Self-dispersing pigments
AssigneeThe Chemours Company Fc, LLC
InventorsFranck Andre Vanhecke, Mitchell Scott Chinn
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Abstract
The disclosure provides self-dispersing pigment having an isoelectric point of at least about 8 comprising an inorganic particle, and in particular a titanium dioxide (TiO2) pigment, treated sequentially by: hydrolyzing an aluminum compound or basic aluminate to deposit a hydrous alumina surface; and adding a dual-functional compound comprising an anchoring group that attaches the dual-functional compound to the pigment surface, and a basic amine group comprising a primary, secondary or tertiary amine. These self-dispersing pigments are useful in making décor paper that may be used in paper laminates.
Claims17
A self-dispersing pigment having an isoelectric point of at least about 8, comprising an inorganic particle treated sequentially by
- (a) hydrolyzing an aluminum compound or basic aluminate to deposit a hydrous alumina surface;
- and
- (b) adding a dual-functional compound comprising
- i. an anchoring group that attaches the dual-functional compound to the pigment surface selected from a carboxylic acid functional group, a di-carboxylic acid group, an oxoanion functional group, a 1,3-diketone, 3-ketoamide, derivative of 1,3-diketone, or derivative of 3-ketoamide, and
- i. ii a basic amine group comprising a primary, secondary or tertiary amine, and
- ii. a tethering group that chemically connects the anchoring group to the basic amine group wherein the tethering group comprises an alkyl chain of 1-8 carbon atoms;
- a carbon atom, an oxygen atom, a nitrogen atom, a phosphorus atom, a sulfur atom;
- or a polyetheramine comprising poly(oxyethylene) or poly(oxypropylene), or mixtures thereof;
- whereby the weight average molecular weight of the polyetheramine tether is about 220 to about 2000.
Dependencies are inferred from the claim text.