# US 10,312,547 B2 · Cross-woven electrode assembly

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- Number: US 10,312,547 B2
- Document ID: US10312547B2
- Status: Granted
- Kind: B2
- Application number: 14/952,431
- Filed: 2015-11-25
- Published: 2017-05-25
- Granted: 2019-06-04
- Earliest claimed: 2015-11-25
- Assignees: Robert Bosch Battery Systems LLC; Robert Bosch GmbH
- Applicants: Bosch Battery Systems, LLC; Robert Bosch GmbH
- Inventors: Yunlu Zhu; Mehul Botadra
- Web page: https://patentgrep.com/patent/US10312547B2

## CPC

- H01M 10/0583: of accumulators with folded construction elements except wound ones, i.e. folded positive or negative electrodes or separators, e.g. with "Z"-shaped electrodes or separators
- H01M 10/0431: {Cells with wound or folded electrodes (H01M10/045 takes precedence)}
- H01M 10/045: {Cells or batteries with folded plate-like electrodes}
- H01M 10/052: Li-accumulators
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A electrode assembly includes an electrode pair having a positive electrode and a negative electrode that are arranged crosswise and each z-folded while being cross-woven together in a continuous manner. The electrode assembly includes an electrode stack in which portions of the positive electrode are stacked along a stack axis so as to alternate with portions of the negative electrode.

## Claims

### Claim 1

An electrode assembly comprising
a positive electrode, and
a negative electrode,
wherein
the positive electrode comprises a first substrate formed of a first electrically-conductive material, the positive electrode having a first active material disposed on both sides of the first substrate,
the negative electrode comprises a second substrate formed of a second electrically-conductive material, the negative electrode having a second active material disposed on both sides of the second substrate,
one of the positive electrode and the negative electrode is disposed between a first separator and a second separator to form an alpha electrode, and the other one of the positive electrode and the negative electrode forms a beta electrode,
opposed lengthwise edges of each of the alpha electrode and the beta electrode are periodically notched and tabs are formed along the lengthwise edges between adjacent notches, and for each of the alpha electrode and the beta electrode, the notches on one lengthwise edge are offset along the length direction from the notches of an opposed lengthwise edge, and the tabs are electrically conductive and free of active material,
the alpha electrode is arranged in a series of z folds in which the alpha electrode is folded in a first direction about an axis parallel to a first fold axis so that a second portion of the alpha electrode overlies a first portion of the alpha electrode, and folded in a second direction about another axis parallel to the first fold axis so that a third portion of the alpha electrode overlies the first portion of the alpha electrode, the first direction being opposed to the second direction, and the first portion of the alpha electrode, the second portion of the alpha electrode, and the third portion of the alpha electrode being arranged in a stacked configuration defining a stack axis,
the beta electrode is arranged in a series of z folds in which the beta electrode is folded in a third direction about an axis parallel to a second fold axis so that a second portion of the beta electrode overlies a first portion of the beta electrode, and folded in a fourth direction about another axis parallel to the second fold axis so that a third portion of the beta electrode overlies the first portion of the beta electrode, the third direction being opposed to the fourth direction, and the second fold axis being perpendicular to the first fold axis and the stack axis, and
the z folds of the alpha electrode are woven with the z folds of the beta electrode such that the first, second and third portions of the beta electrode are stacked along the stack axis so as to alternate with the first, second and third portions of the alpha electrode.

### Claim 2 (depends on 1)

The electrode assembly of claim 1, wherein the alpha electrode and the beta electrode each have a thin, elongated shape and include a lengthwise dimension corresponding to the direction of elongation, a width dimension in a direction perpendicular to, and smaller than, the lengthwise dimension, and a thickness dimension in a direction perpendicular to both the lengthwise and width dimensions, the thickness dimension being smaller than the width dimension, and wherein
the first fold axis is perpendicular to the lengthwise dimension of the alpha electrode, and
the second fold axis is perpendicular to the lengthwise dimension of the beta electrode.

### Claim 3 (depends on 1)

The electrode assembly of claim 1, wherein
the first electrically-conductive material is different from the second electrically-conductive material, and
the first active material is different from the second active material.

### Claim 4 (depends on 1)

The electrode assembly of claim 1, wherein
the first active material is provided along the entire length of the first substrate such that a space exists between lengthwise edges of the positive electrode and the first active material, whereby a positive clear lane of bare substrate is provided along each lengthwise edge of the positive electrode, and
the second active material is provided along the entire length of the second substrate such that a space exists between lengthwise edges of the negative electrode and the second active material, whereby a negative clear lane of bare substrate is provided along each lengthwise edge of the negative electrode.

### Claim 5 (depends on 4)

The electrode assembly of claim 4, wherein
the positive clear lanes are periodically notched such that positive tabs are formed along the lengthwise edges of the positive electrode between adjacent notches, and
the negative clear lanes are periodically notched such that negative tabs are formed along the lengthwise edges of the negative electrode between adjacent notches.

### Claim 6 (depends on 5)

The electrode assembly of claim 5, wherein the tabs of the alpha electrode protrude beyond the first separator and the second separator.

### Claim 7 (depends on 5)

The electrode assembly of claim 5, wherein the positive tabs on one lengthwise edge of the positive electrode are offset along the length direction from the positive tabs of an opposed lengthwise edge of the positive electrode, and the negative tabs on one lengthwise edge of the negative electrode are offset along the length direction from the negative tabs of an opposed lengthwise edge of the negative electrode.

### Claim 8 (depends on 1)

The electrode assembly of claim 1, wherein the tabs of the alpha electrode protrude beyond the first separator and the second separator.

### Claim 9 (depends on 1)

The electrode assembly of claim 1, wherein the other one of the positive electrode and the negative electrode is free of separators.

### Claim 10

An electrode assembly comprising
a positive electrode, and
a negative electrode, wherein
the positive electrode comprises a first substrate formed of a first electrically-conductive material, the positive electrode having a first active material disposed on both sides of the first substrate,
the negative electrode comprises a second substrate formed of a second electrically-conductive material, the negative electrode having a second active material disposed on both sides of the second substrate,
one of the positive electrode and the negative electrode is disposed between a first separator and a second separator to form an insulated electrode,
opposed lengthwise edges of each of the first substrate and the second substrate are periodically notched and tabs are formed along the lengthwise edges between adjacent notches, and for each of the positive electrode and the negative electrode the notches on one lengthwise edge are offset along the length direction from the notches of an opposed lengthwise edge, and the tabs are electrically conductive and free of active material,
the insulated electrode is arranged in z-folds about first fold lines that are parallel to a first axis,
the other of the positive electrode and the negative electrode is arranged in z-folds about second fold lines that are parallel to a second axis, and the second axis is perpendicular to the first axis,
the insulated electrode is cross-woven with the other of the positive electrode and the negative electrode such that portions of the insulated electrode between adjacent first fold lines are stacked in an alternating manner with portions of the other of the positive electrode and the negative electrode between adjacent second fold lines to form an assembly of the portions that is stacked along a third axis that is perpendicular to both the first axis and the second axis.

### Claim 11

An electrochemical cell including
a cell housing, and
an electrode assembly disposed in the cell housing, the electrode assembly including
a positive electrode, and
a negative electrode,
wherein
the positive electrode comprises a first substrate formed of a first electrically-conductive material, the positive electrode having a first active material disposed on both sides of the first substrate,
the negative electrode comprises a second substrate formed of a second electrically-conductive material, the negative electrode having a second active material disposed on both sides of the second substrate,
one of the positive electrode and the negative electrode is disposed between a first separator and a second separator to form an alpha electrode, and the other one of the positive electrode and the negative electrode forms a beta electrode,
opposed lengthwise edges of each of the alpha electrode and the beta electrode are periodically notched and tabs are formed along the lengthwise edges between adjacent notches, and for each of the alpha electrode and the beta electrode, the notches on one lengthwise edge are offset alone the length direction from the notches of an opposed lengthwise edge, and the tabs are electrically conductive and free of active material,
the alpha electrode is arranged in a series of z folds in which the alpha electrode is folded in a first direction about an axis parallel to a first fold axis so that a second portion of the alpha electrode overlies a first portion of the alpha electrode, and folded in a second direction about another axis parallel to the first fold axis so that a third portion of the alpha electrode overlies the first portion of the alpha electrode, the first direction being opposed to the second direction, and the first portion of the alpha electrode, the second portion of the alpha electrode, and the third portion of the alpha electrode being arranged in a stacked configuration defining a stack axis,
the beta electrode is arranged in a series of z folds in which the beta electrode is folded in a third direction about an axis parallel to a second fold axis so that a second portion of the beta electrode overlies a first portion of the beta electrode, and folded in a fourth direction about another axis parallel to the second fold axis so that a third portion of the beta electrode overlies the first portion of the beta electrode, the third direction being opposed to the fourth direction, and the second fold axis being perpendicular to the first fold axis and the stack axis,
the z folds of the alpha electrode are woven with the z folds of the beta electrode such that the first, second and third portions of the beta electrode are stacked along the stack axis so as to alternate with the first, second and third portions of the alpha electrode.

### Claim 12

A method of forming an electrode assembly comprising a positive electrode, and a negative electrode,
the positive electrode comprises a first substrate formed of a first electrically-conductive material, the positive electrode having a first active material disposed on both sides of the first substrate,
the negative electrode comprises a second substrate formed of a second electrically-conductive material, the negative electrode having a second active material disposed on both sides of the second substrate,
wherein the method includes
disposing one of the positive electrode and the negative electrode between a first separator and a second separator to form an alpha electrode, and using the other one of the positive electrode and the negative electrode to form a beta electrode,
arranging the alpha electrode in a first series of z folds,
while arranging the alpha electrode in the first series of z-folds, also arranging the beta electrode in a second series of z folds that is interwoven with the first series of z-folds to provide an electrode stack in which portions of the beta electrode are stacked along a stack axis so as to alternate with portions of the alpha electrode, and
wherein
opposed lengthwise edges of each of the alpha electrode and the beta electrode are periodically notched and tabs are formed along the lengthwise edges between adjacent notches, and for each of the alpha electrode and the beta electrode, the notches on one lengthwise edge are offset along the length direction from the notches of an opposed lengthwise edge, and the tabs are electrically conductive and free of active material.

### Claim 13 (depends on 12)

The method of claim 12, wherein
the step of arranging the alpha electrode in a first series of z folds includes arranging the alpha electrode such that each z fold in the first series of z folds includes folding the alpha electrode in a first direction about an axis parallel to a first fold axis so that a second portion of the alpha electrode overlies a first portion of the alpha electrode, and folding the alpha electrode in a second direction about another axis parallel to the first fold axis so that a third portion of the alpha electrode overlies the first portion of the alpha electrode, the first direction being opposed to the second direction, and the first portion of the alpha electrode, the second portion of the alpha electrode, and the third portion of the alpha electrode being arranged in a stacked configuration defining the stack axis, and
the step of arranging the beta electrode in a second series of z folds includes arranging the beta electrode such that each z-fold in the second series of z folds includes folding the beta electrode in a third direction about an axis parallel to a second fold axis so that a second portion of the beta electrode overlies a first portion of the beta electrode, and folding the beta electrode in a fourth direction about another axis parallel to the second fold axis so that a third portion of the beta electrode overlies the first portion of the beta electrode, the third direction being opposed to the fourth direction, and the second fold axis being perpendicular to the first fold axis and the stack axis.

### Claim 14 (depends on 13)

The method of claim 13, wherein
interweaving the second series of z folds with the first series of z folds provides an electrode stack in which the first, second and third portions of the beta electrode are stacked along the stack axis so as to alternate with the first, second and third portions of the alpha electrode.

### Claim 15 (depends on 13)

The method of claim 13 wherein
the alpha electrode and the beta electrode each have a thin, elongated shape and include a lengthwise dimension corresponding to the direction of elongation, a width dimension in a direction perpendicular to, and smaller than, the lengthwise dimension, and a thickness dimension in a direction perpendicular to both the lengthwise and width dimensions, the thickness dimension being smaller than the width dimension, and
the steps of arranging the alpha electrode and arranging the beta electrode include orienting the alpha electrode and the beta electrode such that the lengthwise dimension of the alpha electrode is perpendicular to the lengthwise dimension of the beta electrode.

### Claim 16 (depends on 12)

The method of claim 12 wherein
prior to the steps of arranging the alpha electrode and arranging the beta electrode, stacking first portions of each of the alpha electrode and the beta electrode such that a lengthwise edge of the alpha electrode extends in a direction perpendicular to a lengthwise edge of the beta electrode.