implanting an impurity of a predetermined conductivity type using the first peripheral gate electrode and the offset spacers as an implantation mask; (i) removing the first insulating film on the photoelectric conversion region while protecting the peripheral region to leave the offset spacers by performing a wet etching process; (j) forming a second insulating film so as to cover the pixel region and the peripheral region; (k) forming a second resist pattern over the second insulating film so as to cover the photoelectric conversion region; (l) performing anisotropic etching of the second insulating film to form respective sidewall spacers interposing the offset spacers on the opposite side surfaces of the first peripheral gate electrode; (m) removing the second resist pattern; (n) after the step (m), forming source-drain regions in the peripheral region on the opposite side surface sides of the first peripheral gate electrode by implanting an impurity of a predetermined conductivity type using the first peripheral gate electrode, the offset spacers and the sidewall spacers as an implantation mask. ### Claim 12 (depends on 11) The method for manufacturing the image capturing device according to claim 11, including in the step (n), forming a floating diffusion region in the pixel region on one side of the transfer gate electrode, such that the transfer gate electrode is disposed between the floating diffusion region and the photoelectric conversion region, by implanting an impurity of a predetermined conductivity type. ### Claim 13 (depends on 11) The method for manufacturing the image capturing device according to claim 11, wherein in the step (1), each sidewall spacer is constituted of at least two layers. ### Claim 14 (depends on 11) The method for manufacturing the image capturing device according to claim 11, wherein the first insulating film consists of a silicon oxide film. ### Claim 15 (depends on 11) The method for manufacturing the image capturing device according to claim 11, wherein the first insulating film consists of a silicon oxide film, and the second insulating film consists of a silicon oxide film and a silicon nitride film.