# US 10,312,465 B2 · Method for making organic light emitting diode > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,312,465 B2 - Document ID: US10312465B2 - Status: Granted - Kind: B2 - Application number: 15/848,362 - Filed: 2017-12-20 - Published: 2019-02-28 - Granted: 2019-06-04 - Earliest claimed: 2017-08-30 - Assignees: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Applicants: Tsinghua University; Hon Hai Precision Industry Co., Ltd. - Inventors: Wen Ning; Peng Liu; Kai-Li Jiang; Shou-Shan Fan - Web page: https://patentgrep.com/patent/US10312465B2 ## CPC - H10K 85/221: {Carbon nanotubes} - H10K 50/115: comprising active inorganic nanostructures, e.g. luminescent quantum dots - H10K 50/16: Electron transporting layers - H10P 14/3464: {Nanotubes} - H10K 71/191: {characterised by provisions for the orientation or alignment of the layer to be deposited} - H10K 71/236: {using printing techniques, e.g. applying the etch liquid using an ink jet printer} - H10K 71/40: Thermal treatment, e.g. annealing in the presence of a solvent vapour - H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES - H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10 ## Abstract A method for making an organic light emitting diode includes providing a preform structure including an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order. The organic light emitting layer has a first surface and a second surface opposite to the first surface, and the second surface is in direct contact with the hole transport layer. A carbon nanotube structure is located on the first surface. A monomer solution is disposed on the carbon nanotube structure, and the monomer solution is formed by dispersing a monomer into an organic solvent. The monomer is polymerized to form a polymer, and a cathode electrode is formed on the polymer. ## Claims ### Claim 1 A method for making an organic light emitting diode, the method comprising: providing a preform structure comprising an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order, wherein the organic light emitting layer has a first surface and a second surface opposite to the first surface, and the second surface is in direct contact with the hole transport layer; placing a carbon nanotube structure comprising a plurality of carbon nanotubes on the first surface; disposing a monomer solution on the carbon nanotube structure after placing the carbon nanotube structure on the first surface, wherein the monomer solution is formed by dispersing a monomer into an organic solvent; polymerizing the monomer to form a polymer; and forming a cathode electrode on a surface of the polymer away from the preform structure. ### Claim 2 (depends on 1) The method of claim 1, wherein the preform structure further comprises a support body for supporting the anode electrode, the hole transport layer, and the organic light emitting layer. ### Claim 3 (depends on 1) The method of claim 1, wherein the plurality of carbon nanotubes is joined end-to-end by van der Wards attractive force and extends substantially along the same direction. ### Claim 4 (depends on 1) The method of claim 1, wherein the plurality of carbon nanotubes is substantially parallel to the first surface. ### Claim 5 (depends on 1) The method of claim 1, wherein a plurality of gaps is defined by the plurality of carbon nanotubes, and the monomer solution passes through the plurality of gaps and arrive at the first surface during disposing the monomer solution. ### Claim 6 (depends on 1) The method of claim 1, wherein the polymer has an ability to transmit electrons. ### Claim 7 (depends on 1) The method of claim 1, wherein the disposing the monomer solution comprises placing the carbon nanotube structure and the preform structure in a container and injecting the monomer solution to the container. ### Claim 8 (depends on 3) The method of claim 3, wherein the carbon nanotube structure comprises two carbon nanotube films, and an angle between the plurality of first carbon nanotubes in the two carbon nanotube films ranges from about 0 degree to about 90 degrees. ### Claim 9 A method for making an organic light emitting diode, the method comprising: providing a preform structure comprising an anode electrode, a hole transport layer, and an organic light emitting layer stacked on each other in that order, wherein the organic light emitting layer has a first surface and a second surface opposite to the first surface, and the second surface is indirect contact with the hole transport layer; placing a first carbon nanotube structure comprising a plurality of first carbon nanotubes on the first surface to form a first composite structure; placing a second carbon nanotube structure comprising a plurality of second carbon nanotubes on a surface of a cathode electrode to form a second composite structure; locating the first composite structure and the second composite structure on a base, wherein the base, the preform structure, and the cathode electrode form a mold having an opening, the first composite structure and the second composite structure are spaced apart from each other; and the first carbon nanotube structure and the second carbon nanotube structure are opposite to each other and inside of the mold; injecting the monomer solution into the inside of the mold from the opening, wherein the monomer solution is formed by dispersing a monomer into an organic solvent; polymerizing the monomer; and removing the base. ### Claim 10 (depends on 9) The method of claim 9, wherein the plurality of first carbon nanotubes is joined end-to-end by van der Waals attractive force, and substantially extends along the same direction. ### Claim 11 (depends on 9) The method of claim 9, wherein the plurality of second carbon nanotubes is joined end-to-end by van der Waals attractive force and substantially extends along the same direction. ### Claim 12 (depends on 9) The method of claim 9, wherein the plurality of first carbon nanotubes is substantially parallel to the first surface. ### Claim 13 (depends on 9) The method of claim 9, wherein the plurality of second carbon nanotubes is substantially parallel to the surface of the cathode electrode. ### Claim 14 (depends on 9) The method of claim 9, wherein a plurality of first gaps is defined by the plurality of first carbon nanotubes, and the monomer solution passes through the plurality of first gaps and arrive at the first surface during injecting the monomer solution. ### Claim 15 (depends on 9) The method of claim 9, wherein a plurality of second gaps is defined by the plurality of second carbon nanotubes, and the monomer solution passes through the plurality of second gaps and arrive at the surface of the cathode electrode during injecting the monomer solution. ### Claim 16 (depends on 9) The method of claim 9, wherein the polymer has ara ability to transmit electrons.