# US 10,312,464 B2 · Active OLED display, method of operating an active OLED display and compound

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- Number: US 10,312,464 B2
- Document ID: US10312464B2
- Status: Granted
- Kind: B2
- Application number: 15/515,174
- Filed: 2015-09-30
- Published: 2017-08-03
- Granted: 2019-06-04
- Earliest claimed: 2014-09-30
- Assignees: Novaled GmbH
- Applicants: Novaled GmbH
- Inventors: Carsten Rothe; Thomas Rosenow; Martin Koehler; Mike Zoellner; Andreas Haldi; Tobias Canzler
- Web page: https://patentgrep.com/patent/US10312464B2

## CPC

- H10K 50/155: comprising dopants
- C07C 211/56: the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
- H10K 59/35: comprising red-green-blue [RGB] subpixels
- H10K 85/631: {Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine}
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

An active OLED display, comprising a plurality of OLED pixels, each of the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers is provided between and in contact with the cathode and the anode and comprises an electron transport layer, a hole transport layer, and a light emitting layer provided between the hole transport layer and the electron transport layer, and a driving circuit configured to separately driving the pixels of the plurality of OLED pixels, wherein, for the plurality of OLED pixels, a common hole transport layer is formed by the hole transport layers provided in the stack of organic layers of the plurality of OLED pixels, the common hole transport layer comprising a hole transport matrix material and at least one electrical p-dopant, and the electrical conductivity of the hole transport material being lower than 1×10−3 S·m−1 and higher than 1×10−8 S·m−1.

## Claims

### Claim 1

An active OLED display, comprising
a plurality of OLED pixels, each of the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers
is provided between and in contact with the cathode and the anode, and
comprises an electron transport layer, a hole transport layer, and a light emitting layer provided between the hole transport layer and the electron transport layer, and
a driving circuit configured for separately driving the pixels of the plurality of OLED pixels,
wherein, for the plurality of OLED pixels, a common hole transport layer is formed by the hole transport layers provided in the stack of organic layers of the plurality of OLED pixels, the common hole transport layer comprising a hole transport matrix material and an electrical p-dopant, and wherein the electrical conductivity of the common hole transport layer is lower than 1×10−3 S·m−1 and higher than 1×10−8 S·m−1, and
wherein the common hole transport layer has a thickness of less than 50 nm.

### Claim 2 (depends on 1)

The active OLED display according to claim 1, wherein the LUMO energy level of the electrical p-dopant, expressed in the absolute scale referring to vacuum energy level being zero, is at least 150 meV higher than the highest HOMO energy level of the one or more compounds forming the hole transport matrix material.

### Claim 3 (depends on 1)

The active OLED display according to claim 1, wherein the LUMO energy level of the electrical p-dopant, expressed in the absolute scale referring to vacuum energy level being zero, is less than 600 meV above the highest HOMO energy level of the one or more compounds forming the hole transport matrix material.

### Claim 4 (depends on 1)

The active OLED display according to claim 1, wherein the hole transport matrix material consists of one or more compounds having energies of their highest occupied molecular orbitals, expressed in the absolute scale referring to vacuum energy level being zero, in the range from −4.8 eV to −5.5 eV.

### Claim 5 (depends on 1)

The active OLED display according to claim 1, wherein the common hole transport layer has a thickness of more than 3 nm.

### Claim 6 (depends on 1)

The active OLED display according to claim 1, wherein the work function of the anode, expressed in the absolute scale referring to vacuum energy level being zero, is less than 500 meV above the highest LUMO energy level of the one or more compounds forming the p-dopant.

### Claim 7 (depends on 1)

The active OLED display according to claim 1, wherein the stack of organic layers further comprises an electron blocking layer provided between the hole transport layer and the light emitting layer.

### Claim 8 (depends on 7)

The active OLED display according to claim 7, wherein the electron blocking layer has a thickness of more than 30 nm.

### Claim 9 (depends on 7)

The active OLED display according to claim 7, wherein the electron blocking layer has a thickness of less than 200 nm.

### Claim 10 (depends on 7)

The active OLED display according to claim 7, wherein each of the one or more compounds forming the electron blocking layer has a HOMO level, expressed in the absolute scale referring to vacuum energy level being zero, higher than the HOMO level of any compound forming the hole transport matrix material of the common hole transport layer.

### Claim 11 (depends on 7)

The active OLED display according to claim 7, wherein the hole transport matrix material of the common hole transport layer is provided with a hole mobility which is lower than a hole mobility of a matrix material of the electron blocking layer.

### Claim 12 (depends on 1)

The active OLED display according to claim 1, wherein the hole transport matrix material of the common hole transport layer is selected from one or more compounds comprising a conjugated system of delocalized electrons, the conjugated system comprising lone electron pairs of at least two tertiary amine nitrogen atoms.

### Claim 13 (depends on 1)

The active OLED display according to claim 1, wherein the light emitting layer comprises a plurality of separated sub-regions, each of the sub-regions being assigned to one of the pixels from the plurality of OLED pixels.

### Claim 14 (depends on 1)

The active OLED display according to claim 1, wherein, for the plurality of OLED pixels, a common electron transport layer is formed by the electron transport layers provided in the stack of organic layers of the plurality of OLED pixels.

### Claim 15 (depends on 14)

The active OLED display according to claim 14, wherein the common electron transport layer comprises an electron transport matrix material and an electrical n-dopant.

### Claim 16 (depends on 1)

A method of operating an active OLED display having a plurality of OLED pixels according claim 1, wherein a driving circuit applies a driving current to each pixel of the plurality of OLED pixels, the driving current being different for neighbor OLED pixels at an operation time.

### Claim 17

Compound having formula
